ES2106984T3 - Metodo para la produccion de una resina absorbente. - Google Patents

Metodo para la produccion de una resina absorbente.

Info

Publication number
ES2106984T3
ES2106984T3 ES93310168T ES93310168T ES2106984T3 ES 2106984 T3 ES2106984 T3 ES 2106984T3 ES 93310168 T ES93310168 T ES 93310168T ES 93310168 T ES93310168 T ES 93310168T ES 2106984 T3 ES2106984 T3 ES 2106984T3
Authority
ES
Spain
Prior art keywords
absorbent resin
carboxyl group
less
production
cal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93310168T
Other languages
English (en)
Inventor
Yorimichi Dairoku
Kinya Nagasuna
Kazutaka Yano
Toru Yanase
Yoshihiko Masuda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Application granted granted Critical
Publication of ES2106984T3 publication Critical patent/ES2106984T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/243Two or more independent types of crosslinking for one or more polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04Acids, Metal salts or ammonium salts thereof
    • C08F20/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • A61L15/60Liquid-swellable gel-forming materials, e.g. super-absorbents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/14Esterification
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00Characterised by the use of unspecified polymers
    • C08J2300/14Water soluble or water swellable polymers, e.g. aqueous gels

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Hematology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

SE PREVE UN METODO PARA LA PRODUCCION DE UNA RESINA ABSORBENTE QUE MANTIENE UN ALTO NIVEL DE CAPACIDAD DE ABSORCION SIN CARGA, UNA DE LAS PROPIEDADES FISICAS BASICAS DE UNA RESINA ABSORBENTE, Y MANTIENE UNA EXCELENTE CAPACIDAD DE ABSORCION BAJO CARGA. EL PRODUCTO SE CONSIGUE MEZCLANDO UNA RESINA ABSORBENTE, COMO PUEDE SER UNA QUE POSEE UN GRUPO CARBOXILO, CON UN PRIMER AGENTE DE RETICULACION QUE POSEE UN PARAMETRO DE SOLUBILIDAD (VALOR SP) NO MENOR QUE 12.5 (CAL/CM3)1/2 Y QUE PRESENTA UNA REACTIVIDAD CON EL GRUPO CARBOXILO, UN SEGUNDO AGENTE DE RETICULACION QUE POSEA UN PARAMETRO DE SOLUBILIDAD (VALOR SP) MENOR QUE 12.5 (CAL/CM3)1/2 Y QUE PRESENTE REACTIVIDAD CON EL GRUPO CARBOXILO, Y SOMETIENDO DESPUES LA MEZCLA RESULTANTE A UN TRATAMIENTO TERMICO A UNA TEMPERATURA NO MENOR DE 160
ES93310168T 1992-12-16 1993-12-16 Metodo para la produccion de una resina absorbente. Expired - Lifetime ES2106984T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4336392A JP2675729B2 (ja) 1992-12-16 1992-12-16 吸水性樹脂の製造方法

Publications (1)

Publication Number Publication Date
ES2106984T3 true ES2106984T3 (es) 1997-11-16

Family

ID=18298665

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93310168T Expired - Lifetime ES2106984T3 (es) 1992-12-16 1993-12-16 Metodo para la produccion de una resina absorbente.

Country Status (6)

Country Link
US (1) US5422405A (es)
EP (1) EP0605150B1 (es)
JP (1) JP2675729B2 (es)
KR (1) KR0137347B1 (es)
DE (1) DE69314451T2 (es)
ES (1) ES2106984T3 (es)

