ES2109997T3 - Bis(fosfolanos)tridentados quirales. - Google Patents

Bis(fosfolanos)tridentados quirales.

Info

Publication number
ES2109997T3
ES2109997T3 ES92911965T ES92911965T ES2109997T3 ES 2109997 T3 ES2109997 T3 ES 2109997T3 ES 92911965 T ES92911965 T ES 92911965T ES 92911965 T ES92911965 T ES 92911965T ES 2109997 T3 ES2109997 T3 ES 2109997T3
Authority
ES
Spain
Prior art keywords
divalent
ring
approximately
aralkilo
fluoralkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92911965T
Other languages
English (en)
Inventor
Mark Joseph Burk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of ES2109997T3 publication Critical patent/ES2109997T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE PRESENTAN BIS(FOSFOLANOS) TRIDENTADOS QUIRALES QUE SE COORDINAN COMO LIGANDOS A MODO MERIDIONAL EN UN METAL OCTAHEDRICO O QUE SE COORDINAN EN ENTORNOS PLANO-CUADRADOS JUNTO CON UN METODO PARA SU PREPARACION. QUEDAN REPRESENTADOS POR LA FORMULA (I) EN DONDE: R ES UN RADICAL QUE CONTIENE ALKILO, FLUORALKILO O PERFLUORALKILO, CADA UNO DE LOS CUALES CONTIENE HASTA 8 ATOMOS DE CARBONO APROXIMADAMENTE; ARILO; ARILO SUSTITUIDO; ARALKILO; ARALKILO SUSTITUIDO POR UN ANILLO; O CR''2(CR''2)QX(CR''2)PR'' EN DONDE Q Y P SON CADA UNO ENTEROS, IGUALES O DIFERENTES, QUE VAN DE 1 A 8 APROXIMADAMENTE; X ES COMO SE DEFINE MAS ABAJO; Y R'' ES H; F; ARILO; O ALKILO, FLUORALKILO O PERFLUORALKILO, CADA UNO DE LOS CUALES CONTIENE HASTA 8 ATOMOS DE CARBONO APROXIMADAMENTE; N Y M SON CADA UNO ENTEROS, IGUALES O DIFERENTES, QUE VAN DE 1 A 8 APROXIMADAMENTE; Y X CONTIENE O, S, NR", PR", ASR", SBR", ARILO DIVALENTE, ARILO FUNDIDO DIVALENTE, UN GRUPO HETEROCICLICO CON UN ANILLO DE SEIS MIEMBROS DIVALENTE, UN GRUPO HETEROCICLICO CON UN ANILLO DE CINCO MIEMBROS DIVALENTE O UN GRUPO HETEROCICLICO FUNDIDO DIVALENTE, EN DONDE R" ES HIDROGENO; ALKILO, FLUORALKILO O PERFLUORALKILO, CADA UNO DE LOS CUALES CONTIENE HASTA 8 ATOMOS DE CARBONO APROXIMADAMENTE; ARILO; ARILO SUSTITUIDO; ARALKILO; ARALKILO SUSTITUIDO POR UN ANILLO; O CR''2(CR''2)QZ(CR''2)PR'' EN DONDE Z ES O, S, NR'', PR'', ASR'' O SBR'' Y R'', P Y Q SON COMO SE HAN DEFINIDO ARRIBA.
ES92911965T 1991-04-26 1992-04-20 Bis(fosfolanos)tridentados quirales. Expired - Lifetime ES2109997T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/691,954 US5202493A (en) 1991-04-26 1991-04-26 Chiral tridentate bis(phospholane) ligands

Publications (1)

Publication Number Publication Date
ES2109997T3 true ES2109997T3 (es) 1998-02-01

Family

ID=24778672

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92911965T Expired - Lifetime ES2109997T3 (es) 1991-04-26 1992-04-20 Bis(fosfolanos)tridentados quirales.

Country Status (7)

