ES2108295T3 - Procedimiento mejorado para la preparacion de acido 3-pentenoico a partir de butadieno. - Google Patents

Procedimiento mejorado para la preparacion de acido 3-pentenoico a partir de butadieno.

Info

Publication number
ES2108295T3
ES2108295T3 ES93920052T ES93920052T ES2108295T3 ES 2108295 T3 ES2108295 T3 ES 2108295T3 ES 93920052 T ES93920052 T ES 93920052T ES 93920052 T ES93920052 T ES 93920052T ES 2108295 T3 ES2108295 T3 ES 2108295T3
Authority
ES
Spain
Prior art keywords
butadiene
preparation
pentenoic acid
improved procedure
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93920052T
Other languages
English (en)
Inventor
Patrick Michael Burke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of ES2108295T3 publication Critical patent/ES2108295T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215Sulfur-containing compounds
    • B01J31/0225Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08Ion-exchange resins
    • B01J31/10Ion-exchange resins sulfonated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2291Olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PREPARACION DE ACIDO 3-PENTENOICO REACCIONADO BUTADIENO Y MONOXIDO DE CARBONO USANDO UN CATALIZADOR DE RODIO Y UN CATALIZADOR DE ACIDO SULFONICO EN AGUA Y UN SOLVENTE DE ACIDO CARBOXILICO.
ES93920052T 1992-08-24 1993-08-18 Procedimiento mejorado para la preparacion de acido 3-pentenoico a partir de butadieno. Expired - Lifetime ES2108295T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/933,942 US5250726A (en) 1992-08-24 1992-08-24 Process for the preparation of 3-pentenoic acid from butadiene

Publications (1)

Publication Number Publication Date
ES2108295T3 true ES2108295T3 (es) 1997-12-16

Family

ID=25464706

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93920052T Expired - Lifetime ES2108295T3 (es) 1992-08-24 1993-08-18 Procedimiento mejorado para la preparacion de acido 3-pentenoico a partir de butadieno.

Country Status (8)

Country Link
US (1) US5250726A (es)
EP (1) EP0655993B1 (es)
JP (1) JPH08500363A (es)
KR (1) KR950702954A (es)
CA (1) CA2142823A1 (es)
DE (1) DE69315080T2 (es)
ES (1) ES2108295T3 (es)
WO (1) WO1994004479A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996020154A1 (en) * 1994-12-28 1996-07-04 Exxon Chemical Patents Inc. Production of trialkylacetic acids using a solid cationic resin catalyst system
TW513401B (en) * 1997-02-25 2002-12-11 Shell Internattonale Res Mij B Process for the manufacture of carboxylic acids
AU726899B2 (en) * 1997-02-25 2000-11-23 Shell Internationale Research Maatschappij B.V. Process for the manufacture of carboxylic acids
WO1998038149A1 (en) * 1997-02-25 1998-09-03 Shell Internationale Research Maatschappij B.V. Process for the manufacture of carboxylic acids
US5962680A (en) * 1997-04-15 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactams
US5886236A (en) * 1997-04-15 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Process for producing aldehyde acid salts
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions
EP0989969B1 (en) * 1997-06-20 2002-04-10 Resolution Research Nederland B.V. Process for the manufacture of carboxylic acids
US6133477A (en) * 1997-07-23 2000-10-17 E. I. Du Pont De Nemours And Company Preparation of 3-pentenoic acid
US5962732A (en) * 1998-12-17 1999-10-05 E. I. Du Pont De Nemours And Company Process for the preparation of 3-pentenoic acid from butadiene using a nickel catalyst
US6437192B1 (en) 2000-11-17 2002-08-20 E. I. Du Pont De Nmeours And Company Hydroformylation of conjugated dienes to alkenals using phosphonite ligands
US6362354B1 (en) 2000-11-17 2002-03-26 E. I. Du Pont De Nemours And Company Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same
US20040249229A1 (en) * 2003-06-06 2004-12-09 Gee Jeffery C. Isomerization of olefins with carboxylic acid

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3816488A (en) * 1968-08-15 1974-06-11 Monsanto Co Increasing the selectivity and yield in the production of carboxylic acids
US4690912A (en) * 1968-08-15 1987-09-01 Monsanto Company Rhodium-containing carbonylation catalysts with halogen-containing promoter
DE3200990A1 (de) * 1982-01-15 1983-07-28 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von ungesaettigten alkoholen und/oder deren estern
US4622423A (en) * 1984-11-09 1986-11-11 E. I. Du Pont De Nemours And Company Hydrocarboxylation of butadiene to 3-pentenoic acid
US4788334A (en) * 1986-12-10 1988-11-29 E. I. Du Pont De Nemours And Company Acid accelerated hydrocarboxylation
US5145995A (en) * 1989-06-26 1992-09-08 E. I. Du Pont De Nemours And Company Process for the manufacture of 3-pentenoic acid
GB9026211D0 (en) * 1990-12-03 1991-01-16 Shell Int Research Carbonylation process

Also Published As

Publication number Publication date
KR950702954A (ko) 1995-08-23
EP0655993B1 (en) 1997-11-05
CA2142823A1 (en) 1994-03-03
JPH08500363A (ja) 1996-01-16
EP0655993A1 (en) 1995-06-07
DE69315080D1 (de) 1997-12-11
WO1994004479A1 (en) 1994-03-03
DE69315080T2 (de) 1998-05-20
US5250726A (en) 1993-10-05

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