ES2115936T3 - Procedimiento para fabricar 1,3-dioles y 3-hidroxialdehidos. - Google Patents

Procedimiento para fabricar 1,3-dioles y 3-hidroxialdehidos.

Info

Publication number
ES2115936T3
ES2115936T3 ES94906916T ES94906916T ES2115936T3 ES 2115936 T3 ES2115936 T3 ES 2115936T3 ES 94906916 T ES94906916 T ES 94906916T ES 94906916 T ES94906916 T ES 94906916T ES 2115936 T3 ES2115936 T3 ES 2115936T3
Authority
ES
Spain
Prior art keywords
anyhane
carbon
atoms
eyen
hydrocarbylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94906916T
Other languages
English (en)
Inventor
Lynn Henry Slaugh
Paul Richard Weider
Juan Pedro Arhancet
Jiang-Jen Lin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/013,834 external-priority patent/US5256827A/en
Priority claimed from US08/091,108 external-priority patent/US5304691A/en
Priority claimed from US08/091,107 external-priority patent/US5304686A/en
Priority claimed from US08/130,258 external-priority patent/US5344993A/en
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of ES2115936T3 publication Critical patent/ES2115936T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/58—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

ESTA INVENCION SE REFIERE A UN PROCESO PARA FABRICAR 1,3-DIOLES Y 3-HIDROXIALDEHIDOS POR HIDROFORMILACION DE 1,2-EPOXIDOS, DICHO PROCESO COMPRENDE LA PUESTA EN CONTACTO INTIMO DE (A) UN 1,2EPOXIDO QUE TENGA MAS DE 2 ATOMOS DE CARBONO, (B) UN CATALIZADOR DE CARBONIL DE COBALTO MODIFICADO CON FOSFINA DITERCIARIA, DICHA FOSFINA COMPRENDE UN HIDROCARBILENO-BIS(MONOFOSFABICICLO-ALCANO) EN EL CUAL CADA ATOMO DE FOSFORO ESTA UNIDO A UN HIDROCARBILENO Y ES UN MIEMBRO DE UNA UNION EN PUENTE SIN SER UN ATOMO DE CABEZA DE PUENTE EN DONDE EL HIDROCARBILENO-BIS(MONOFOSFABICICLO-ALCANO) TIENE ENTRE 1 Y 300 ATOMOS DE CARBONO; DE LOS CUALES ENTRE 5 Y 12 ATOMOS DE CARBONO JUNTO CON UN ATOMO DE FOSFORO SON MIEMBROS DE CADA UNA DE LAS DOS ESTRUCTURAS ESQUELETALES BICICLICAS, (C) MONOXIDO DE CARBONO Y (D) HIDROGENO, LA PROPORCION MOLAR DE MONOXIDO DE CARBONO CON RESPECTO AL HIDROGENO ESTA ENTRE 4:1 Y 1:6, PREFERIBLEMENTE ENTRE 1:1 Y 1:4 EN SOLUCION DE FASE LIQUIDA EN UN SOLVENTE DE REACCION INERTE A UNA TEMPERATURA DE ENTRE 30 (GRADOS) Y 150 (GRADOS) C Y A UNA PRESION DE ENTRE 345 Y 68948 KPA (ENTRE 50 Y 10000 PSI).
ES94906916T 1993-02-05 1994-02-03 Procedimiento para fabricar 1,3-dioles y 3-hidroxialdehidos. Expired - Lifetime ES2115936T3 (es)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US1383593A 1993-02-05 1993-02-05
US1383693A 1993-02-05 1993-02-05
US08/013,834 US5256827A (en) 1993-02-05 1993-02-05 Process for making 3-hydroxypropanal and 1,3-propanediol
US08/091,108 US5304691A (en) 1993-07-13 1993-07-13 Process for making 1,3-propanediol and 3-hydroxypropanal
US08/091,107 US5304686A (en) 1993-07-13 1993-07-13 Process for making 3-hydroxypropanal and 1,3-propanediol
US13026093A 1993-10-01 1993-10-01
US08/130,258 US5344993A (en) 1993-10-01 1993-10-01 Process or making 3-hydroxyaldehydes

Publications (1)

Publication Number Publication Date
ES2115936T3 true ES2115936T3 (es) 1998-07-01

Family

ID=27567510

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94906916T Expired - Lifetime ES2115936T3 (es) 1993-02-05 1994-02-03 Procedimiento para fabricar 1,3-dioles y 3-hidroxialdehidos.

