ES2108429T3 - Procedimiento de carbonilacion. - Google Patents

Procedimiento de carbonilacion.

Info

Publication number
ES2108429T3
ES2108429T3 ES94907533T ES94907533T ES2108429T3 ES 2108429 T3 ES2108429 T3 ES 2108429T3 ES 94907533 T ES94907533 T ES 94907533T ES 94907533 T ES94907533 T ES 94907533T ES 2108429 T3 ES2108429 T3 ES 2108429T3
Authority
ES
Spain
Prior art keywords
sup
group
bivalent
independently represent
represent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94907533T
Other languages
English (en)
Inventor
Eit Drent
Dennis Humphrey Louis Pello
Melis Hasselaar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of ES2108429T3 publication Critical patent/ES2108429T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
    • B01J31/2433—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/248—Bridged ring systems, e.g. 9-phosphabicyclononane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
    • C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Steroid Compounds (AREA)

Abstract

EL INVENTO PROPORCIONA UN PROCESO PARA LA CARBONILACION DE COMPUESTOS NO SATURADOS ETILENICAMENTE POR REACCION CON MONOXIDO DE CARBONO Y UN CO-REACTIVO EN PRESENCIA DE UN SISTEMA CATALIZADOR NO ACIDICO SUSTANCIALMENTE BASADO EN UN COMPUESTO DE PALADIO Y UN LIGANDO BIDENTADO DE LA FORMULA (I): R{SUP,1}R{SUP,2}M{SUP,1}, RM{SUP,2},R{SUP,3}R{SUP,4} EN LA QUE M{SUP,1} Y M{SUP,2} INDEPENDIENTEMENTE REPRESENTAN UN ATOMO DE ANTIMONIO, ARSENICO O FOSFORO, R REPRESENTA UN GRUPO PUENTE ORGANICO, R{SUP,1}, R{SUP,2}, R{SUP,3} Y R{SUP,4} INDEPENDIENTEMENTE REPRESENTAN GRUPOS ALIFATICOS SUSTITUIDOS O NO SUSTITUIDOS, CON LA CONDICION DE QUE R{SUP,1} JUNTO CON R{SUP,2}, Y/O R{SUP,3} JUNTO CON R{SUP,4} REPRESENTEN UN GRUPO CICLICO BIVALENTE CON AL MENOS 5 ATOMOS ANILLO DE MODO QUE LAS DOS VALENCIAS LIBRES SEAN UNIDAS A M{SUP,1} O M{SUP,2}, RESPECTIVAMENTE. EN SUMA EL INVENTO PROPORCIONA COMPOSICIONES CATALIZADORAS QUE CONTIENEN: A) COMPUESTO DE PALADIO; B) UN LIGANDO BIDENTADO DE LA FORMULA (II): R{SUP,1}R{SUP,2}PRPR{SUP,3}R{SUP,4} EN LA QUE R ES UN GRUPO PUENTE ORGANICO BIVALENTE QUE CONTIENE DE 1 A 10 ATOMOS EN EL PUENTE Y R{SUP,1}, R{SUP,2}, R{SUP,3} Y R{SUP,4} INDEPENDIENTEMENTE REPRESENTAN GRUPOS ALIFATICOS SUSTITUIDOS O NO SUSTITUIDOS, CON LA CONDICION DE QUE R{SUP,1} JUNTO CON R{SUP,2} Y/O R{SUP,3} JUNTO CON R{SUP,4} REPRESENTEN UN GRUPO CICLICO BIVALENTE CON AL MENOS 6 ATOMOS ANILLO DE MODO QUE DOS VALENCIAS LIBRES SEAN UNIDAS AL ATOMO(S) DE FOSFORO Y C) UN COMPUESTO BASICO.
ES94907533T 1993-02-09 1994-02-07 Procedimiento de carbonilacion. Expired - Lifetime ES2108429T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP93200360 1993-02-09

Publications (1)

Publication Number Publication Date
ES2108429T3 true ES2108429T3 (es) 1997-12-16

Family

ID=8213626

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94907533T Expired - Lifetime ES2108429T3 (es) 1993-02-09 1994-02-07 Procedimiento de carbonilacion.

