ES2119014T3 - Copolimeros elastomericos de etileno con propileno y procedimiento para su preparacion. - Google Patents

Copolimeros elastomericos de etileno con propileno y procedimiento para su preparacion.

Info

Publication number
ES2119014T3
ES2119014T3 ES94106975T ES94106975T ES2119014T3 ES 2119014 T3 ES2119014 T3 ES 2119014T3 ES 94106975 T ES94106975 T ES 94106975T ES 94106975 T ES94106975 T ES 94106975T ES 2119014 T3 ES2119014 T3 ES 2119014T3
Authority
ES
Spain
Prior art keywords
propylene
epe
ethylene
procedure
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94106975T
Other languages
English (en)
Inventor
Maurizio Galimberti
Luigi Resconi
Enrico Albizzati
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11366503&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2119014(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Application granted granted Critical
Publication of ES2119014T3 publication Critical patent/ES2119014T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Medicinal Preparation (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

COPOLIMEROS AMORFOS DE ETILENO CON PROPILENO Y OPCIONALMENTE CON MENORES CANTIDADES DE POLIENOS, QUE TIENEN LAS SIGUIENTES CARACTERISTICAS: (A) EL % DE CONTENIDO POR MOL DE PROPILENO EN EL COPOLIMERO (% P) Y LA RELACION TRIVALENTE EPE/(EPE+PPE+PPP) SATISFACE LA SIGUIENTE RELACION: 0,01% P + EPE/(EPE + PPE + PPP) 1, (B) MENOS DEL 2% DE LOS GRUPOS CH2 DE LA CADENA SE ENCUENTRAN EN LAS SECUENCIAS (CH2)N, EN DONDE N ES UN NUMERO PAR. ESTOS COPOLIMEROS SE PUEDEN OBTENER SI SE TRABAJA EN PRESENCIA DE CATALIZADORES DE METALOCENO PARTICULARES QUE TENGAN DOS GRUPO FLUORENILO UNIDOS ENTRE SI A TRAVES DE UN GRUPO PUENTE.
ES94106975T 1993-06-30 1994-05-04 Copolimeros elastomericos de etileno con propileno y procedimiento para su preparacion. Expired - Lifetime ES2119014T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI001405A IT1264482B1 (it) 1993-06-30 1993-06-30 Copolimeri amorfi dell'etilene con propilene e procedimento per la loro preparazione

Publications (1)

Publication Number Publication Date
ES2119014T3 true ES2119014T3 (es) 1998-10-01

Family

ID=11366503

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94106975T Expired - Lifetime ES2119014T3 (es) 1993-06-30 1994-05-04 Copolimeros elastomericos de etileno con propileno y procedimiento para su preparacion.

Country Status (16)

Country Link
US (2) US6221992B1 (es)
EP (1) EP0632066B2 (es)
JP (1) JPH0733825A (es)
KR (1) KR950000742A (es)
CN (1) CN1051322C (es)
AT (1) ATE167880T1 (es)
AU (1) AU674208B2 (es)
BR (1) BR9401058A (es)
CA (1) CA2123336A1 (es)
DE (1) DE69411330T3 (es)
ES (1) ES2119014T3 (es)
FI (1) FI942157A7 (es)
IL (1) IL109435A (es)
IT (1) IT1264482B1 (es)
NO (1) NO303877B1 (es)
RU (1) RU2140426C1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
IT1275857B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Copolimeri atattici del propilene con l'etilene
SG64939A1 (en) * 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
IT1282683B1 (it) * 1996-02-23 1998-03-31 Montell North America Inc Mescole di bitume e di polimeri olefinici atti alla modifica dei bitumi
AU8491298A (en) 1997-07-14 1999-02-08 Board Of Trustees Of The Leland Stanford Junior University Catalysts and processes for the synthesis of alternating ethylene/alpha-olefin copolymers, and isotactic copolymers thereof
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
EP1157046B1 (en) 1999-12-28 2005-12-07 Basell Polyolefine GmbH Process for the preparation of ethylene polymers
WO2001058968A1 (en) * 2000-02-09 2001-08-16 Idemitsu Petrochemical Co., Ltd. Ethylene-base copolymers, process for producing the same and lubricating oil compositions containing the same
US6858767B1 (en) 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
WO2004044108A1 (ja) * 2002-11-12 2004-05-27 Mitsui Chemicals, Inc. 潤滑油組成物および内燃機関用潤滑油
US7399737B2 (en) 2005-06-13 2008-07-15 Exxonmobil Chemical Patents Inc. Lube additives
KR100994252B1 (ko) * 2007-05-09 2010-11-12 주식회사 엘지화학 에틸렌 알파-올레핀 공중합체
WO2019139355A1 (ko) * 2018-01-11 2019-07-18 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조방법
KR102363189B1 (ko) * 2018-01-11 2022-02-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법
CN116789884B (zh) * 2023-08-28 2024-01-09 万华化学集团股份有限公司 高透光率的乙烯/α-烯烃共聚物

