ES2113710T3 - Proceso para la polimerizacion de olefinas en fase gaseosa. - Google Patents
Proceso para la polimerizacion de olefinas en fase gaseosa.Info
- Publication number
- ES2113710T3 ES2113710T3 ES95303163T ES95303163T ES2113710T3 ES 2113710 T3 ES2113710 T3 ES 2113710T3 ES 95303163 T ES95303163 T ES 95303163T ES 95303163 T ES95303163 T ES 95303163T ES 2113710 T3 ES2113710 T3 ES 2113710T3
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- gaseous
- mixture
- zone
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/001—Removal of residual monomers by physical means
- C08F6/005—Removal of residual monomers by physical means from solid polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCESO PARA MANUFACTURAR DE FORMA CONTINUA (CO-)POLIMERO DE ETILENO EN UNA FASE GASEOSA EN UNA ZONA DE POLIMERIZACION A TRAVES DE LA CUAL PASA UNA MEZCLA DE REACCION ESENCIALMENTE GASEOSA QUE COMPRENDE LOS (CO-)MONOMEROS. ADEMAS, EL PROCESO COMPRENDE LA TRANSFERENCIA DE UNA MEZCLA (A) FORMADA POR LA MEZCLA DE REACCION GASEOSA Y EL (CO-)POLIMERO SOLIDO EN UNA ZONA DE DESPRESURIZACION, Y LA SEPARACION DE LA MEZCLA (A) EN UNA FASE SOLIDA (B) Y UNA FASE GASEOSA (C) QUE SE HACE RETORNAR A LA ZONA DE POLIMERIZACION. LA FASE SOLIDA (B) SE EXPONE A (1) AL MENOS UN LAVADO NO DESACTIVANTE CON RESPECTO A LOS RESIDUOS CATALITICOS ACTIVOS, Y SUBSECUENTEMENTE (2) A UN LAVADO DE DESACTIVACION CON UNA MEZCLA GASEOSA DE NITROGENO, AGUA Y OXIGENO. EL (CO-)POLIMERO ASI OBTENIDO TIENE MUY BAJOS CONTENIDOS DE (CO-)MONOMEROS NO REACCIONADOS Y COMPUESTOS ORGANICOS VOLATILES, Y EXHIBE UN ALTO INDICE DE BLANCURA Y UNA LARGA ESTABILIDAD TERMICA A LO LARGO DEL TIEMPO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9406221A FR2719847B1 (fr) | 1994-05-16 | 1994-05-16 | Procédé de polymérisation d'oléfine en phase gazeuse. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2113710T3 true ES2113710T3 (es) | 1998-05-01 |
Family
ID=9463419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95303163T Expired - Lifetime ES2113710T3 (es) | 1994-05-16 | 1995-05-10 | Proceso para la polimerizacion de olefinas en fase gaseosa. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5789501A (es) |
| EP (1) | EP0683176B1 (es) |
| JP (1) | JP3606477B2 (es) |
| KR (1) | KR100346670B1 (es) |
| CN (1) | CN1118786A (es) |
| CA (1) | CA2149374A1 (es) |
| DE (1) | DE69501850T2 (es) |
| EG (1) | EG20607A (es) |
| ES (1) | ES2113710T3 (es) |
| FI (1) | FI952376A7 (es) |
| FR (1) | FR2719847B1 (es) |
| MY (1) | MY118447A (es) |
| NO (1) | NO307658B1 (es) |
| TW (1) | TW357152B (es) |
Families Citing this family (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0814100A1 (en) * | 1996-06-21 | 1997-12-29 | Bp Chemicals S.N.C. | Polymerisation process |
| TW440572B (en) * | 1996-04-11 | 2001-06-16 | Mitsui Petrochemical Ind | Method of drying solid polymer and drying apparatus |
| EP0803519A1 (en) * | 1996-04-26 | 1997-10-29 | Bp Chemicals S.N.C. | Polymerisation process |
| AU731501B2 (en) * | 1997-05-23 | 2001-03-29 | Dow Chemical Company, The | Solid state devolatilization of syndiotactic vinyl aromatic polymers with catalyst deactivation |
| US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| FR2774991B1 (fr) * | 1998-02-18 | 2000-03-17 | Inst Francais Du Petrole | Procede de polymerisation en presence d'alpha-olefines |
