ES2128795T3 - Procedimiento para recuperar los metales de acumuladores usados de niquel-hidruro metalico. - Google Patents
Procedimiento para recuperar los metales de acumuladores usados de niquel-hidruro metalico.Info
- Publication number
- ES2128795T3 ES2128795T3 ES95941642T ES95941642T ES2128795T3 ES 2128795 T3 ES2128795 T3 ES 2128795T3 ES 95941642 T ES95941642 T ES 95941642T ES 95941642 T ES95941642 T ES 95941642T ES 2128795 T3 ES2128795 T3 ES 2128795T3
- Authority
- ES
- Spain
- Prior art keywords
- sub
- faith
- alloys
- accumulators
- accumulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/409—Mixtures at least one compound being an organo-metallic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Secondary Cells (AREA)
Abstract
MEZCLA DE H{SUB,2}SO{SUB,4}QUE DISUELVE EN PARTICULAR ALEACIONES DE ACUMULACION DE HIDROGENO TIPO AB{SUB,5} QUE FORMAN EL COMPONENTE PRINCIPAL DE ELECTRODOS NEGATIVOS SIN DEJAR RESIDUOS, ADECUADA PARA DESINTEGRAR LA FRACCION FINA QUE CONTIENE EL MATERIAL ACTIVO DE LOS ELECTRODOS NEGATIVO Y POSITIVO, SEPARADA MECANICAMENTE DE LA GRANALLA DE ACUMULADORES. EL EXCESO DE H{SUB,2}O{SUB,2} SE DESTRUYE Y EL FE{SUP,3+} PRESENTE SE REDUCE A FE{SUP,2+} MEDIANTE FLUJO DE LA DISOLUCION DE DESINTEGRACION FUERTEMENTE ACIDA SOBRE LA FRACCION GROSERA METALICA, DE FORMA QUE LAS TIERRAS RARAS DE LAS ALEACIONES DE ACUMULACION PUEDEN PRECIPITARSE COMO SULFATOS DOBLES SIN IMPUREZAS DE FE. PUEDEN RECUPERARSE NI Y CO JUNTOS MEDIANTE EXTRACCION EN DISOLVENTE Y ELECTROLISIS SIMULTANEA; EL PRODUCTO SEPARADO PUEDE UTILIZARSE COMO PREALEACION EN LA PREPARACION DE NUEVAS ALEACIONES DE ACUMULACION DE HIDROGENO. EL PROCESO PUEDE REALIZARSE INCLUSO CUANDO A CAUSA DE ERRORES EN LA EXTRACCION LA GRANALLA DE ACUMULADORES CONTIENE PEQUEÑAS CANTIDADES DE PILAS DE NI/CD.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4445495A DE4445495A1 (de) | 1994-12-20 | 1994-12-20 | Verfahren zur Rückgewinnung von Metallen aus gebrauchten Nickel-Metallhydrid-Akkumulatoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2128795T3 true ES2128795T3 (es) | 1999-05-16 |
Family
ID=6536406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95941642T Expired - Lifetime ES2128795T3 (es) | 1994-12-20 | 1995-12-01 | Procedimiento para recuperar los metales de acumuladores usados de niquel-hidruro metalico. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6110433A (es) |
| EP (1) | EP0806059B1 (es) |
| JP (1) | JPH10510879A (es) |
| CN (1) | CN1171171A (es) |
| AT (1) | ATE175526T1 (es) |
| CA (1) | CA2208320A1 (es) |
| DE (2) | DE4445495A1 (es) |
| DK (1) | DK0806059T3 (es) |
| ES (1) | ES2128795T3 (es) |