Country Status (9)

Country Link
US (1) US5436356A (es)
EP (1) EP0683764B1 (es)
JP (1) JP3827323B2 (es)
KR (1) KR100286535B1 (es)
CN (1) CN1041517C (es)
CA (1) CA2155574C (es)
DE (1) DE69405713T2 (es)
ES (1) ES2108429T3 (es)
WO (1) WO1994018154A1 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5719313A (en) * 1995-03-16 1998-02-17 Shell Oil Company Carbonylation catalyst system and a process for the carbonylation of acetylenically unsaturated compounds
US6103927A (en) * 1996-04-16 2000-08-15 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds
US6037506A (en) * 1998-09-18 2000-03-14 Shell Oil Company Hydroformylation process
TW524801B (en) * 1999-03-22 2003-03-21 Shell Int Research Process for the carbonylation of conjugated dienes
CN1252012C (zh) 2000-03-22 2006-04-19 国际壳牌研究有限公司 制备1,3－二醇的方法
IT1318712B1 (it) 2000-08-01 2003-08-27 Graziano Vignali Composizione colorante per materiali ceramici e relativo processo dicolorazione.
DE10048874A1 (de) 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
DE10228293A1 (de) 2001-07-28 2003-02-13 Basf Ag Verfahren zur Herstellung von Dialkylketonen
US7767864B2 (en) 2003-07-03 2010-08-03 Lucite International Uk Limited Process for the hydroformylation of ethylenically unsaturated compounds
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0411951D0 (en) * 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
US20110167841A1 (en) 2004-06-04 2011-07-14 Brasscorp Limited Compositions and methods for injection of sealants and/or drying agents into air conditioning and refrigeration systems
US7296423B2 (en) * 2004-06-04 2007-11-20 Brasscorp Limited Composition and methods for injection of sealants into air conditioning and refrigeration systems
WO2010028493A1 (en) * 2008-09-11 2010-03-18 Brasscorp Limited Compositions and methods for injection of sealants and/or drying agents into air conditioning and refrigeration systems
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
CA2626107C (en) 2005-11-17 2016-06-21 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
JP2010511600A (ja) * 2006-12-02 2010-04-15 ルーサイト インターナショナル ユーケー リミテッド 新規のカルボニル化配位子及びエチレン性不飽和化合物のカルボニル化におけるその使用
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
JP5813625B2 (ja) * 2009-04-23 2015-11-17 ヴイティーユー ホールディング ゲーエムベーハーＶｔｕ Ｈｏｌｄｉｎｇ Ｇｍｂｈ イオン性液体を脱水する方法
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1127965A (en) * 1965-11-26 1968-09-25 Shell Int Research Ditertiary phosphines and application thereof as catalyst components for alcohol production
US4172087A (en) * 1978-02-13 1979-10-23 Texaco Development Corporation Process for preparing unsaturated aliphatic esters from aliphatic dienes
GB2058074B (en) * 1979-08-23 1983-10-12 Secr Defence Palladium complexes
DE3175174D1 (en) * 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
DE3332018A1 (de) * 1983-09-06 1985-03-21 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von bernsteinsaeurediestern
GB2183631A (en) * 1985-11-27 1987-06-10 Shell Int Research Process for the preparation of oxo-alkanedioic acids or diesters thereof
GB2185740A (en) * 1986-01-27 1987-07-29 Shell Int Research Process for the preparation of ketones
KR880007426A (ko) * 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB9002521D0 (en) * 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
DE69210054T2 (de) * 1991-01-15 1996-12-12 Shell Int Research Carbonylierung von Olefinen

Also Published As

Publication number Publication date
DE69405713D1 (en) 1997-10-23
US5436356A (en) 1995-07-25
KR960700993A (ko) 1996-02-24
WO1994018154A1 (en) 1994-08-18
JP3827323B2 (ja) 2006-09-27
CN1041517C (zh) 1999-01-06
KR100286535B1 (ko) 2001-04-16
CA2155574A1 (en) 1994-08-18
EP0683764B1 (en) 1997-09-17
DE69405713T2 (de) 1998-01-08
CA2155574C (en) 2004-07-27
EP0683764A1 (en) 1995-11-29
JPH08506575A (ja) 1996-07-16
CN1117726A (zh) 1996-02-28

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