ES2109613T3 - Preparacion de 1,2-diacil-2-(t-alquil)hidrazinas. - Google Patents
Preparacion de 1,2-diacil-2-(t-alquil)hidrazinas.Info
- Publication number
- ES2109613T3 ES2109613T3 ES94305803T ES94305803T ES2109613T3 ES 2109613 T3 ES2109613 T3 ES 2109613T3 ES 94305803 T ES94305803 T ES 94305803T ES 94305803 T ES94305803 T ES 94305803T ES 2109613 T3 ES2109613 T3 ES 2109613T3
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- alkylhydrazine
- hydrazines
- diacyl
- afford
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000002429 hydrazines Chemical class 0.000 title abstract 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- QCQCHGYLTSGIGX-GHXANHINSA-N 4-[[(3ar,5ar,5br,7ar,9s,11ar,11br,13as)-5a,5b,8,8,11a-pentamethyl-3a-[(5-methylpyridine-3-carbonyl)amino]-2-oxo-1-propan-2-yl-4,5,6,7,7a,9,10,11,11b,12,13,13a-dodecahydro-3h-cyclopenta[a]chrysen-9-yl]oxy]-2,2-dimethyl-4-oxobutanoic acid Chemical compound N([C@@]12CC[C@@]3(C)[C@]4(C)CC[C@H]5C(C)(C)[C@@H](OC(=O)CC(C)(C)C(O)=O)CC[C@]5(C)[C@H]4CC[C@@H]3C1=C(C(C2)=O)C(C)C)C(=O)C1=CN=CC(C)=C1 QCQCHGYLTSGIGX-GHXANHINSA-N 0.000 abstract 1
- 241000254173 Coleoptera Species 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 abstract 1
- 241000255777 Lepidoptera Species 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000008037 diacylhydrazines Chemical class 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C241/00—Preparation of compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
- C07C241/04—Preparation of hydrazides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
- C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
- C07C243/38—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
LA INVENCION SUMINISTRA UN PROCESO PARA PREPARAR 1,2-DIACIL-2(T-ALQUIL)HIDRAZINAS. MAS PARTICULARMENTE, LA INVENCION SE REFIERE A UN PROCESO PARA PREPARAR LAS DIACILHIDRAZINAS ANTES MENCIONADAS UTILIZANDO UN SOLVENTE QUE COMPRENDE UN ESTER O UNA MEZCLA DE UN ESTER Y AGUA EN UN PROCESO EN EL QUE EL CLORURO DE ACIDO AROMATICO SE HACE REACCIONAR EN UN PRIMER PASO CON T-ALQUILHIDRACINA O UNA SAL DE ADICION ACIDA CORRESPONDIENTE DE UNA T-ALQUILHIDRAZINA TAL COMO LA SAL DE HIDROCLORURO EN LA PRESENCIA DE UNA BASE PARA OBTENER 1-ACIL-2-T-ALQUILHIDRAZINA, SEGUIDO POR UN SEGUNDO PASO EN EL QUE CLORURO DEL ACIDO AROMATICO SE HACE REACCIONAR CON LA MONOACILHIDRAZINA ANTES MENCIONADA EN LA PRESENCIA DE UNA BASE PARA OBTENER LA 1,2-DIACIL-2-(T-ALQUIL)HIDRACINA DESEADA. TALES COMPUESTOS SON CONOCIDOS POR TENER UNA EXCELENTE ACTIVIDAD INSECTICIDA CONTRA LOS INSECTOS DE LOS ORDENES LEPIDOPTERA Y COLEOPTERA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10911693A | 1993-08-19 | 1993-08-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2109613T3 true ES2109613T3 (es) | 1998-01-16 |
Family
ID=22325870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94305803T Expired - Lifetime ES2109613T3 (es) | 1993-08-19 | 1994-08-04 | Preparacion de 1,2-diacil-2-(t-alquil)hidrazinas. |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0639559B1 (es) |
| JP (1) | JPH07145127A (es) |
| KR (1) | KR100355253B1 (es) |
| CN (1) | CN1050599C (es) |
| AT (1) | ATE159244T1 (es) |
| AU (1) | AU692447B2 (es) |
| BR (1) | BR9403271A (es) |
| CA (1) | CA2129770C (es) |
| DE (1) | DE69406227T2 (es) |
| ES (1) | ES2109613T3 (es) |
| IL (1) | IL110584A (es) |
| TW (1) | TW295533B (es) |
| ZA (1) | ZA945958B (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19730848A1 (de) | 1997-07-18 | 1999-01-21 | Bayer Ag | Verfahren zur Herstellung von 3-Hydroxy-2-methylbenzoesäure |
| JP2000178462A (ja) | 1998-12-16 | 2000-06-27 | Konica Corp | ヒドラジン化合物、それを含有するハロゲン化銀写真感光材料および画像形成方法 |
| DE19953775A1 (de) | 1999-11-09 | 2001-05-10 | Bayer Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| DE10018370A1 (de) | 2000-04-14 | 2001-10-18 | Bayer Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| DE10043610A1 (de) | 2000-09-05 | 2002-03-14 | Bayer Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| DE10212885A1 (de) * | 2002-03-22 | 2003-10-02 | Bayer Ag | Verfahren zur Herstellung von 3-Hydroxy-2-methylbenzoesäure |