| WO (1) | WO1996019841A1 (es) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1179434C (zh) * | 1996-06-26 | 2004-12-08 | 三洋电机株式会社 | 贮氢合金电极和贮氢合金电极的制造方法 |
| DE19727880B4 (de) * | 1997-06-30 | 2009-11-26 | K-Utec Ag Salt Technologies | Verfahren zur Wertstoffrückgewinnung aus Nickel-Metallhydridzellen |
| JP3452769B2 (ja) * | 1997-09-18 | 2003-09-29 | 株式会社東芝 | 電池の処理方法 |
| DE19941231C2 (de) * | 1999-08-30 | 2003-09-25 | Howaldtswerke Deutsche Werft | Verfahren und Anordnung zur Behandlung von Wasserstoffspeichern |
| BE1013311A4 (fr) * | 2000-04-17 | 2001-11-06 | Revatech S A | Procede de recyclage et de valorisation de piles salines et alcalines |
| FR2812973A1 (fr) * | 2000-08-11 | 2002-02-15 | Yves Jehanne | Procede de traitement hydrometallurgique d'accumulateurs usages pour en recuperer des sous-produits valorisables, tels que le nickel et le cobalt |
| RU2178933C1 (ru) * | 2000-11-08 | 2002-01-27 | Закрытое акционерное общество "Компания Сезар" | Способ переработки отработанных щелочных аккумуляторов |
| JP4506002B2 (ja) * | 2001-02-21 | 2010-07-21 | 住友金属鉱山株式会社 | 使用済みニッケル水素二次電池からの有価金属回収方法 |
| US8623822B2 (en) | 2002-03-01 | 2014-01-07 | Bracco Suisse Sa | KDR and VEGF/KDR binding peptides and their use in diagnosis and therapy |
| US7794693B2 (en) | 2002-03-01 | 2010-09-14 | Bracco International B.V. | Targeting vector-phospholipid conjugates |
| US7211240B2 (en) | 2002-03-01 | 2007-05-01 | Bracco International B.V. | Multivalent constructs for therapeutic and diagnostic applications |
| WO2004065621A1 (en) | 2002-03-01 | 2004-08-05 | Dyax Corp. | Kdr and vegf/kdr binding peptides and their use in diagnosis and therapy |
| US7261876B2 (en) | 2002-03-01 | 2007-08-28 | Bracco International Bv | Multivalent constructs for therapeutic and diagnostic applications |
| CN1324758C (zh) * | 2005-04-25 | 2007-07-04 | 武汉理工大学 | 从废旧锂离子电池中分离回收钴的方法 |
| CN101383440B (zh) * | 2007-11-16 | 2010-05-12 | 佛山市邦普镍钴技术有限公司 | 一种从镍氢电池正极废料中回收、制备超细金属镍粉的方法 |
| CN101624651B (zh) * | 2009-06-23 | 2011-07-27 | 四川师范大学 | 镍氢废电池正极材料的浸出方法 |
| JP5012970B2 (ja) * | 2010-07-21 | 2012-08-29 | 住友金属鉱山株式会社 | 使用済みニッケル水素電池に含有される活物質からのニッケル、コバルトの分離方法 |
| US8252085B1 (en) * | 2010-08-23 | 2012-08-28 | Toxco, Inc. | Process for the recovery of metals from used nickel/metal hydride batteries |
| US8246717B1 (en) * | 2010-08-23 | 2012-08-21 | Toxco, Inc. | Process for the recovery of metals from used nickel/metal hydride batteries |
| US8696788B1 (en) | 2010-08-23 | 2014-04-15 | Retriev Technologies Incorporated | Process for the Recovery of AB5 Alloy from Used Nickel/Metal Hydride Batteries |
| EP2444507B1 (en) | 2010-10-20 | 2015-03-04 | Montanuniversität Leoben | Recovery of rare earth metals from waste material by leaching in non-oxidizing acid and by precipitating using sulphates |