Families Citing this family (89)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4333056C2 (de) * 1993-09-29 1998-07-02 Stockhausen Chem Fab Gmbh Pulverförmige, wäßrige Flüssigkeiten absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Absorptionsmittel
US5610208A (en) * 1994-02-17 1997-03-11 Nippon Shokubai Co., Ltd. Water-absorbent agent, method for production thereof, and water-absorbent composition
US5830543A (en) 1994-05-30 1998-11-03 Nippon Shokubai Co., Ltd. Gelling material for aqueous fluids
US5624967A (en) 1994-06-08 1997-04-29 Nippon Shokubai Co., Ltd. Water-absorbing resin and process for producing same
WO1995034377A1 (en) * 1994-06-13 1995-12-21 Nippon Shokubai Co., Ltd. Water absorbent, process for producing the same, and absorbent article containing the same
JP2918808B2 (ja) * 1994-06-13 1999-07-12 株式会社日本触媒 吸収体および吸収性物品
GB9413605D0 (en) * 1994-07-06 1994-08-24 American Colloid Co Method of increasing the size and absorption under load of super-absorbent fine particles by impregnation with an aqueous acrylic monomer solution
KR100371649B1 (ko) * 1994-08-12 2003-05-22 가오가부시끼가이샤 개선된초흡수성중합체의제조방법
DE69632570T3 (de) 1995-07-07 2013-01-17 Nippon Shokubai Co. Ltd. Wasserabsorbierendes pulver und verfahren zur herstellung
JP2000342963A (ja) * 1995-09-01 2000-12-12 Nippon Shokubai Co Ltd 吸収剤組成物およびその製造方法、並びに、吸収剤組成物を含む吸収物品
JP3335843B2 (ja) * 1995-09-01 2002-10-21 株式会社日本触媒 吸収剤組成物および吸収体、並びに、吸収体を含む吸収物品
US5804318A (en) * 1995-10-26 1998-09-08 Corvita Corporation Lubricious hydrogel surface modification
EP0882502B1 (en) * 1996-08-07 2007-04-11 Nippon Shokubai Co., Ltd. Water-absorbent and process for preparing the same
ID19116A (id) * 1996-10-15 1998-06-18 Nippon Catalytic Chem Ind Bahan pengabsorpsi air dan proses produksinya
US6228930B1 (en) 1997-06-18 2001-05-08 Nippon Shokubai Co., Ltd. Water-absorbent resin granule-containing composition and production process for water-absorbent resin granule
JPH11263850A (ja) * 1997-12-02 1999-09-28 Nippon Shokubai Co Ltd 吸水剤およびその製造方法とその用途
US6254990B1 (en) * 1998-02-18 2001-07-03 Nippon Shokubai Co., Ltd. Surface-crosslinking process for water-absorbent resin
JP3389130B2 (ja) 1998-02-18 2003-03-24 株式会社日本触媒 吸水性樹脂の表面架橋方法
US6444744B1 (en) 1998-03-11 2002-09-03 Nippon Shokubai Co., Ltd. Hydrophilic resin, absorbent article, and acrylic acid for polymerization
US6103785A (en) * 1998-03-26 2000-08-15 Nippon Shokubai Co., Ltd. Water-absorbing agent and its production process and use
DE19909653A1 (de) * 1999-03-05 2000-09-07 Stockhausen Chem Fab Gmbh Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung
EP1130045B2 (en) 2000-02-29 2015-10-28 Nippon Shokubai Co., Ltd. Process for producing a water-absorbent resin powder
US6617489B2 (en) 2000-05-09 2003-09-09 Nippon Shokubai Co., Ltd. Absorbent, absorbing product based thereon, and water-absorbing resin
US6720389B2 (en) 2000-09-20 2004-04-13 Nippon Shokubai Co., Ltd. Water-absorbent resin and production process therefor
US7595428B2 (en) * 2000-11-22 2009-09-29 Nippon Shokubai Co., Ltd. Water-absorbing agent composition and method for production thereof, absorptive article and absorbing material
US20030065296A1 (en) * 2001-02-26 2003-04-03 Kaiser Thomas A. Absorbent material of water absorbent polymer, thermoplastic polymer, and water and method for making same
US7009010B2 (en) 2001-12-19 2006-03-07 Nippon Shokubai Co., Ltd. Water-absorbent resin and production process therefor