| DE50302717D1 (de) | 2002-08-21 | 2006-05-11 | Lanxess Deutschland Gmbh | Chirale Diphosphorverbindungen und deren Übergangsmetallkomplexe |
| DE10248257A1 (de) | 2002-10-16 | 2004-04-29 | Bayer Cropscience Ag | Wirkstoffkombinationen im insektiziden und akariziden Eigenschaften |
| US7304161B2 (en) | 2003-02-10 | 2007-12-04 | Intrexon Corporation | Diaclhydrazine ligands for modulating the expression of exogenous genes in mammalian systems via an ecdysone receptor complex |
| US7456315B2 (en) | 2003-02-28 | 2008-11-25 | Intrexon Corporation | Bioavailable diacylhydrazine ligands for modulating the expression of exogenous genes via an ecdysone receptor complex |
| CL2008000979A1 (es) | 2007-04-11 | 2008-10-17 | Sumitomo Chemical Co | Proceso para producir un compuesto derivado de 2-piridin-2-il-2h-pirazol-3-fenilamida; compuestos intermediarios; el compuesto en si; composicion plaguicida que contiene a dicho compuesto; uso de dicho compuesto como plaguicida; y metodo para control |
| EP2127522A1 (de) | 2008-05-29 | 2009-12-02 | Bayer CropScience AG | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| EP2382865A1 (de) | 2010-04-28 | 2011-11-02 | Bayer CropScience AG | Synergistische Wirkstoffkombinationen |
| CN103539874B (zh) * | 2012-07-12 | 2016-02-10 | 中国石油天然气股份有限公司 | 烯烃聚合用固体钛催化剂及其制备方法 |
| CN103694385B (zh) * | 2012-09-28 | 2016-03-09 | 中国石油天然气股份有限公司 | 丙烯聚合催化组分及其催化剂 |
| US9127024B2 (en) | 2013-03-15 | 2015-09-08 | Intrexon Corporation | Boron-containing diacylhydrazines |
| AU2015317862A1 (en) | 2014-09-17 | 2017-04-06 | Intrexon Corporation | Boron-containing diacylhydrazine compounds |
| GB2612942A (en) * | 2021-09-16 | 2023-05-24 | Rotam Agrochem Int Co Ltd | A crystalline form of methoxyfenozide, a process for its preparation and use of the same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4985461A (en) | 1985-10-21 | 1991-01-15 | Rohm And Haas Company | Insecticidal N'-substituted-N,N'-diacylhydrazines |
| DK483586A (da) * | 1985-10-21 | 1987-04-22 | Rohm & Haas | Insecticide n'-substituerede-n,n'-diacylhydraziner |
| NZ240155A (en) * | 1990-10-29 | 1992-10-28 | Ishihara Sangyo Kaisha | Heterocyclyl acyl and (hexahydro) indanyl acyl substituted hydrazine derivatives, preparation thereof and pesticidal compositions |
| US5675037A (en) * | 1990-12-17 | 1997-10-07 | Rohm And Haas Company | Selective acylation of hydrazines |
-
1994
- 1994-08-04 EP EP94305803A patent/EP0639559B1/en not_active Expired - Lifetime
- 1994-08-04 ES ES94305803T patent/ES2109613T3/es not_active Expired - Lifetime
- 1994-08-04 DE DE69406227T patent/DE69406227T2/de not_active Expired - Lifetime
- 1994-08-04 AT AT94305803T patent/ATE159244T1/de not_active IP Right Cessation
- 1994-08-08 AU AU68976/94A patent/AU692447B2/en not_active Expired
- 1994-08-08 IL IL11058494A patent/IL110584A/xx not_active IP Right Cessation
- 1994-08-09 CA CA002129770A patent/CA2129770C/en not_active Expired - Lifetime
- 1994-08-09 ZA ZA945958A patent/ZA945958B/xx unknown
- 1994-08-12 TW TW083107367A patent/TW295533B/zh not_active IP Right Cessation
- 1994-08-18 KR KR1019940020378A patent/KR100355253B1/ko not_active Expired - Lifetime
- 1994-08-18 BR BR9403271A patent/BR9403271A/pt not_active IP Right Cessation
- 1994-08-18 CN CN94115419A patent/CN1050599C/zh not_active Expired - Lifetime
- 1994-08-18 JP JP6194339A patent/JPH07145127A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| TW295533B (es) | 1997-01-11 |
| CA2129770C (en) | 2005-05-03 |
| CN1050599C (zh) | 2000-03-22 |
| ZA945958B (en) | 1995-02-20 |
| IL110584A (en) | 1999-10-28 |
| ATE159244T1 (de) | 1997-11-15 |
| IL110584A0 (en) | 1994-11-11 |
| BR9403271A (pt) | 1995-04-11 |
| DE69406227D1 (de) | 1997-11-20 |
| AU692447B2 (en) | 1998-06-11 |
| KR100355253B1 (ko) | 2004-12-23 |
| DE69406227T2 (de) | 1998-04-30 |
| CN1109049A (zh) | 1995-09-27 |
| JPH07145127A (ja) | 1995-06-06 |
| CA2129770A1 (en) | 1995-02-20 |
| KR950005160A (ko) | 1995-03-20 |
| EP0639559B1 (en) | 1997-10-15 |
| AU6897694A (en) | 1995-03-02 |
| EP0639559A1 (en) | 1995-02-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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