| JP5651462B2 (ja) * | 2010-12-27 | 2015-01-14 | Dowaエコシステム株式会社 | リチウムイオン二次電池からの有価物の回収方法、及び有価物を含有する回収物 |
| RU2479078C2 (ru) * | 2011-02-22 | 2013-04-10 | Владимир Фёдорович Воржев | Способ утилизации никель-цинковых щелочных аккумуляторов |
| DE102011000955A1 (de) * | 2011-02-25 | 2012-08-30 | Deutsche Edelstahlwerke Gmbh | Verfahren zur Rückgewinnung von Hartstoffpartikeln |
| JP5565380B2 (ja) * | 2011-06-13 | 2014-08-06 | 住友金属鉱山株式会社 | ニッケルの浸出方法 |
| CN102251118B (zh) * | 2011-06-25 | 2012-10-03 | 鞍山鑫普新材料有限公司 | 一种从废旧镍氢电池中回收金属的方法 |
| CN102251097B (zh) * | 2011-07-08 | 2012-09-26 | 鞍山鑫普新材料有限公司 | 一种从废旧锂电池中回收金属的方法 |
| CN103221557B (zh) * | 2011-11-22 | 2015-04-29 | 住友金属矿山株式会社 | 含镍酸性溶液的制造方法 |
| WO2013103099A1 (ja) * | 2012-01-06 | 2013-07-11 | 日立金属株式会社 | 希土類元素の分離回収方法 |
| KR101210983B1 (ko) * | 2012-05-25 | 2012-12-11 | 한국지질자원연구원 | 혼합 추출제의 스크린 효과를 이용한 코발트 및 니켈로부터 망간의 선택적인 분리 및 회수 방법 |
| JP5958316B2 (ja) * | 2012-12-07 | 2016-07-27 | 住友金属鉱山株式会社 | アルミニウムの分離除去方法、並びにリチウムイオン電池からの有価金属の回収方法 |
| KR102421905B1 (ko) * | 2013-10-02 | 2022-07-18 | 솔베이(소시에떼아노님) | 정제된 과산화수소 수용액의 제조 방법 |
| US10030286B1 (en) | 2013-11-13 | 2018-07-24 | Ii-Vi Incorporated | Method of direct solvent extraction of rare earth metals from an aqueous acid-leached ore slurry |
| CN103757357A (zh) * | 2013-12-29 | 2014-04-30 | 四川师范大学 | 镍镉废电池正极材料的浸出方法 |
| CN103757307B (zh) * | 2013-12-29 | 2016-01-20 | 四川师范大学 | 镍氢废电池正负极混合材料的浸出方法 |
| CN103757310B (zh) * | 2013-12-29 | 2016-01-20 | 四川师范大学 | 镍氢废电池正负极混合材料的浸出方法 |
| CN103725891A (zh) * | 2014-01-27 | 2014-04-16 | 先进储能材料国家工程研究中心有限责任公司 | 一种从废旧镍氢电池中回收稀土的方法 |
| US9670565B2 (en) | 2014-06-20 | 2017-06-06 | Johnson Controls Technology Company | Systems and methods for the hydrometallurgical recovery of lead from spent lead-acid batteries and the preparation of lead oxide for use in new lead-acid batteries |
| US9533273B2 (en) | 2014-06-20 | 2017-01-03 | Johnson Controls Technology Company | Systems and methods for isolating a particulate product when recycling lead from spent lead-acid batteries |
| CN104073638B (zh) * | 2014-06-23 | 2016-05-25 | 先进储能材料国家工程研究中心有限责任公司 | 一种采用使用过的镍氢电池制备球形氢氧化镍的方法 |
| CN104073637B (zh) * | 2014-06-23 | 2016-05-25 | 先进储能材料国家工程研究中心有限责任公司 | 一种制备含镍钴锌离子的强酸盐的方法 |
| JP6314730B2 (ja) * | 2014-07-30 | 2018-04-25 | 住友金属鉱山株式会社 | 廃ニッケル水素電池からの有価金属の回収方法 |
| JP6314814B2 (ja) * | 2014-12-16 | 2018-04-25 | 住友金属鉱山株式会社 | 廃リチウムイオン電池からの有価金属の回収方法 |
| US10808296B2 (en) | 2015-10-30 | 2020-10-20 | Ii-Vi Delaware, Inc. | Selective recovery of rare earth metals from an acidic slurry or acidic solution |
| AU2016344326B2 (en) | 2015-10-30 | 2019-05-16 | Ii-Vi Incorporated | Composite extractant-enhanced polymer resin, method of making the same, and its usage for extraction of valuable metal(s) |
