ES2106174T3 - Procedimiento para preparar poliolefinas que tienen una distribucion bimodal de peso molecular. - Google Patents

Procedimiento para preparar poliolefinas que tienen una distribucion bimodal de peso molecular.

Info

Publication number
ES2106174T3
ES2106174T3 ES92907694T ES92907694T ES2106174T3 ES 2106174 T3 ES2106174 T3 ES 2106174T3 ES 92907694 T ES92907694 T ES 92907694T ES 92907694 T ES92907694 T ES 92907694T ES 2106174 T3 ES2106174 T3 ES 2106174T3
Authority
ES
Spain
Prior art keywords
molecular weight
copolymer
weight distribution
catalyst
polyolefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92907694T
Other languages
English (en)
Inventor
Phil Marvin Stricklen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ES2106174T3 publication Critical patent/ES2106174T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SE PRESENTA UN PROCESO DE POLIMERIZACION EN DOS PASOS PARA PRODUCIR UNA POLIOLEFINA QUE TIENE UNA DISTRIBUCION BIMODAL DE PESO MOLECULAR. EN EL PASO UNO, BAJO CONDICIONES DE POLIMERIZACION, SE PONEN EN CONTACTO AL MENOS DOS ALFA-OLEFINAS DIFERENTES CON UN SISTEMA CATALIZADOR QUE COMPRENDE UN ALUMINOXANO Y UN METALOCENO, SELECCIONADOS ENTRE EL GRUPO QUE CONSTA DE MONO, DI Y TRI-CICLOPENTADIENILES Y CICLOPENTADIENILES SUBSTITUIDOS, DE UN METAL SELECCIONADO ENTRE TITANIO, VANADIO, CROMO, CIRCONIO, NIOBIO, MOLIBDENO, HAFNIO, TANTALIO Y TUNGSTENO, CON LA CONDICION DE QUE SI DICHO METAL ES TITANIO ENTONCES ESTARA PRESENTE UN METALOCENO DE AL MENOS ALGUN OTRO DE DICHOS METALES DE MANERA QUE SE FORME UNA PRIMERA MEZCLA DE POLIMERIZACION QUE COMPRENDA UN COPOLIMERO DE BAJA CRISTALINIDAD Y ALTO PESO MOLECULAR, UN MONOMERO NO REACCIONADO, UN COMONOMERO NO REACCIONADO Y EL CATALIZADOR. TODO ELLO VA SEGUIDO POR LA PUESTA EN CONTACTO, BAJO CONDICIONES DE POLIMERIZACION, DE HIDROGENO (Y OPCIONALMENTE ALFA-OLEFINA ADICIONAL), CON DICHA PRIMERA MEZCLA DE POLIMERIZACION QUE COMPRENDE COPOLIMERO, MONOMERO NO REACCIONADO, COMONOMERO NO REACCIONADO Y EL CATALIZADOR DE MANERA QUE SE FORME UNA SEGUNDA MEZCLA DE POLIMERIZACION QUE COMPRENDA UN COPOLIMERO DE BAJA CRISTALINIDAD Y ALTO PESO MOLECULAR, Y UN HOMOPOLIMERO DE ALTA CRISTALINIDAD Y BAJO PESO MOLECULAR.
ES92907694T 1991-03-04 1992-03-03 Procedimiento para preparar poliolefinas que tienen una distribucion bimodal de peso molecular. Expired - Lifetime ES2106174T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US66415891A 1991-03-04 1991-03-04
US83984392A 1992-02-21 1992-02-21

Publications (1)

Publication Number Publication Date
ES2106174T3 true ES2106174T3 (es) 1997-11-01

Family

ID=27098901

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92907694T Expired - Lifetime ES2106174T3 (es) 1991-03-04 1992-03-03 Procedimiento para preparar poliolefinas que tienen una distribucion bimodal de peso molecular.