Country Status (9)

Country Link
EP (1) EP0682650B1 (es)
JP (1) JP3571720B2 (es)
KR (1) KR100308507B1 (es)
CN (1) CN1045202C (es)
AU (1) AU6039394A (es)
BR (1) BR9405823A (es)
DE (1) DE69410442T2 (es)
ES (1) ES2115936T3 (es)
WO (1) WO1994018149A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1064345C (zh) * 1994-09-30 2001-04-11 国际壳牌研究有限公司 制备1,3－链烷二醇和3－羟基醛的方法
SK281565B6 (sk) * 1994-09-30 2001-05-10 Shell Internationale Research Maatschappij B. V. Spôsob prípravy 1,3-alkándiolov a 3-hydroxyaldehydov
MY112931A (en) * 1994-09-30 2001-10-31 Shell Int Research Process for preparing 1, 3-alkanediols and 3-hydroxyaldehydes
TW593238B (en) * 2001-05-18 2004-06-21 Kevin Dale Allen One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a N-heterocyclic ligand
US6750373B2 (en) 2001-05-18 2004-06-15 Shell Oil Company One-step production of 1, 3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst
US6576802B2 (en) * 2001-06-04 2003-06-10 Shell Oil Company One-step production of 1, 3-propanediol from ethylene oxide and syngas with a catalyst with a phospholanoalkane ligand
US20030032845A1 (en) * 2001-08-08 2003-02-13 Yuan-Zhang Han Hydroformylation of ethylene oxide
WO2008151102A2 (en) * 2007-06-04 2008-12-11 Shell Oil Company Hydrogenation process
CN108017510B (zh) * 2016-11-03 2021-02-02 万华化学集团股份有限公司 一种羟基特戊醛的制备方法，及其在新戊二醇制备方面的应用
CN108047013B (zh) * 2017-12-16 2020-11-24 万华化学集团股份有限公司 一种异戊烯醛的合成方法
US10544076B1 (en) * 2019-09-04 2020-01-28 Eastman Chemical Company Method of making a dialdeyhde
CN113134362B (zh) * 2021-04-28 2022-10-04 陕西延长石油（集团）有限责任公司 一种用于乙醛与合成气无配体氢甲酰化制备乳醛的多相催化剂及其制备方法与应用
CN113461926B (zh) * 2021-07-30 2022-08-02 大连理工大学 一种聚β-羟基脂肪酸酯的化学合成方法
CN117983201A (zh) * 2024-01-29 2024-05-07 山东尚舜化工有限公司 催化剂、其制备方法及利用其氧化合成ns的工艺和设备

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3463819A (en) * 1965-10-21 1969-08-26 Shell Oil Co Glycol production
US3456017A (en) * 1965-10-21 1969-07-15 Shell Oil Co Glycol production
GB1127965A (en) * 1965-11-26 1968-09-25 Shell Int Research Ditertiary phosphines and application thereof as catalyst components for alcohol production
US3456617A (en) * 1967-07-10 1969-07-22 Robert B Way Work support fixture for a coating machine
US5256827A (en) * 1993-02-05 1993-10-26 Shell Oil Company Process for making 3-hydroxypropanal and 1,3-propanediol

Also Published As

Publication number Publication date
DE69410442D1 (de) 1998-06-25
EP0682650B1 (en) 1998-05-20
WO1994018149A1 (en) 1994-08-18
KR100308507B1 (ko) 2001-11-30
AU6039394A (en) 1994-08-29
DE69410442T2 (de) 1998-10-15
JP3571720B2 (ja) 2004-09-29
EP0682650A1 (en) 1995-11-22
CN1045202C (zh) 1999-09-22
JPH08507048A (ja) 1996-07-30
KR960700988A (ko) 1996-02-24
CN1117289A (zh) 1996-02-21
BR9405823A (pt) 1995-12-05

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