ES2116274T3 - ELASTOMER MODIFIED EPOXY RESIN FOR POWDER COMPOSITIONS FOR COATINGS. - Google Patents

ELASTOMER MODIFIED EPOXY RESIN FOR POWDER COMPOSITIONS FOR COATINGS.

Info

Publication number
ES2116274T3
ES2116274T3 ES91200622T ES91200622T ES2116274T3 ES 2116274 T3 ES2116274 T3 ES 2116274T3 ES 91200622 T ES91200622 T ES 91200622T ES 91200622 T ES91200622 T ES 91200622T ES 2116274 T3 ES2116274 T3 ES 2116274T3
Authority
ES
Spain
Prior art keywords
epoxy resin
elastomer
modified
composition
coatings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91200622T
Other languages
Spanish (es)
Inventor
Edward John Marx
Michael James Watkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of ES2116274T3 publication Critical patent/ES2116274T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02Polycondensates containing more than one epoxy group per molecule
    • C08G59/04Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/934Powdered coating composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

SE FACILITA UN METODO PARA DISPERSAR Y ESTABILIZAR UN POLIMERO EN BLOQUES CARBOXI-FUNCIONALIZADO QUE INCLUYE LOS PASOS DE: (A) DISPERSAR ENTRE EL 5 Y EL 30 POR CIENTO DEL PESO DE COPOLIMERO EN BLOQUES DE DIOLEFINAMONOALQUENILARENO, HIDROGENADO, CARBOXI-FUNCIONALIZADO EN UNA RESINA EPOXI LIQUIDA PARA PRODUCIR UNA COMPOSICION DE RESINA EPOXI DE ELASTOMERODISPERSO; (B) PONER EN CONTACTO LA COMPOSICION DE RESINA EPOXI DE ELASTOMERO-DISPERSO Y ENTRE EL 15 Y EL 30 POR CIENTO, BASADO EN EL PESO DE LA COMPOSICION DE RESINA EXPOXI ELASTOMERO-MODIFICADO, DE UN COMPUESTO FENOLICO POLIHIDRICO EN PRESENCIA DE UN CATALIZADOR DE AVANCE A UNA TEMPERATURA DENTRO DEL AMBITO ENTRE 40 C A 200 C DURANTE UN TIEMPO EFECTIVO PARA PRODUCIR UNA RESINA EPOXI DE ELASTOMERO-MODIFICADO SOLIDO CON UN PESO EQUIVALENTE DE EPOXI EN EL AMBITO ENTRE 500 Y 1,500; Y (C) RECOBRAR LA RESINA EPOXI DE ELASTOMERO-MODIFICADO SOLIDA.A METHOD FOR DISPERSING AND STABILIZING A POLYMER IN CARBOXI-FUNCTIONAL BLOCKS IS PROVIDED, WHICH INCLUDES THE STEPS OF: (A) DISPERSING BETWEEN 5 AND 30 PERCENT OF THE WEIGHT OF COPOLYMER IN A BLOCK OF DIOLEFINAMONO-ALKENYLENE, AID LIQUID EPOXY TO PRODUCE A DISPOSED ELASTOMER EPOXY RESIN COMPOSITION; (B) TO CONTACT THE COMPOSITION OF ELASTOMER-DISPERSED EPOXY RESIN AND BETWEEN 15 AND 30 PERCENT, BASED ON THE WEIGHT OF THE COMPOSITION OF ELASTOMER-MODIFIED EXPOXI RESIN, OF A POLYHYDRIC PHENOLIC COMPOUND IN THE PRESENCE OF A CATALYST ADVANCE TO A TEMPERATURE WITHIN THE SCOPE BETWEEN 40 AC 200 C DURING AN EFFECTIVE TIME TO PRODUCE A SOLID-MODIFIED ELASTOMER EPOXY RESIN WITH AN EQUIVALENT WEIGHT OF EPOXY IN THE SCOPE BETWEEN 500 AND 1,500; AND (C) RECOVER THE SOLID ELASTOMER-MODIFIED EPOXY RESIN.