| JP2002519497A (ja) | 1998-07-01 | 2002-07-02 | エクソンモービル・ケミカル・パテンツ・インク | 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド |
| US6022946A (en) * | 1998-12-23 | 2000-02-08 | Union Carbide Chemicals & Plastics Technology Corporation | Process for deactivation of polyolefin compositions utilizing carbon dioxide as a deactivation agent |
| US6111034A (en) * | 1998-12-31 | 2000-08-29 | Union Carbide Chemicals & Plastics Technology Corporation | Static control in olefin polymerization |
| DE19922677C1 (de) * | 1999-05-18 | 2001-04-19 | Elenac Gmbh | Verfahren zum Trocknen und Entgasen von Polyolefinen und nach diesem Verfahren hergestelltes Polyethylen |
| DE60238049D1 (de) | 2001-04-12 | 2010-12-02 | Exxonmobil Chem Patents Inc | Verfahren zur Polymerisation von Propylen und Ethylen in Lösung |
| EP1444276A1 (en) | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
| JP4436801B2 (ja) | 2002-10-30 | 2010-03-24 | イネオス マニュファクチャリング ベルギウム ナームローゼ フェンノートシャップ | 重合体の処理 |
| US7459500B2 (en) | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| US7579407B2 (en) | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| WO2005111091A1 (en) * | 2004-04-30 | 2005-11-24 | Dow Global Technologies Inc. | Reduction of discoloration in polyolefin resins |
| DE102005005506A1 (de) * | 2005-02-04 | 2006-08-10 | Basell Polyolefine Gmbh | Verfahren und Vorrichtung zur Polymerisation von Ethylen |
| DE602007004495D1 (de) | 2006-08-03 | 2010-03-11 | Basell Polyolefine Gmbh | Verfahren zur endbehandlung von polyolefin |
| EP2172495A1 (en) | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Method for the production of polymers |
| EP2172494A1 (en) | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Process |
| CN102256697B (zh) * | 2008-12-18 | 2014-11-12 | 埃克森美孚化学专利公司 | 高压聚合工艺 |
| EP2357035A1 (en) | 2010-01-13 | 2011-08-17 | Ineos Europe Limited | Polymer powder storage and/or transport and/or degassing vessels |
| ES2665545T3 (es) * | 2011-10-17 | 2018-04-26 | Ineos Europe Ag | Control del proceso de desgasificación del polímero |
| EP2743278A1 (en) | 2012-12-11 | 2014-06-18 | Basell Polyolefine GmbH | Process for degassing and buffering polyolefin particles obtained by olefin polymerization |
| EP2743279A1 (en) | 2012-12-11 | 2014-06-18 | Basell Polyolefine GmbH | Process for treating polyolefin particles obtained by gas-phase polymerization |
| EP3235832B1 (en) | 2013-04-22 | 2018-06-20 | Borealis AG | Polypropylene compositions |
| ES2632593T3 (es) | 2013-04-22 | 2017-09-14 | Borealis Ag | Procedimiento de dos fases de producción de composiciones de polipropileno |
| EP2796473B1 (en) | 2013-04-22 | 2017-05-31 | Borealis AG | Multistage process for producing low-temperature resistant polypropylene compositions |
| EP2853562A1 (en) | 2013-09-27 | 2015-04-01 | Borealis AG | Two-stage process for producing polypropylene compositions |
| EP2860203B1 (en) | 2013-10-10 | 2016-12-14 | Borealis AG | Multistage process for producing polyethylene compositions |
| EP2883887A1 (en) | 2013-12-13 | 2015-06-17 | Borealis AG | Multistage process for producing polyethylene compositions |
| EP2883885A1 (en) | 2013-12-13 | 2015-06-17 | Borealis AG | Multistage process for producing polyethylene compositions |
| WO2015128329A1 (en) | 2014-02-26 | 2015-09-03 | Ineos Europe Ag | Polymerisation process and polymerisation unit comprising a degassing section |
| EP2913345B1 (en) | 2014-02-28 | 2016-11-02 | Borealis AG | Gas phase polymerization process |
