ES2106984T3 - Metodo para la produccion de una resina absorbente. - Google Patents
Metodo para la produccion de una resina absorbente.Info
- Publication number
- ES2106984T3 ES2106984T3 ES93310168T ES93310168T ES2106984T3 ES 2106984 T3 ES2106984 T3 ES 2106984T3 ES 93310168 T ES93310168 T ES 93310168T ES 93310168 T ES93310168 T ES 93310168T ES 2106984 T3 ES2106984 T3 ES 2106984T3
- Authority
- ES
- Spain
- Prior art keywords
- absorbent resin
- carboxyl group
- less
- production
- cal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000002745 absorbent Effects 0.000 title abstract 4
- 239000002250 absorbent Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000011347 resin Substances 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
- -1 CARBOXYL GROUP Chemical group 0.000 abstract 3
- 238000010521 absorption reaction Methods 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 230000009257 reactivity Effects 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/243—Two or more independent types of crosslinking for one or more polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Hematology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
SE PREVE UN METODO PARA LA PRODUCCION DE UNA RESINA ABSORBENTE QUE MANTIENE UN ALTO NIVEL DE CAPACIDAD DE ABSORCION SIN CARGA, UNA DE LAS PROPIEDADES FISICAS BASICAS DE UNA RESINA ABSORBENTE, Y MANTIENE UNA EXCELENTE CAPACIDAD DE ABSORCION BAJO CARGA. EL PRODUCTO SE CONSIGUE MEZCLANDO UNA RESINA ABSORBENTE, COMO PUEDE SER UNA QUE POSEE UN GRUPO CARBOXILO, CON UN PRIMER AGENTE DE RETICULACION QUE POSEE UN PARAMETRO DE SOLUBILIDAD (VALOR SP) NO MENOR QUE 12.5 (CAL/CM3)1/2 Y QUE PRESENTA UNA REACTIVIDAD CON EL GRUPO CARBOXILO, UN SEGUNDO AGENTE DE RETICULACION QUE POSEA UN PARAMETRO DE SOLUBILIDAD (VALOR SP) MENOR QUE 12.5 (CAL/CM3)1/2 Y QUE PRESENTE REACTIVIDAD CON EL GRUPO CARBOXILO, Y SOMETIENDO DESPUES LA MEZCLA RESULTANTE A UN TRATAMIENTO TERMICO A UNA TEMPERATURA NO MENOR DE 160
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4336392A JP2675729B2 (ja) | 1992-12-16 | 1992-12-16 | 吸水性樹脂の製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2106984T3 true ES2106984T3 (es) | 1997-11-16 |
Family
ID=18298665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93310168T Expired - Lifetime ES2106984T3 (es) | 1992-12-16 | 1993-12-16 | Metodo para la produccion de una resina absorbente. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5422405A (es) |
| EP (1) | EP0605150B1 (es) |
| JP (1) | JP2675729B2 (es) |
| KR (1) | KR0137347B1 (es) |
| DE (1) | DE69314451T2 (es) |
| ES (1) | ES2106984T3 (es) |
Families Citing this family (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4333056C2 (de) * | 1993-09-29 | 1998-07-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, wäßrige Flüssigkeiten absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Absorptionsmittel |
| US5610208A (en) * | 1994-02-17 | 1997-03-11 | Nippon Shokubai Co., Ltd. | Water-absorbent agent, method for production thereof, and water-absorbent composition |
| US5830543A (en) | 1994-05-30 | 1998-11-03 | Nippon Shokubai Co., Ltd. | Gelling material for aqueous fluids |
| US5624967A (en) | 1994-06-08 | 1997-04-29 | Nippon Shokubai Co., Ltd. | Water-absorbing resin and process for producing same |
| WO1995034377A1 (en) * | 1994-06-13 | 1995-12-21 | Nippon Shokubai Co., Ltd. | Water absorbent, process for producing the same, and absorbent article containing the same |
| JP2918808B2 (ja) * | 1994-06-13 | 1999-07-12 | 株式会社日本触媒 | 吸収体および吸収性物品 |