CN1831019B (zh) 2001-12-19 2010-05-12 株式会社日本触媒 吸水性树脂及其制备方法
MXPA04005565A (es) * 2002-06-06 2004-12-06 Nippon Catalytic Chem Ind Composicion de agente de absorcion de agua y metodo para la produccion de la misma y material de absorcion y articulo absorbente.
JP3917052B2 (ja) * 2002-10-16 2007-05-23 信和化工株式会社 コポリマー、これを用いた吸着剤又は濃縮媒体、固相マイクロ抽出用注射針
US7193006B2 (en) 2002-12-06 2007-03-20 Nippon Shokubai Co., Ltd. Process for continuous production of water-absorbent resin product
EP1592750B1 (en) 2003-02-10 2013-11-13 Nippon Shokubai Co., Ltd. Particulate water absorbent containing water absorbent resin as a main component
US7169843B2 (en) 2003-04-25 2007-01-30 Stockhausen, Inc. Superabsorbent polymer with high permeability
DE10334286B4 (de) * 2003-07-25 2006-01-05 Stockhausen Gmbh Pulverförmige,wasserabsorbierende Polymere mit mittels thermoplastischen Klebstoffen gebundenen Feinteilchen, Verfahren zu deren Herstellung sowie diese beinhaltende chemische Produkte und Verbunde
DE10334584A1 (de) * 2003-07-28 2005-02-24 Basf Ag Verfahren zur Nachvernetzung von Hydrogelen mit bicyclischen Amidacetalen
CN1274754C (zh) * 2003-09-09 2006-09-13 青岛科技大学高分子科学与工程学院 遇水崩解型环境友好高分子共混材料及其制取方法
US7173086B2 (en) * 2003-10-31 2007-02-06 Stockhausen, Inc. Superabsorbent polymer with high permeability
AU2005210411B2 (en) * 2004-02-05 2008-01-31 Nippon Shokubai Co., Ltd. Particulate water absorbing agent and method for production thereof, and water absorbing article
DE602004029569D1 (de) * 2004-07-20 2010-11-25 Procter & Gamble Oberflächlich vernetzte superabsorbierende Partikeln und Verfahren zu ihrer Herstellung
US8080705B2 (en) * 2004-07-28 2011-12-20 The Procter & Gamble Company Superabsorbent polymers comprising direct covalent bonds between polymer chain segments and method of making them
CN101010364B (zh) * 2004-09-02 2011-07-27 株式会社日本触媒 吸水性材料、用于表面交联的吸水性树脂的生产方法以及用于吸水性材料的评价方法
US20060128827A1 (en) * 2004-12-10 2006-06-15 The Procter & Gamble Company Absorbent members comprising modified water absorbent resin for use in diapers
WO2006062258A2 (en) * 2004-12-10 2006-06-15 Nippon Shokubai Co., Ltd. Method for production of modified water absorbent resin
JP5022226B2 (ja) * 2004-12-10 2012-09-12 株式会社日本触媒 吸水性樹脂の表面処理方法
EP1669394A1 (en) * 2004-12-10 2006-06-14 The Procter & Gamble Company Superabsorbent polymer particles with improved surface cross-linking and hydrophilicity and method of making them
TWI344469B (en) 2005-04-07 2011-07-01 Nippon Catalytic Chem Ind Polyacrylic acid (salt) water-absorbent resin, production process thereof, and acrylic acid used in polymerization for production of water-absorbent resin
US8481664B2 (en) 2005-04-12 2013-07-09 Nippon Shokubai Co., Ltd. Particulate water absorbing agent including polyacrylic acid (polyacrylate) based water absorbing resin as a principal component, method for production thereof, water-absorbent core and absorbing article in which the particulate water absorbing agent is used
JP2007077366A (ja) * 2005-09-16 2007-03-29 Procter & Gamble Co 吸水剤の製法
TW200712065A (en) * 2005-09-16 2007-04-01 Nippon Catalytic Chem Ind Method for production of water absorbing agent
JP2007099845A (ja) * 2005-09-30 2007-04-19 Procter & Gamble Co 水性液吸収剤およびその製法
US7812082B2 (en) * 2005-12-12 2010-10-12 Evonik Stockhausen, Llc Thermoplastic coated superabsorbent polymer compositions