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5008302A (en) * 1987-12-01 1991-04-16 Ciba-Geigy Corporation Titanocenes, the use thereof, and N-substituted pyrroles
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
DE3907964A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
DE3932181A1 (de) * 1989-09-27 1991-04-04 Hoechst Ag Verfahren zur herstellung eines polyolefins
WO1991006583A1 (en) * 1989-10-30 1991-05-16 Fina Research S.A. Syndiotactic copolymers of propylene and olefins
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
CA2068939C (en) * 1991-05-20 1996-04-09 Takashi Ueda Olefin polymerization catalyst and olefin polymerization
EP0552946B1 (en) * 1992-01-23 1997-04-16 Mitsui Petrochemical Industries, Ltd. Ethylene/alpha-olefin/7-methyl-1,6-octadiene copolymer rubber and composition of the same
IT1254547B (it) * 1992-03-23 1995-09-25 Montecatini Tecnologie Srl Copolimeri elastomerici dell'etilene con alfa-olefine.
EP0647243B1 (en) * 1992-06-18 1998-03-18 Montell Technology Company bv Process for preparing an ethylenic copolymer
IT1264406B1 (it) * 1993-05-11 1996-09-23 Spherilene Srl Copolimeri amorfi dell'etilene con alfa-olefine e procedimento per la loro preparazione
IT1264483B1 (it) * 1993-06-30 1996-09-23 Spherilene Srl Copolimeri elastomerici dell'etilene con propilene

Also Published As

Publication number Publication date
NO941741L (no) 1995-01-02
ITMI931405A1 (it) 1994-12-30
IL109435A (en) 1999-07-14
IT1264482B1 (it) 1996-09-23
KR950000742A (ko) 1995-01-03
FI942157L (fi) 1994-12-31
FI942157A0 (fi) 1994-05-10
DE69411330T3 (de) 2002-05-16
CN1051322C (zh) 2000-04-12
AU674208B2 (en) 1996-12-12
AU6184894A (en) 1995-01-12
CN1096304A (zh) 1994-12-14
DE69411330D1 (de) 1998-08-06
RU2140426C1 (ru) 1999-10-27
EP0632066B1 (en) 1998-07-01
EP0632066A1 (en) 1995-01-04
RU94015591A (ru) 1996-04-20
US6221992B1 (en) 2001-04-24
ATE167880T1 (de) 1998-07-15
JPH0733825A (ja) 1995-02-03
ITMI931405A0 (it) 1993-06-30
NO303877B1 (no) 1998-09-14
CA2123336A1 (en) 1994-12-31
US6448351B1 (en) 2002-09-10
FI942157A7 (fi) 1994-12-31
DE69411330T2 (de) 1999-01-07
BR9401058A (pt) 1994-12-27
NO941741D0 (no) 1994-05-10
IL109435A0 (en) 1994-07-31
EP0632066B2 (en) 2001-08-22

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