| GB9413605D0 (en) * | 1994-07-06 | 1994-08-24 | American Colloid Co | Method of increasing the size and absorption under load of super-absorbent fine particles by impregnation with an aqueous acrylic monomer solution |
| KR100371649B1 (ko) * | 1994-08-12 | 2003-05-22 | 가오가부시끼가이샤 | 개선된초흡수성중합체의제조방법 |
| DE69632570T3 (de) † | 1995-07-07 | 2013-01-17 | Nippon Shokubai Co. Ltd. | Wasserabsorbierendes pulver und verfahren zur herstellung |
| JP2000342963A (ja) * | 1995-09-01 | 2000-12-12 | Nippon Shokubai Co Ltd | 吸収剤組成物およびその製造方法、並びに、吸収剤組成物を含む吸収物品 |
| JP3335843B2 (ja) * | 1995-09-01 | 2002-10-21 | 株式会社日本触媒 | 吸収剤組成物および吸収体、並びに、吸収体を含む吸収物品 |
| US5804318A (en) * | 1995-10-26 | 1998-09-08 | Corvita Corporation | Lubricious hydrogel surface modification |
| EP0882502B1 (en) * | 1996-08-07 | 2007-04-11 | Nippon Shokubai Co., Ltd. | Water-absorbent and process for preparing the same |
| ID19116A (id) * | 1996-10-15 | 1998-06-18 | Nippon Catalytic Chem Ind | Bahan pengabsorpsi air dan proses produksinya |
| US6228930B1 (en) | 1997-06-18 | 2001-05-08 | Nippon Shokubai Co., Ltd. | Water-absorbent resin granule-containing composition and production process for water-absorbent resin granule |
| JPH11263850A (ja) * | 1997-12-02 | 1999-09-28 | Nippon Shokubai Co Ltd | 吸水剤およびその製造方法とその用途 |
| US6254990B1 (en) * | 1998-02-18 | 2001-07-03 | Nippon Shokubai Co., Ltd. | Surface-crosslinking process for water-absorbent resin |
| JP3389130B2 (ja) | 1998-02-18 | 2003-03-24 | 株式会社日本触媒 | 吸水性樹脂の表面架橋方法 |
| US6444744B1 (en) | 1998-03-11 | 2002-09-03 | Nippon Shokubai Co., Ltd. | Hydrophilic resin, absorbent article, and acrylic acid for polymerization |
| US6103785A (en) * | 1998-03-26 | 2000-08-15 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and its production process and use |
| DE19909653A1 (de) * | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| EP1130045B2 (en) | 2000-02-29 | 2015-10-28 | Nippon Shokubai Co., Ltd. | Process for producing a water-absorbent resin powder |
| US6617489B2 (en) | 2000-05-09 | 2003-09-09 | Nippon Shokubai Co., Ltd. | Absorbent, absorbing product based thereon, and water-absorbing resin |
| US6720389B2 (en) | 2000-09-20 | 2004-04-13 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process therefor |
| US7595428B2 (en) * | 2000-11-22 | 2009-09-29 | Nippon Shokubai Co., Ltd. | Water-absorbing agent composition and method for production thereof, absorptive article and absorbing material |
| US20030065296A1 (en) * | 2001-02-26 | 2003-04-03 | Kaiser Thomas A. | Absorbent material of water absorbent polymer, thermoplastic polymer, and water and method for making same |
| US7009010B2 (en) | 2001-12-19 | 2006-03-07 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process therefor |
| CN1831019B (zh) | 2001-12-19 | 2010-05-12 | 株式会社日本触媒 | 吸水性树脂及其制备方法 |
| MXPA04005565A (es) * | 2002-06-06 | 2004-12-06 | Nippon Catalytic Chem Ind | Composicion de agente de absorcion de agua y metodo para la produccion de la misma y material de absorcion y articulo absorbente. |
| JP3917052B2 (ja) * | 2002-10-16 | 2007-05-23 | 信和化工株式会社 | コポリマー、これを用いた吸着剤又は濃縮媒体、固相マイクロ抽出用注射針 |
| US7193006B2 (en) | 2002-12-06 | 2007-03-20 | Nippon Shokubai Co., Ltd. | Process for continuous production of water-absorbent resin product |
| EP1592750B1 (en) | 2003-02-10 | 2013-11-13 | Nippon Shokubai Co., Ltd. | Particulate water absorbent containing water absorbent resin as a main component |
| US7169843B2 (en) | 2003-04-25 | 2007-01-30 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