Country Status (9)

Country Link
EP (1) EP0527221B1 (es)
JP (1) JPH06511502A (es)
AT (1) ATE157673T1 (es)
CA (2) CA2060019A1 (es)
DE (1) DE69221976T2 (es)
DK (1) DK0527221T3 (es)
ES (1) ES2106174T3 (es)
GR (1) GR3025088T3 (es)
WO (1) WO1992015619A1 (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
JP3264333B2 (ja) * 1992-05-28 2002-03-11 出光興産株式会社 エチレン系重合体組成物の製造方法
DE4330667A1 (de) * 1993-09-10 1995-03-16 Basf Ag Verfahren zur Herstellung von mehrphasigen Homo- oder Copolymerisaten von C¶2¶-C¶1¶¶0¶-Alk-1-enen in einer Reaktionszone
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
US5399622A (en) * 1993-11-17 1995-03-21 Phillips Petroleum Company System of chromium catalyst and yttrium catalyst, olefin polymerization process, and polymer
US5648438A (en) * 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
ES2150529T3 (es) * 1994-04-07 2000-12-01 Bp Chem Int Ltd Procedimiento de polimerizacion.
ES2116188B1 (es) 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
BE1009186A3 (fr) * 1995-03-13 1996-12-03 Solvay Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene.
DE69602329T2 (de) * 1995-09-14 1999-09-23 Showa Denko K.K., Tokio/Tokyo Katalysator für ethylenische Polymerisation
EP0881237A1 (en) 1997-05-26 1998-12-02 Fina Research S.A. Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
FI973050L (fi) * 1997-07-18 1999-01-19 Borealis As Menetelmä sellaisten olefiinipolymeerien valmistamiseksi joilla on haluttu molekyylipainojakauma
KR100556319B1 (ko) * 1997-08-15 2006-03-03 다우 글로벌 테크놀로지스 인크. 실질적으로 선형인 균질한 올레핀 중합체 조성물로부터제조된 필름
US6166152A (en) * 1998-02-26 2000-12-26 Phillips Petroleum Company Process to produce low density polymer in a loop reactor
KR20010052195A (ko) 1998-03-04 2001-06-25 엑손 케미칼 패턴츠 인코포레이티드 폴리올레핀 중합체 분산액을 제조하기 위한 생성물 및 방법
US6329477B1 (en) 1998-03-04 2001-12-11 Exxonmobil Chemical Patents Inc. Method for increasing diene conversion in EPDM type polymerizations
US6319998B1 (en) 1998-03-04 2001-11-20 Exxon Mobil Chemical Patents Inc. Method for making polymer blends by using series reactors
US6207606B1 (en) 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process
CN1982361B (zh) 2001-08-17 2011-11-16 陶氏环球技术有限责任公司 双峰聚乙烯组合物及其制品
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US8835577B2 (en) 2007-11-15 2014-09-16 Univation Technologies, Llc Catalyst systems having a tailored hydrogen response
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
WO2010132811A1 (en) 2009-05-14 2010-11-18 Univation Technologies, Llc Mixed metal catalyst systems having a tailored hydrogen response
GB2533770B (en) 2014-12-22 2021-02-10 Norner Verdandi As Polyethylene for pipes
CN111356705A (zh) 2017-11-15 2020-06-30 埃克森美孚化学专利公司 聚合方法
EP3710502A1 (en) 2017-11-15 2020-09-23 ExxonMobil Chemical Patents Inc. Polymerization processes
CN111448226B (zh) 2017-11-15 2023-08-25 埃克森美孚化学专利公司 聚合方法
EP3749707A1 (en) 2018-02-05 2020-12-16 ExxonMobil Chemical Patents Inc. Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5032562A (en) * 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
TW206240B (es) * 1990-02-13 1993-05-21 Mitsui Petroleum Chemicals Ind

Also Published As

Publication number Publication date
DE69221976D1 (de) 1997-10-09
CA2060019A1 (en) 1992-09-05
EP0527221B1 (en) 1997-09-03
EP0527221A1 (en) 1993-02-17
CA2078777C (en) 1998-09-29
JPH06511502A (ja) 1994-12-22
CA2078777A1 (en) 1992-09-05
DK0527221T3 (da) 1997-09-29
GR3025088T3 (en) 1998-01-30
DE69221976T2 (de) 1998-01-02
ATE157673T1 (de) 1997-09-15
EP0527221A4 (en) 1993-09-15
WO1992015619A1 (en) 1992-09-17

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