TWI394789B (zh) 2005-12-22 2013-05-01 Nippon Catalytic Chem Ind 吸水性樹脂組成物及其製造方法、吸收性物品
EP1837348B9 (en) 2006-03-24 2020-01-08 Nippon Shokubai Co.,Ltd. Water-absorbing resin and method for manufacturing the same
DE602007003397D1 (de) 2006-03-29 2010-01-07 Nippon Catalytic Chem Ind Verfahren zur Herstellung von wasserabsorbierendem Polyacrylsäure (Salz)-Harz
MX2008013041A (es) * 2006-04-10 2008-10-17 Procter & Gamble Un miembro absorbente que comprende una resina absorbente de agua modificada.
CN101589066B (zh) 2007-01-24 2013-07-03 株式会社日本触媒 粒子状吸水性聚合物及其制造方法
JP5669354B2 (ja) 2007-02-05 2015-02-12 株式会社日本触媒 粒子状吸水剤およびその製造方法
EP2121049B1 (en) 2007-02-22 2016-03-30 The Procter and Gamble Company Method of surface treating particulate material using electromagnetic radiation
JP5558096B2 (ja) * 2007-03-01 2014-07-23 株式会社日本触媒 吸水性樹脂を主成分とする粒子状吸水剤
SA08290402B1 (ar) 2007-07-04 2014-05-22 نيبون شوكوباي كو. ، ليمتد عامل دقائقي ماص للماء وطريقة لتصنيعه
SA08290542B1 (ar) 2007-08-28 2012-11-14 نيبون شوكوباي كو. ، ليمتد طريقة لإنتاج راتنج ماص للماء
SA08290556B1 (ar) * 2007-09-07 2012-05-16 نيبون شوكوباي كو. ، ليمتد طريقة لربط راتنجات ممتصة للماء
JP5448699B2 (ja) * 2008-10-14 2014-03-19 Sdpグローバル株式会社 吸収性樹脂粒子、この製造方法、これを含む吸収体及び吸収性物品
JP5615801B2 (ja) 2009-03-04 2014-10-29 株式会社日本触媒 吸水性樹脂の製造方法
CN102414160B (zh) 2009-05-15 2014-06-04 株式会社日本触媒 制备(甲基)丙烯酸的方法和结晶系统
RU2523796C2 (ru) 2009-05-15 2014-07-27 Ниппон Сокубаи Ко., Лтд. Способ получения (мет)акриловой кислоты
CN102428065B (zh) 2009-05-15 2014-02-26 株式会社日本触媒 制备(甲基)丙烯酸的方法
US9138505B2 (en) 2009-08-27 2015-09-22 Nippon Shokubai Co., Ltd. Polyacrylic acid (salt)-type water absorbent resin and method for producing of same
US8802800B2 (en) 2009-08-28 2014-08-12 Nippon Shokubai Co., Ltd. Production method for water-absorbent resin
EP2484439B1 (en) 2009-09-29 2022-12-14 Nippon Shokubai Co., Ltd. Particulate water absorbent and process for production thereof
EP2484702B2 (en) 2009-09-30 2021-11-10 Nippon Shokubai Co., Ltd. Polyacrylic acid salt-based water absorbent resin and method for producing same
WO2011090129A1 (ja) 2010-01-20 2011-07-28 株式会社日本触媒 吸水性樹脂の製造方法
EP2527391B1 (en) 2010-01-20 2023-08-09 Nippon Shokubai Co., Ltd. Method for producing water absorbent resin
WO2011099586A1 (ja) 2010-02-10 2011-08-18 株式会社日本触媒 吸水性樹脂粉末の製造方法
JP5658229B2 (ja) 2010-03-08 2015-01-21 株式会社日本触媒 粒子状含水ゲル状架橋重合体の乾燥方法
JP5554268B2 (ja) * 2010-03-11 2014-07-23 株式会社クラレ 架橋性組成物、架橋物及びその製造方法、並びに多層構造体
JP5605862B2 (ja) 2010-03-12 2014-10-15 株式会社日本触媒 吸水性樹脂の製造方法
WO2011115221A1 (ja) 2010-03-17 2011-09-22 株式会社日本触媒 吸水性樹脂の製造方法
JP5806209B2 (ja) 2010-04-26 2015-11-10 株式会社日本触媒 ポリアクリル酸(塩)系吸水性樹脂及びその製造方法
JP5764122B2 (ja) 2010-04-26 2015-08-12 株式会社日本触媒 ポリアクリル酸(塩)、ポリアクリル酸(塩)系吸水性樹脂及びその製造方法
WO2014021388A1 (ja) * 2012-08-01 2014-02-06 株式会社日本触媒 ポリアクリル酸(塩)系吸水性樹脂粉末を用いた吸水剤及びその製造方法
JP5766344B1 (ja) 2014-07-11 2015-08-19 住友精化株式会社 吸水性樹脂及び吸収性物品
KR102011926B1 (ko) * 2014-12-22 2019-08-20 주식회사 엘지화학 고흡수성 수지 및 이의 제조 방법
KR102162500B1 (ko) * 2016-12-13 2020-10-06 주식회사 엘지화학 고흡수성 수지 및 이의 제조 방법
KR102094453B1 (ko) 2016-12-23 2020-03-27 주식회사 엘지화학 고흡수성 수지 및 이의 제조 방법
KR102489568B1 (ko) 2017-11-07 2023-01-16 주식회사 엘지화학 고흡수성 수지 및 이의 제조 방법
JP6979487B1 (ja) * 2020-07-13 2021-12-15 長瀬産業株式会社 吸水性樹脂架橋剤組成物
US12583980B2 (en) 2020-10-29 2026-03-24 Lg Chem, Ltd. Preparation method of super absorbent polymer
WO2022108430A1 (ko) * 2020-11-18 2022-05-27 주식회사 엘지화학 고흡수성 수지의 제조 방법