| DE10334286B4 (de) * | 2003-07-25 | 2006-01-05 | Stockhausen Gmbh | Pulverförmige,wasserabsorbierende Polymere mit mittels thermoplastischen Klebstoffen gebundenen Feinteilchen, Verfahren zu deren Herstellung sowie diese beinhaltende chemische Produkte und Verbunde |
| DE10334584A1 (de) * | 2003-07-28 | 2005-02-24 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit bicyclischen Amidacetalen |
| CN1274754C (zh) * | 2003-09-09 | 2006-09-13 | 青岛科技大学高分子科学与工程学院 | 遇水崩解型环境友好高分子共混材料及其制取方法 |
| US7173086B2 (en) * | 2003-10-31 | 2007-02-06 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
| AU2005210411B2 (en) * | 2004-02-05 | 2008-01-31 | Nippon Shokubai Co., Ltd. | Particulate water absorbing agent and method for production thereof, and water absorbing article |
| DE602004029569D1 (de) * | 2004-07-20 | 2010-11-25 | Procter & Gamble | Oberflächlich vernetzte superabsorbierende Partikeln und Verfahren zu ihrer Herstellung |
| US8080705B2 (en) * | 2004-07-28 | 2011-12-20 | The Procter & Gamble Company | Superabsorbent polymers comprising direct covalent bonds between polymer chain segments and method of making them |
| CN101010364B (zh) * | 2004-09-02 | 2011-07-27 | 株式会社日本触媒 | 吸水性材料、用于表面交联的吸水性树脂的生产方法以及用于吸水性材料的评价方法 |
| US20060128827A1 (en) * | 2004-12-10 | 2006-06-15 | The Procter & Gamble Company | Absorbent members comprising modified water absorbent resin for use in diapers |
| WO2006062258A2 (en) * | 2004-12-10 | 2006-06-15 | Nippon Shokubai Co., Ltd. | Method for production of modified water absorbent resin |
| JP5022226B2 (ja) * | 2004-12-10 | 2012-09-12 | 株式会社日本触媒 | 吸水性樹脂の表面処理方法 |
| EP1669394A1 (en) * | 2004-12-10 | 2006-06-14 | The Procter & Gamble Company | Superabsorbent polymer particles with improved surface cross-linking and hydrophilicity and method of making them |
| TWI344469B (en) | 2005-04-07 | 2011-07-01 | Nippon Catalytic Chem Ind | Polyacrylic acid (salt) water-absorbent resin, production process thereof, and acrylic acid used in polymerization for production of water-absorbent resin |
| US8481664B2 (en) | 2005-04-12 | 2013-07-09 | Nippon Shokubai Co., Ltd. | Particulate water absorbing agent including polyacrylic acid (polyacrylate) based water absorbing resin as a principal component, method for production thereof, water-absorbent core and absorbing article in which the particulate water absorbing agent is used |
| JP2007077366A (ja) * | 2005-09-16 | 2007-03-29 | Procter & Gamble Co | 吸水剤の製法 |
| TW200712065A (en) * | 2005-09-16 | 2007-04-01 | Nippon Catalytic Chem Ind | Method for production of water absorbing agent |
| JP2007099845A (ja) * | 2005-09-30 | 2007-04-19 | Procter & Gamble Co | 水性液吸収剤およびその製法 |
| US7812082B2 (en) * | 2005-12-12 | 2010-10-12 | Evonik Stockhausen, Llc | Thermoplastic coated superabsorbent polymer compositions |
| TWI394789B (zh) | 2005-12-22 | 2013-05-01 | Nippon Catalytic Chem Ind | 吸水性樹脂組成物及其製造方法、吸收性物品 |
| EP1837348B9 (en) | 2006-03-24 | 2020-01-08 | Nippon Shokubai Co.,Ltd. | Water-absorbing resin and method for manufacturing the same |
| DE602007003397D1 (de) | 2006-03-29 | 2010-01-07 | Nippon Catalytic Chem Ind | Verfahren zur Herstellung von wasserabsorbierendem Polyacrylsäure (Salz)-Harz |
| MX2008013041A (es) * | 2006-04-10 | 2008-10-17 | Procter & Gamble | Un miembro absorbente que comprende una resina absorbente de agua modificada. |
| CN101589066B (zh) | 2007-01-24 | 2013-07-03 | 株式会社日本触媒 | 粒子状吸水性聚合物及其制造方法 |
| JP5669354B2 (ja) | 2007-02-05 | 2015-02-12 | 株式会社日本触媒 | 粒子状吸水剤およびその製造方法 |
| EP2121049B1 (en) | 2007-02-22 | 2016-03-30 | The Procter and Gamble Company | Method of surface treating particulate material using electromagnetic radiation |