| EP2913346B1 (en) | 2014-02-28 | 2016-11-02 | Borealis AG | Process for polymerizing olefins in a fluidized bed |
| US10308737B2 (en) | 2014-09-30 | 2019-06-04 | Borealis Ag | Process for polymerising ultra-high molecular weight polyethylene |
| WO2016091803A1 (en) | 2014-12-08 | 2016-06-16 | Borealis Ag | Process for producing pellets of copolymers of propylene |
| US10723870B2 (en) | 2015-02-20 | 2020-07-28 | Borealis Ag | Process for producing heterophasic copolymers of propylene |
| HUE039059T2 (hu) | 2015-06-12 | 2018-12-28 | Borealis Ag | Eljárás és berendezés olefinek gázfázisban történõ polimerizálására |
| ES2707391T3 (es) | 2015-06-23 | 2019-04-03 | Borealis Ag | Procedimiento para la producción de resinas de LLDPE |
| EP3184166A1 (en) | 2015-12-22 | 2017-06-28 | Borealis AG | A method for withdrawing agglomerates from a fluidised bed reactor |
| EP3184167B8 (en) | 2015-12-22 | 2022-03-30 | Borealis AG | A method for returning polymer to a fluidised bed reactor |
| EP3464457B2 (en) | 2016-05-31 | 2025-04-09 | Borealis AG | Polymer composition and a process for production of the polymer composition |
| CN109415448B (zh) | 2016-06-22 | 2021-04-13 | 北欧化工公司 | 聚合物组合物以及制备聚合物组合物的方法 |
| PL3519444T3 (pl) | 2016-09-28 | 2021-05-04 | Borealis Ag | Proces wytwarzania powlekanej rury |
| US10982025B2 (en) | 2016-11-25 | 2021-04-20 | Borealis Ag | Process for producing polyolefin film composition and films prepared thereof |
| BR112019002951B1 (pt) | 2016-11-25 | 2022-12-20 | Borealis Ag | Composição de polímero, artigo, uso da composição de polietileno, e, processo para a produção de uma composição de polímero |
| GB201620525D0 (en) | 2016-12-02 | 2017-01-18 | Ineos Europe Ag | Process |
| ES2786756T3 (es) | 2017-06-20 | 2020-10-13 | Borealis Ag | Un método, una disposición y uso de una disposición para la polimerización de olefinas |
| EP3418309A1 (en) | 2017-06-20 | 2018-12-26 | Borealis AG | A method, an arrangement and use of an arrangement of preparing polymer |
| EP3418330B2 (en) | 2017-06-21 | 2023-07-19 | Borealis AG | Polymer composition and a process for production of the polymer composition |
| EP3418310B1 (en) | 2017-06-23 | 2020-04-08 | Borealis AG | Process and apparatus for removing polymer material from a gas-solids olefin polymerization reactor |
| US10730032B2 (en) * | 2018-05-16 | 2020-08-04 | Chevron Phillips Chemical Company Lp | Polymer flake degassing system and methods |
| WO2019238428A1 (en) | 2018-06-14 | 2019-12-19 | Borealis Ag | Process for polymerizing olefin in a gas phase reactor with improved thermal homogeneity |
| EP3902851A1 (en) | 2018-12-28 | 2021-11-03 | Borealis AG | A process for producing polyolefin film composition and films prepared thereof |
| EP3902850A1 (en) | 2018-12-28 | 2021-11-03 | Borealis AG | A process for producing polyolefin film composition and films prepared thereof |
| US12291594B2 (en) | 2019-06-24 | 2025-05-06 | Borealis Ag | Process for preparing polypropylene with improved recovery |
| EP3868793B1 (en) | 2020-02-24 | 2026-01-07 | Borealis GmbH | Process for producing alpha-olefin polymers in a multistage polymerization process |
| CN117480191A (zh) | 2021-06-11 | 2024-01-30 | 博里利斯股份公司 | 一种生产多峰乙烯聚合物的方法以及由其制备的薄膜 |
| EP4344869A1 (en) | 2022-09-30 | 2024-04-03 | Borealis AG | Multimodal ethylene copolymer composition and films comprising the same |
