ES2106810T3 - Procedimiento para la policondensacion continua de acido tereftalico y 1,4-bis-(hidroximetil)-ciclohexano. - Google Patents
Procedimiento para la policondensacion continua de acido tereftalico y 1,4-bis-(hidroximetil)-ciclohexano.Info
- Publication number
- ES2106810T3 ES2106810T3 ES92117441T ES92117441T ES2106810T3 ES 2106810 T3 ES2106810 T3 ES 2106810T3 ES 92117441 T ES92117441 T ES 92117441T ES 92117441 T ES92117441 T ES 92117441T ES 2106810 T3 ES2106810 T3 ES 2106810T3
- Authority
- ES
- Spain
- Prior art keywords
- bis
- procedure
- hydroximetil
- cycllohexane
- continuous polycondensation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION CONTINUADA DE POLIESTERES POR MEDIO DE LA ESTERIFICACION DE ACIDO TEREFTALICO CON 1,4 BIS(HIDROXIMETIL) ENCIA DE UN CATALIZADOR DE TITANIO, A 265 A 305 (GRADOS) C Y 0,8 A 2,0 BAR, HASTA UN GRADO DE TRANSFORMACION DE 98,0 A 99,0 %, PRECONDENSACION A 290 A 305 (GRADOS) C Y 0,01 A 1,5 BAR, HASTA UN GRADO DE TRANSFORMACION DE 99,4 A 99,7 % Y POLICONDENSACION BAJO ADICION DE MAS CATALIZADOR DE TITANIO A 295 A 310 (GRADOS) C Y MENOS DE 1,5 MBAR, HASTA UN GRADO DE TRANSFORMACION CORRESPONDIENTE A 50 A 95 % DE LA VISCOSIDAD MAXIMA POSIBLE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4137842A DE4137842A1 (de) | 1991-11-16 | 1991-11-16 | Verfahren zur kontinuierlichen polykondensation von terephthalsaeure und 1,4-bis-(hydroxymethyl)-cyclohexan |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2106810T3 true ES2106810T3 (es) | 1997-11-16 |
Family
ID=6445016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92117441T Expired - Lifetime ES2106810T3 (es) | 1991-11-16 | 1992-10-13 | Procedimiento para la policondensacion continua de acido tereftalico y 1,4-bis-(hidroximetil)-ciclohexano. |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5198530A (es) |
| EP (1) | EP0537672B1 (es) |
| DE (2) | DE4137842A1 (es) |
| ES (1) | ES2106810T3 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW381104B (en) * | 1996-02-20 | 2000-02-01 | Eastman Chem Co | Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol |
| US6103859A (en) * | 1997-04-09 | 2000-08-15 | Eastman Chemical Company | Late addition of supplemental ethylene glycol in the preparation of copolyesters |
| US6376642B1 (en) | 1998-07-07 | 2002-04-23 | Atofina Chemicals, Inc. | Polyester polycondensation with lithium titanyl oxalate catalyst |
| US6372879B1 (en) | 2000-01-07 | 2002-04-16 | Atofina Chemicals, Inc. | Polyester polycondensation with catalyst and a catalyst enhancer |
| US6258925B1 (en) | 2000-01-07 | 2001-07-10 | Atofina Chemicals, Inc. | Polyester polycondensation with titanyl oxalate catalyst and a catalyst enhancer |
| US6429278B1 (en) | 2001-01-22 | 2002-08-06 | Eastman Chemical Company | Process for manufacture of polyesters based on 1,4-cyclohexanedimethanol and isophthalic acid |
| US6653440B2 (en) | 2001-11-13 | 2003-11-25 | Mitsubishi Gas Chemical Company | Process for producing copolyester resin |
| ITMI20021293A1 (it) * | 2002-06-12 | 2003-12-12 | Gen Electric | Metodo per preparare poli(cicloesan-1,4-dicarbossilato) (i) da acido cicloesan-1,4-bicarbossilico e composizione |
| US6914120B2 (en) * | 2002-11-13 | 2005-07-05 | Eastman Chemical Company | Method for making isosorbide containing polyesters |
| US8586701B2 (en) * | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US7211634B1 (en) * | 2006-04-28 | 2007-05-01 | Eastman Chemical Company | Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol |
| WO2008042383A1 (en) * | 2006-10-02 | 2008-04-10 | Armstrong World Industries, Inc. | Process for preparing high molecular weight polyesters |
| EP2225084B1 (en) | 2007-11-21 | 2013-05-29 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
| US9517584B2 (en) | 2013-12-18 | 2016-12-13 | Eastman Chemical Company | Articles comprising isosorbide and processes for their manufacture |
| CN113444235A (zh) * | 2020-05-06 | 2021-09-28 | 广东虹勤通讯技术有限公司 | 一种改性pct树脂及其制备方法和树脂合金材料 |
| CN119751832A (zh) * | 2024-12-27 | 2025-04-04 | 四川轻化工大学 | 高耐温pctg及其制备方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1258086B (de) * | 1961-03-09 | 1968-01-04 | Eastman Kodak Co | Hochschmelzende Polyester zur Herstellung von Faeden und Folien |
| US3431243A (en) * | 1963-12-04 | 1969-03-04 | Teijin Ltd | Process for preparation of poly(ethylene terphthalate) from compressed terephthalic acid |
| GB1445034A (en) * | 1974-01-25 | 1976-08-04 | Monsanto Co | Continuous production of polyesters |
| DE2414122C3 (de) * | 1974-03-23 | 1982-03-25 | Davy International Ag, 6000 Frankfurt | Verfahren zur Herstellung linearer Polyester aus Äthylenglykol und Terephthalsäure |
| DE2651639A1 (de) * | 1976-11-12 | 1978-05-24 | Bayer Ag | Verfahren zur herstellung von kohlensaeureestern von polyesterpolyolen |
| US4297455A (en) * | 1977-03-22 | 1981-10-27 | Bayer Aktiengesellschaft | Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates |
| US4155889A (en) * | 1978-04-10 | 1979-05-22 | Eastman Kodak Company | Process for substantially increasing the flexibility of a polyester |
| US4346213A (en) * | 1980-08-25 | 1982-08-24 | Celanese Corporation | Process for the preparation of polybutylene terephthalate |
| US4350807A (en) * | 1981-02-09 | 1982-09-21 | Eastman Kodak Company | Copolyester compositions |
| US4396746A (en) * | 1981-04-16 | 1983-08-02 | Daicel Chemical Industries, Ltd. | Thermoplastic polyester copolymer |
| US4379912A (en) * | 1982-08-12 | 1983-04-12 | Eastman Kodak Company | Method of making polyester prepolymers |
| US4786692A (en) * | 1982-12-20 | 1988-11-22 | General Electric Company | High strength, reduced heat distortion temperature thermoplastic composition |
| US4481352A (en) * | 1983-06-30 | 1984-11-06 | Eastman Kodak Company | Polyester waxes based on mixed aliphatic dibasic acids |
| US4446303A (en) * | 1983-07-26 | 1984-05-01 | Eastman Kodak Company | Process for preparing high molecular weight polyesters |
| US4780527A (en) * | 1987-05-06 | 1988-10-25 | Industrial Technology Research Institute | Preparation of polyesters from terephthalic acid |
| US4900610A (en) * | 1988-02-19 | 1990-02-13 | Hoechst Celanese Corporation | Polyester molding composition |
-
1991
- 1991-11-16 DE DE4137842A patent/DE4137842A1/de not_active Withdrawn
-
1992
- 1992-03-20 US US07/853,974 patent/US5198530A/en not_active Expired - Fee Related
- 1992-10-13 ES ES92117441T patent/ES2106810T3/es not_active Expired - Lifetime
- 1992-10-13 DE DE59208774T patent/DE59208774D1/de not_active Expired - Fee Related
- 1992-10-13 EP EP92117441A patent/EP0537672B1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0537672B1 (de) | 1997-08-06 |
| DE4137842A1 (de) | 1993-05-19 |
| US5198530A (en) | 1993-03-30 |
| EP0537672A3 (en) | 1993-05-05 |
| EP0537672A2 (de) | 1993-04-21 |
| DE59208774D1 (de) | 1997-09-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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