ES91200622T 1990-03-30 1991-03-20 ELASTOMER MODIFIED EPOXY RESIN FOR POWDER COMPOSITIONS FOR COATINGS. Expired - Lifetime ES2116274T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/503,343 US5115019A (en) 1990-03-30 1990-03-30 Carboxy-functional hydrogenated block copolymer dispersed in epoxy resin

Publications (1)

Publication Number Publication Date
ES2116274T3 true ES2116274T3 (en) 1998-07-16

Family

ID=24001696

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91200622T Expired - Lifetime ES2116274T3 (en) 1990-03-30 1991-03-20 ELASTOMER MODIFIED EPOXY RESIN FOR POWDER COMPOSITIONS FOR COATINGS.

Country Status (8)

Country Link
US (1) US5115019A (en)
EP (1) EP0449359B1 (en)
JP (1) JP3023515B2 (en)
KR (1) KR0177167B1 (en)
CA (1) CA2039273A1 (en)
DE (1) DE69129476T2 (en)
DK (1) DK0449359T3 (en)
ES (1) ES2116274T3 (en)

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US5248400A (en) * 1992-03-27 1993-09-28 Ppg Industries, Inc. Thermosetting powder coating compositions based on polyepoxides and elastomer-modified phenolics
USH1405H (en) * 1992-04-09 1995-01-03 Shell Oil Company Epoxy resin composition
DE4313762C1 (en) * 1993-04-27 1994-04-28 Ppg Ind Deutschland Gmbh Coating metal to improve stone impact resistance - by spraying primer-coated metal with a powder paint, presintering, applying a filler compsn. and stoving
US5332783A (en) * 1993-07-12 1994-07-26 Shell Oil Company Compatible blends of epoxy resins and epoxidized polydienes
US5478885A (en) * 1994-04-15 1995-12-26 Shell Oil Company Composition of epoxy resin, epoxidized block polydiene and curing agent
US5420202A (en) * 1994-04-15 1995-05-30 Shell Oil Company Epoxidized low viscosity rubber toughening modifiers for cycloaliphatic epoxy resins
US5499409A (en) * 1994-07-18 1996-03-19 Shell Oil Company Epoxidized polydiene block polymer with epoxy resins
US5459200A (en) * 1994-10-11 1995-10-17 Shell Oil Company Polyurethane coatings and adhesives containing monohydroxylated diene polymers and epoxidized derivatives thereof
US5500481A (en) * 1995-05-17 1996-03-19 Shell Oil Company Compositions containing epoxidized monohydroxylated diene polymers, amino resins, and reactive reinforcement agents
US6525142B1 (en) 1994-10-11 2003-02-25 Kraton Polymers U.S. Llc Monohydroxylated diene polymers and epoxidized derivatives thereof
US5576388A (en) * 1994-10-11 1996-11-19 Shell Oil Company Telechelic polymers and heterotelechelic polydiene block polymers with dual cure systems
US5461112A (en) * 1994-10-11 1995-10-24 Shell Oil Company Epoxidized monohydroxylated block polymer, epoxy resin, curing agent and epoxy diluent
US5721316A (en) * 1995-07-12 1998-02-24 Shell Oil Company Process for incorporation of expoxidized polydienes into epoxy resins
KR100454366B1 (en) * 1995-11-16 2005-04-28 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 Crosslinkable hydroxy functional polydiene polymer coating compositions and a process for preparing them
US5922467A (en) * 1996-10-15 1999-07-13 Shell Oil Company Method for coating crosslinkable epoxidized monohydroxylated diene polymer coating compositions on primed substrates
US6043316A (en) * 1996-11-13 2000-03-28 Shell Oil Company Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them
KR100563806B1 (en) * 1997-08-19 2006-03-28 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 Conductive epoxy resin composition, anisotropic conductive adhesive film and electrical connection method
US6309502B1 (en) 1997-08-19 2001-10-30 3M Innovative Properties Company Conductive epoxy resin compositions, anisotropically conductive adhesive films and electrical connecting methods
US6486256B1 (en) * 1998-10-13 2002-11-26 3M Innovative Properties Company Composition of epoxy resin, chain extender and polymeric toughener with separate base catalyst
US6924328B2 (en) 2001-09-06 2005-08-02 Valspar Sourcing, Inc. Stabilized coating compositions
MXPA04002112A (en) * 2001-09-06 2004-07-08 Valspar Sourcing Inc Stabilized coating compositions.
US6916874B2 (en) 2001-09-06 2005-07-12 Valspar Sourcing, Inc. Coating compositions having epoxy functional stabilizer
US20080199713A1 (en) * 2004-07-14 2008-08-21 David Murray James Powder Coating Composition
US8338535B2 (en) 2006-06-30 2012-12-25 Toray Industries, Inc. Epoxy resins, curing agent and (Co)poly(methyl methacrylate) block copolymer
DE102007052069A1 (en) * 2007-07-20 2009-01-22 Tesa Ag Process for the corrosion protection treatment of metal surfaces
JP5420212B2 (en) * 2007-10-31 2014-02-19 アクゾ ノーベル コーティングス インターナショナル ビー ヴィ Thin chip powder top coat for steel
EP2240544B1 (en) * 2008-01-25 2016-07-13 Akzo Nobel Coatings International B.V. Powder coating compositions having a substantially non-zinc containing primer
US9321856B2 (en) 2013-12-19 2016-04-26 Exxonmobil Chemical Patents Inc. Process to produce functionalized polymer
WO2015094580A1 (en) * 2013-12-19 2015-06-25 Exxonmobil Chemical Patents Inc. Process to produce functionalized polymer
WO2020096032A1 (en) * 2018-11-09 2020-05-14 味の素株式会社 Adhesive composition