Country Link
US (1) US5202493A (es)
EP (1) EP0582668B1 (es)
JP (1) JP3100982B2 (es)
CA (1) CA2108160C (es)
DE (1) DE69223240T2 (es)
ES (1) ES2109997T3 (es)
WO (1) WO1992019630A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5250731A (en) * 1992-03-17 1993-10-05 E. I. Du Pont De Nemours And Company Preparation of optically active hydrazines and amines
DE4333307A1 (de) * 1993-09-30 1995-04-06 Hoechst Ag Cyclische Verbindungen des dreiwertigen Phosphors
DE19725796A1 (de) * 1997-06-18 1998-12-24 Basf Ag Herstellung optisch aktiver Phospholane, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese
DE19824121A1 (de) * 1998-05-29 1999-12-02 Basf Ag Herstellung optisch aktiver Phospholane, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese
US6337406B1 (en) 1998-08-21 2002-01-08 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes and hydroxyl phospholanes
WO2000011008A1 (en) * 1998-08-21 2000-03-02 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes
US6727377B2 (en) * 1998-08-21 2004-04-27 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes and hydroxyl phospholanes
DE19845517A1 (de) * 1998-10-02 2000-04-06 Basf Ag Verfahren zur asymmetrische Hydrierung von beta-Ketoestern
EP1063239A1 (fr) * 1999-06-25 2000-12-27 Societe De Conseils De Recherches Et D'applications Scientifiques (S.C.R.A.S.) Nouveaux composés possédant un lanthanide et un ligand tridentate, leur procédé de préparation et leur application notamment comme catalyseurs de polymérisation
EP1206427B1 (en) 1999-08-23 2005-11-09 The Penn State Research Foundation Chiral ligands, transition-metal complexes thereof and uses thereof in asymmetric reactions
US7560499B2 (en) * 2001-12-28 2009-07-14 Calhoun Vision, Inc. Initiator and ultraviolet absorber blends for changing lens power by ultraviolet light
US6900352B1 (en) 2002-02-25 2005-05-31 Advanced Syntech, Llc Six-membered chiral phosphine ligands
WO2004096735A2 (en) * 2003-05-02 2004-11-11 Kamaluddin Abdur-Rashid Transfer hydrogenation processes and catalysts
CA2717943C (en) * 2008-03-11 2014-01-28 Fukuoka University Phosphine compound, process for producing the same, and peroxide scavenger using the same
WO2016086837A1 (zh) * 2014-12-05 2016-06-09 中国石油天然气股份有限公司 一种二元磺酸酯化合物及其应用与烯烃聚合催化剂组分和烯烃聚合催化剂
CN104402776B (zh) * 2014-12-05 2017-06-13 中国石油天然气股份有限公司 一种二元醇磺酸酯化合物及其制备方法与应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4391756A (en) * 1978-06-05 1983-07-05 The Standard Oil Company Organo-monovalent aurus complex catalysts for the manufacture of olefin oxides
IL59647A (en) * 1980-03-14 1984-01-31 Yeda Res & Dev Organo-metallic catalytic system
US4394322A (en) * 1980-08-18 1983-07-19 Gulf Research & Development Company Group VA ylides and process for preparing same
US5008457A (en) * 1990-05-17 1991-04-16 E. I. Du Pont De Nemours And Company Chiral phospholane transition metal catalysts
US5021131A (en) * 1990-05-17 1991-06-04 E. I. Du Pont De Nemours And Company Optically pure 1,4-diols

Also Published As

Publication number Publication date
EP0582668B1 (en) 1997-11-19
DE69223240D1 (de) 1998-01-02
EP0582668A1 (en) 1994-02-16
JP3100982B2 (ja) 2000-10-23
US5202493A (en) 1993-04-13
CA2108160A1 (en) 1992-10-27
CA2108160C (en) 2002-10-08
WO1992019630A1 (en) 1992-11-12
JPH06507175A (ja) 1994-08-11
DE69223240T2 (de) 1998-04-16

Similar Documents

Publication Publication Date Title
HUT64944A (en) New aryl-glycide-amide derivatives and method for producing them
ES2085877T3 (es) Azolilmetilcicloalcanoles substituidos y fungicidas que los contienen.
DE3675226D1 (de) Triazinderivate, verfahren zur herstellung der derivate und die derivate als wirksamen bestandteil enthaltende herbizide.
SE7706392L (sv) N-fosfonometylenmonoaminoalkanmono- och -polyfosfonsyror respektive n-fosfonometylendiaminoalkanpolyfosfonsyror samt sett for deras framstellning
CA2108160A1 (en) Chiral tridentate bis(phospholane) ligands
MX7157E (es) Procedimiento para preparar derivados de fenilpiperazina
ATE191915T1 (de) Herstellung von borester
HU903266D0 (en) Process for producing amine-derivatives and pharmaceutical preparatives containing these compounds as active substance
ES2045282T3 (es) Un procedimiento para la preparacion de antraciclinona 4-sustituida.
DE3060245D1 (en) Triazolyl derivatives, process for their preparation and plant growth regulation agents containing them
NO910617L (no) Heterocykliske forbindelser.
GB1550733A (en) Thermosettable compositions and method for producing mouldings and coatings
FR2485539B1 (es)
KR850001165A (ko) 중추 신경계 활성을 갖는 피롤리디논의 제조방법
ES8201526A1 (es) Un procedimiento para la preparacion de nuevos derivados de 1,1'-binefil-2-il-alquilamina
EP0033098A3 (en) N-methyl-n-silyl-carbamates, process for their preparation and their use as pesticides
GB1497570A (en) Compounds containing an unsaturated aliphatic chain having an insecticidal action and having an inhibiting effect on the development and metamorphosis of insects
ES2056467T3 (es) Metodo para la preparacion de compuestos de organotelurio y organoselenio.
ES448995A1 (es) Procedimiento para preparar derivados de 10-(2-hidroxi-3-ami-no-propoxi)-4h-benzon4,5 ciclohetan1,2-bntiofeno.
DE3563745D1 (en) 4,4-dimethyl tetrahydro-2h-pyran-2-on derivatives, process for their preparation and their use for the preparation of cyclopropanic derivatives
ES444930A1 (es) Procedimiento para preparar triazinadionas.
ATE113287T1 (de) Phosphoniumverbindungen und verfahren zu ihrer herstellung.
ES553600A0 (es) Un procedimiento para la preparacion de nuevos derivados de diamina.
GB771418A (en) Improvements in polyalkylphenylpentenyl halides
ES439235A1 (es) Procedimiento para la preparacion de bufadienolid-eteres y bufatrienolid-eteres.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 582668

Country of ref document: ES