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| US9138505B2 (en) | 2009-08-27 | 2015-09-22 | Nippon Shokubai Co., Ltd. | Polyacrylic acid (salt)-type water absorbent resin and method for producing of same |
| US8802800B2 (en) | 2009-08-28 | 2014-08-12 | Nippon Shokubai Co., Ltd. | Production method for water-absorbent resin |
| EP2484439B1 (en) | 2009-09-29 | 2022-12-14 | Nippon Shokubai Co., Ltd. | Particulate water absorbent and process for production thereof |
| EP2484702B2 (en) | 2009-09-30 | 2021-11-10 | Nippon Shokubai Co., Ltd. | Polyacrylic acid salt-based water absorbent resin and method for producing same |
| WO2011090129A1 (ja) | 2010-01-20 | 2011-07-28 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| EP2527391B1 (en) | 2010-01-20 | 2023-08-09 | Nippon Shokubai Co., Ltd. | Method for producing water absorbent resin |
| WO2011099586A1 (ja) | 2010-02-10 | 2011-08-18 | 株式会社日本触媒 | 吸水性樹脂粉末の製造方法 |
| JP5658229B2 (ja) | 2010-03-08 | 2015-01-21 | 株式会社日本触媒 | 粒子状含水ゲル状架橋重合体の乾燥方法 |
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| JP6979487B1 (ja) * | 2020-07-13 | 2021-12-15 | 長瀬産業株式会社 | 吸水性樹脂架橋剤組成物 |
| US12583980B2 (en) | 2020-10-29 | 2026-03-24 | Lg Chem, Ltd. | Preparation method of super absorbent polymer |
| WO2022108430A1 (ko) * | 2020-11-18 | 2022-05-27 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4061846A (en) * | 1974-03-13 | 1977-12-06 | The Dow Chemical Company | Flexible water swellable crosslinked polyacrylate film |
| JPS60163956A (ja) * | 1984-02-04 | 1985-08-26 | Arakawa Chem Ind Co Ltd | 吸水性樹脂の製法 |
| US4666975A (en) * | 1984-03-05 | 1987-05-19 | Kao Corporation | Absorptive material |
| US4880868A (en) * | 1986-10-06 | 1989-11-14 | Arco Chemical Technology, Inc. | Extended shelf life water-absorbing composition which facilitates fiber formation |
| JPS63118308A (ja) * | 1986-11-06 | 1988-05-23 | Nippon Synthetic Chem Ind Co Ltd:The | 高吸水性樹脂の製造法 |
| ES2039640T3 (es) * | 1987-10-29 | 1993-10-01 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Un metodo de tratamiento de la superficie de una resina absorbente de agua. |
| KR910008293B1 (ko) * | 1988-05-13 | 1991-10-12 | 주식회사 럭키 | 흡수 속도가 우수한 고흡수성 수지의 제조방법 |
| JPH02132103A (ja) * | 1988-11-11 | 1990-05-21 | Idemitsu Petrochem Co Ltd | ポリアクリル酸アルカリ金属塩の製造方法 |
| SG55143A1 (en) * | 1990-04-02 | 1998-12-21 | Procter & Gamble | Particulate absorbent polymeric compositions containing interparticles crosslinked aggregates |
| US5164459A (en) * | 1990-04-02 | 1992-11-17 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for treating the surface of an absorbent resin |
| GB9107952D0 (en) * | 1991-04-15 | 1991-05-29 | Dow Rheinmuenster | Surface crosslinked and surfactant coated absorbent resin particles and method of preparation |
-
1992
- 1992-12-16 JP JP4336392A patent/JP2675729B2/ja not_active Expired - Fee Related
-
1993
- 1993-12-15 US US08/167,077 patent/US5422405A/en not_active Expired - Lifetime
- 1993-12-16 DE DE69314451T patent/DE69314451T2/de not_active Expired - Lifetime
- 1993-12-16 EP EP93310168A patent/EP0605150B1/en not_active Expired - Lifetime
- 1993-12-16 KR KR1019930027967A patent/KR0137347B1/ko not_active Expired - Lifetime
- 1993-12-16 ES ES93310168T patent/ES2106984T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2675729B2 (ja) | 1997-11-12 |
| DE69314451T2 (de) | 1998-05-20 |
| EP0605150A1 (en) | 1994-07-06 |
| EP0605150B1 (en) | 1997-10-08 |
| KR940014468A (ko) | 1994-07-18 |
| JPH06184320A (ja) | 1994-07-05 |
| DE69314451D1 (de) | 1997-11-13 |
| KR0137347B1 (ko) | 1998-04-27 |
| US5422405A (en) | 1995-06-06 |
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