ES2109321T3 - Intermedios de sintesis que presentan un ciclo hexanico y sus procedimientos de preparacion. - Google Patents
Intermedios de sintesis que presentan un ciclo hexanico y sus procedimientos de preparacion.Info
- Publication number
- ES2109321T3 ES2109321T3 ES92400866T ES92400866T ES2109321T3 ES 2109321 T3 ES2109321 T3 ES 2109321T3 ES 92400866 T ES92400866 T ES 92400866T ES 92400866 T ES92400866 T ES 92400866T ES 2109321 T3 ES2109321 T3 ES 2109321T3
- Authority
- ES
- Spain
- Prior art keywords
- chain
- hydrogen
- group
- hexanic
- presenting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 239000000543 intermediate Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 150000002430 hydrocarbons Chemical group 0.000 abstract 3
- 150000002431 hydrogen Chemical group 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 125000004423 acyloxy group Chemical group 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003368 amide group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 125000001153 fluoro group Chemical group F* 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- -1 imido Chemical group 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 125000005392 carboxamide group Chemical group NC(=O)* 0.000 abstract 1
- 229910052798 chalcogen Inorganic materials 0.000 abstract 1
- 150000001787 chalcogens Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 125000002577 pseudohalo group Chemical group 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
- C07C45/512—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being a free hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C35/48—Halogenated derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
- C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
- C07C45/58—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/385—Saturated compounds containing a keto group being part of a ring
- C07C49/457—Saturated compounds containing a keto group being part of a ring containing halogen
- C07C49/463—Saturated compounds containing a keto group being part of a ring containing halogen a keto group being part of a six-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
- Epoxy Compounds (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A NUEVOS COMPUESTOS FLUORADOS HEXANICOS Y SU UTILIZACION EN SINTESIS INDUSTRIAL. ESTOS COMPUESTOS SE CARACTERIZAN POR EL HECHO DE QUE RESPONDEN A LA SIGUIENTE FORMULA GENERAL (II): EN LA QUE X''2, X''3 Y X''4 (QUE CORRESPONDEN UNO A UNO A X2, X3 Y X4 O X1, X2 Y X3 DE LA FORMULA (I) SEMEJANTES O DIFERENTES REPRESENTAN UN HALOGENO O UN SEUDOHALOGENO, PREFERENTEMENTE UN HALOGENO, VENTAJOSAMENTE EL CLORO Y EL FLUOR CON LA CONDICION DE QUE CUANDO R1 ES HIDROXILO, CIANO, AMIDO, IMIDO, ETOXILO, BENCILOXILO, CICLOHEXILO Y TERTIOBUTILO, TODOS LOS HALOGENOS NO PUEDE SER SIMULTANEAMENTE CLORO Y R4, R3 Y R5 SIMULTANEAMENTE IGUAL A H; EN LA QUE R1 REPRESENTA UN HIDROGENO, UNA CADENA HIDROCARBONADA TAL COMO POR EJEMPLO UNA CADENA ALCOHILA, UNA CADENA AROMATICA O UN GRUPO ALCOXILO, CARBONILO, CARBOXILO O ACILOXILO, VEASE HIDROXILO; EN LA QUE R4 REPRESENTA UN HIDROGENO, UN ATOMO DE FLUOR, UNA CADENA HIDROCARBONADA TAL COMO POR EJEMPLO UNA CADENA ALCOHILA, UNA CADENA AROMATICAO UN GRUPO CARBONILO, CARBOXILO, CARBOXAMIDA O UN RADICAL ENLAZADO AL CICLO HEXANICO POR UN CALCOGEN O POR ELEMENTO DE LA COLUMNA PREFERENTEMENTE DEL PRIMER PERIODO, TAL COMO UN GRUPO AMIDO, ALCOXILO O ACILOXILO; EN LA QUE LOS RADICALES R3 Y R5 DIFERENTES O PREFERENTEMENTE SEMEJANTES, REPRESENTAN UN ATOMO DE FLUOR, O PREFERENTEMENTE DE HIDROGENO, O TAMBIEN CADENAS HIDROCARBONADAS TALES COMO ESTAN DEFINIDAS ANTERIORMENTE PARA R4.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9104701A FR2675501B1 (fr) | 1991-04-17 | 1991-04-17 | Intermediaires de synthese presentant un cycle hexanique polyhalogene alcoolique et leurs procedes de preparation. |