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4061846A (en) * 1974-03-13 1977-12-06 The Dow Chemical Company Flexible water swellable crosslinked polyacrylate film
JPS60163956A (ja) * 1984-02-04 1985-08-26 Arakawa Chem Ind Co Ltd 吸水性樹脂の製法
US4666975A (en) * 1984-03-05 1987-05-19 Kao Corporation Absorptive material
US4880868A (en) * 1986-10-06 1989-11-14 Arco Chemical Technology, Inc. Extended shelf life water-absorbing composition which facilitates fiber formation
JPS63118308A (ja) * 1986-11-06 1988-05-23 Nippon Synthetic Chem Ind Co Ltd:The 高吸水性樹脂の製造法
ES2039640T3 (es) * 1987-10-29 1993-10-01 Nippon Shokubai Kagaku Kogyo Co., Ltd Un metodo de tratamiento de la superficie de una resina absorbente de agua.
KR910008293B1 (ko) * 1988-05-13 1991-10-12 주식회사 럭키 흡수 속도가 우수한 고흡수성 수지의 제조방법
JPH02132103A (ja) * 1988-11-11 1990-05-21 Idemitsu Petrochem Co Ltd ポリアクリル酸アルカリ金属塩の製造方法
SG55143A1 (en) * 1990-04-02 1998-12-21 Procter & Gamble Particulate absorbent polymeric compositions containing interparticles crosslinked aggregates
US5164459A (en) * 1990-04-02 1992-11-17 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for treating the surface of an absorbent resin
GB9107952D0 (en) * 1991-04-15 1991-05-29 Dow Rheinmuenster Surface crosslinked and surfactant coated absorbent resin particles and method of preparation

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JP2675729B2 (ja) 1997-11-12
DE69314451T2 (de) 1998-05-20
EP0605150A1 (en) 1994-07-06
EP0605150B1 (en) 1997-10-08
KR940014468A (ko) 1994-07-18
JPH06184320A (ja) 1994-07-05
DE69314451D1 (de) 1997-11-13
KR0137347B1 (ko) 1998-04-27
US5422405A (en) 1995-06-06

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