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* Cited by examiner, † Cited by third party
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US3477990A (en) * 1967-12-07 1969-11-11 Shell Oil Co Process for reacting a phenol with an epoxy compound and resulting products
BE791204A (en) * 1971-11-12 1973-05-10 Dow Chemical Co PROCESS FOR PREPARING SOLID EPOXY RESINS
US4119592A (en) * 1977-02-25 1978-10-10 The B. F. Goodrich Company Rubbery bladders from epoxy compositions
US4399241A (en) * 1980-03-21 1983-08-16 Scm Corporation Base for a graft polymer, novel graft polymer compositions, solvents and water-reducible coatings incorporating the novel graft polymers, and processes for making them
JPS57149369A (en) * 1981-03-11 1982-09-14 Asahi Chem Ind Co Ltd Novel adhesive
JPS5817160A (en) * 1981-07-24 1983-02-01 Asahi Chem Ind Co Ltd Thermosetting resin composition
JPS62501299A (en) * 1985-06-26 1987-05-21 ザ ダウ ケミカル カンパニ− rubber modified epoxy compound
US4734468A (en) * 1986-02-28 1988-03-29 Shell Oil Company Epoxy resin composition
US4804581A (en) * 1987-05-14 1989-02-14 Ppg Industries, Inc. Chip resistant coatings
JPH07108934B2 (en) * 1987-06-09 1995-11-22 財団法人接着剤研究所 Hydrogenated block copolymer-dispersed liquid epoxy resin composition
US5264503A (en) 1990-01-29 1993-11-23 Shell Oil Company Phenol-terminated epoxy resin with functional elastomer

Also Published As

Publication number Publication date
US5115019A (en) 1992-05-19
DK0449359T3 (en) 1998-10-12
CA2039273A1 (en) 1991-10-01
EP0449359B1 (en) 1998-05-27
DE69129476D1 (en) 1998-07-02
DE69129476T2 (en) 1998-11-05
EP0449359A2 (en) 1991-10-02
JP3023515B2 (en) 2000-03-21
KR0177167B1 (en) 1999-05-15
EP0449359A3 (en) 1992-07-08
KR910016855A (en) 1991-11-05
JPH04224818A (en) 1992-08-14

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