| FR9104700A FR2675505B1 (fr) | 1991-04-17 | 1991-04-17 | Intermediaires de synthese presentant un cycle hexanique et leurs procedes de preparation. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2109321T3 true ES2109321T3 (es) | 1998-01-16 |
Family
ID=26228629
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92400866T Expired - Lifetime ES2109321T3 (es) | 1991-04-17 | 1992-03-27 | Intermedios de sintesis que presentan un ciclo hexanico y sus procedimientos de preparacion. |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US5424460A (es) |
| EP (1) | EP0511036B1 (es) |
| JP (1) | JPH0735375B2 (es) |
| AT (1) | ATE159238T1 (es) |
| DE (1) | DE69222678T2 (es) |
| ES (1) | ES2109321T3 (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5496542A (en) * | 1993-10-25 | 1996-03-05 | Church & Dwight Co., Inc. | Stable sodium percarbonate formulation |
| DE4407464A1 (de) * | 1994-03-07 | 1995-09-28 | Basf Ag | Verfahren zur Herstellung von (1R,4S)-4-Hydroxy-1,2,2-trimethyl-cyclopentyl-methylketon sowie Derivaten und Stereoisomeren dieser Verbindung |
| EP1955992B1 (en) * | 2007-02-07 | 2011-11-23 | Tokuyama Corporation | Process for the preparation of 1-aryl-3, 4-dihydro-1h-napthalene-2-one |
| MX380241B (es) * | 2014-06-11 | 2025-03-12 | Bayer Cropscience Ag | Proceso para preparar 3-cloro-2-vinilfenol. |
| KR102595410B1 (ko) * | 2015-03-05 | 2023-10-27 | 바이엘 크롭사이언스 악티엔게젤샤프트 | 3-클로로-2-비닐페닐설포네이트의 제조 방법 |
| EP3497075B1 (de) | 2016-08-12 | 2020-08-05 | Bayer CropScience Aktiengesellschaft | Verfahren zur herstellung von substituierten styrol-derivaten |
| WO2018104105A1 (de) | 2016-12-05 | 2018-06-14 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von 3-substituierten 2-vinylphenylsulfonaten |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2794812A (en) * | 1953-08-13 | 1957-06-04 | Union Carbide & Carbon Corp | 7-oxabicyclo-heptane 3-carboxylic acids and esters |
| NL287844A (es) * | 1962-01-18 | |||
| GB1022203A (en) * | 1962-01-18 | 1966-03-09 | Shell Int Research | Novel epoxycyclohexane derivatives |
| NL292269A (es) * | 1963-05-02 | |||
| NL292268A (es) * | 1963-05-02 | |||
| US3898289A (en) * | 1970-11-05 | 1975-08-05 | Chevron Res | Hydroxy-substituted aromatic hydrocarbon process |
| GB1528528A (en) * | 1976-08-09 | 1978-10-11 | Shell Int Research | Cyclohexane derivatives |
-
1992
- 1992-03-27 DE DE69222678T patent/DE69222678T2/de not_active Expired - Fee Related
- 1992-03-27 ES ES92400866T patent/ES2109321T3/es not_active Expired - Lifetime
- 1992-03-27 AT AT92400866T patent/ATE159238T1/de not_active IP Right Cessation
- 1992-03-27 EP EP92400866A patent/EP0511036B1/fr not_active Expired - Lifetime
- 1992-04-15 JP JP4095620A patent/JPH0735375B2/ja not_active Expired - Lifetime
-
1993
- 1993-10-21 US US08/139,049 patent/US5424460A/en not_active Expired - Fee Related
-
1995
- 1995-03-09 US US08/401,254 patent/US5817890A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5817890A (en) | 1998-10-06 |
| ATE159238T1 (de) | 1997-11-15 |
| JPH05140137A (ja) | 1993-06-08 |
| US5424460A (en) | 1995-06-13 |
| JPH0735375B2 (ja) | 1995-04-19 |
| EP0511036A1 (fr) | 1992-10-28 |
| EP0511036B1 (fr) | 1997-10-15 |
| DE69222678D1 (de) | 1997-11-20 |
| DE69222678T2 (de) | 1998-02-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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