| EP4605239A1 (en) | 2022-10-18 | 2025-08-27 | Borealis GmbH | Multilayer film |
| EP4638080A1 (en) | 2022-12-20 | 2025-10-29 | INEOS Europe AG | Process for the production of polyolefin pellets |
| EP4403598A1 (en) | 2023-01-23 | 2024-07-24 | Borealis AG | Polymer composition comprising recycled low density polyethylene for packaging applications |
| KR20260016942A (ko) | 2023-05-23 | 2026-02-04 | 보레알리스 게엠베하 | 폴리올레핀 펠릿을 생산하는 방법, 및 이에 의해 생산되는 펠릿 |
| WO2026046878A1 (en) | 2024-08-26 | 2026-03-05 | Borealis Gmbh | Polyolefin powder decontamination process |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5231269B2 (es) * | 1974-06-13 | 1977-08-13 | ||
| DE2735355A1 (de) * | 1977-08-05 | 1979-02-15 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des aethylens |
| US4156075A (en) * | 1977-08-29 | 1979-05-22 | Eastman Kodak Company | Two step polyolefin catalyst deactivation |
| US4314053A (en) * | 1980-05-08 | 1982-02-02 | Standard Oil Company (Indiana) | Process for reducing polyolefin die smoke |
| US4372758A (en) * | 1980-09-02 | 1983-02-08 | Union Carbide Corporation | Degassing process for removing unpolymerized monomers from olefin polymers |
| US4758654A (en) * | 1987-04-28 | 1988-07-19 | Union Carbide Corporation | Method for treating resin in a purge vessel |
| DE3815487A1 (de) * | 1988-05-06 | 1989-11-16 | Basf Ag | Verfahren zur niederdruckcopolymerisation von ethylen mit (alpha)-olefinen und ethylencopolymerisate mit niederem restmonomerengehalt |
-
1994
- 1994-05-16 FR FR9406221A patent/FR2719847B1/fr not_active Expired - Fee Related
-
1995
- 1995-05-10 DE DE69501850T patent/DE69501850T2/de not_active Expired - Lifetime
- 1995-05-10 EP EP95303163A patent/EP0683176B1/en not_active Expired - Lifetime
- 1995-05-10 ES ES95303163T patent/ES2113710T3/es not_active Expired - Lifetime
- 1995-05-15 CA CA002149374A patent/CA2149374A1/en not_active Abandoned
- 1995-05-15 NO NO951910A patent/NO307658B1/no not_active IP Right Cessation
- 1995-05-15 EG EG38895A patent/EG20607A/xx active
- 1995-05-15 TW TW084104784A patent/TW357152B/zh not_active IP Right Cessation
- 1995-05-16 JP JP11751395A patent/JP3606477B2/ja not_active Expired - Lifetime
- 1995-05-16 CN CN95106506A patent/CN1118786A/zh active Pending
- 1995-05-16 FI FI952376A patent/FI952376A7/fi unknown
- 1995-05-16 MY MYPI95001280A patent/MY118447A/en unknown
- 1995-05-16 KR KR1019950012148A patent/KR100346670B1/ko not_active Expired - Lifetime
-
1997
- 1997-01-15 US US08/782,261 patent/US5789501A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| MY118447A (en) | 2004-11-30 |
| JP3606477B2 (ja) | 2005-01-05 |
| CA2149374A1 (en) | 1995-11-17 |
| DE69501850D1 (de) | 1998-04-30 |
| KR950032310A (ko) | 1995-12-20 |
| US5789501A (en) | 1998-08-04 |
| FI952376L (fi) | 1995-11-17 |
| NO307658B1 (no) | 2000-05-08 |
| CN1118786A (zh) | 1996-03-20 |
| EP0683176A1 (en) | 1995-11-22 |
| FR2719847B1 (fr) | 1996-08-09 |
| NO951910D0 (no) | 1995-05-15 |
| KR100346670B1 (ko) | 2002-11-29 |
| EG20607A (en) | 1999-09-30 |
| FI952376A7 (fi) | 1995-11-17 |
| FR2719847A1 (fr) | 1995-11-17 |
| HK1010055A1 (en) | 1999-06-11 |
| FI952376A0 (fi) | 1995-05-16 |
| EP0683176B1 (en) | 1998-03-25 |
| TW357152B (en) | 1999-05-01 |
| NO951910L (no) | 1995-11-17 |
| JPH0841115A (ja) | 1996-02-13 |
| DE69501850T2 (de) | 1998-07-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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