| US10062933B2 (en) | 2015-12-14 | 2018-08-28 | Johnson Controls Technology Company | Hydrometallurgical electrowinning of lead from spent lead-acid batteries |
| CN106252774A (zh) * | 2016-08-25 | 2016-12-21 | 株洲鼎端装备股份有限公司 | 一种废旧镍氢动力电池的回收处理方法 |
| US11186895B2 (en) | 2018-08-07 | 2021-11-30 | University Of Kentucky Research Foundation | Continuous solvent extraction process for generation of high grade rare earth oxides from leachates generated from coal sources |
| RU2703663C1 (ru) * | 2018-11-20 | 2019-10-21 | Общество с ограниченной ответственностью "ЭКОСНАБ" | Система утилизации химических источников тока в виде отработанных батареек |
| CN110605105A (zh) * | 2019-08-23 | 2019-12-24 | 北京航天国环技术有限公司 | 一种从废活性炭中再生金属的方法 |
| CN111041214B (zh) * | 2019-12-23 | 2021-08-31 | 先进储能材料国家工程研究中心有限责任公司 | 利用废旧含锌镍氢电池回收制备α球镍的方法 |
| CN111689530B (zh) * | 2020-05-25 | 2023-08-22 | 荆门市格林美新材料有限公司 | 一种硫酸镍溶液的生产方法和装置 |
| CN115842186A (zh) * | 2022-11-22 | 2023-03-24 | 广东邦普循环科技有限公司 | 一种废锂电池的回收处理方法 |
| KR102667954B1 (ko) * | 2023-06-02 | 2024-05-23 | 고려아연 주식회사 | 아황산가스 환원침출법을 이용한 황산망간 수용액의 제조 방법 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE262845C (es) * | ||||
| DE294681C (es) * | ||||
| FR2131824A1 (en) * | 1971-03-29 | 1972-11-17 | Nickel Le | High purity nickel prodn - from oxide ores (cased) |
| US4041125A (en) * | 1973-06-15 | 1977-08-09 | Forskningsgruppe For Sjeldne Jordarter | Process for separation of the lanthanides |
| DE2704181C3 (de) * | 1977-02-02 | 1980-04-30 | Th. Goldschmidt Ag, 4300 Essen | Flüssig-flüssig-Extraktion von Nickel |
| JPS5967326A (ja) * | 1982-10-07 | 1984-04-17 | Sumitomo Metal Mining Co Ltd | 希土類元素含有合金からの有価金属の回収法 |
| JPS61251514A (ja) * | 1985-04-30 | 1986-11-08 | Mitsubishi Chem Ind Ltd | 高純度希土類酸化物の回収方法 |
| US5180563A (en) * | 1989-10-24 | 1993-01-19 | Gte Products Corporation | Treatment of industrial wastes |
| NL9001825A (nl) * | 1990-08-15 | 1992-03-02 | Tno | Terugwinning van cd en ni uit batterijen. |
| US5129945A (en) * | 1990-10-24 | 1992-07-14 | The United States Of America As Represented By The Secretary Of The Interior | Scrap treatment method for rare earth transition metal alloys |
| DE4224884A1 (de) * | 1992-07-28 | 1994-02-03 | Batenus Gmbh & Co Kg | Verfahren zur Rückgewinnung von Rohstoffen aus vorsortiert gesammeltem, verbrauchten Gut, insbesondere aus verbrauchten elektrochemischen Batterien und Akkumulatoren |
| CH684225A5 (de) * | 1992-09-02 | 1994-07-29 | Inter Recycling Ag | Verfahren zum Entsorgen von Nickel-Cadmium- oder Nickel-Hydrid-Zellen. |
| KR970007520B1 (ko) * | 1993-04-05 | 1997-05-09 | 산도쿠긴조쿠 고교 가부시키가이샤 | 니켈수소 2차 전지로부터의 유효금속회수법 |
| US5429887A (en) * | 1994-05-16 | 1995-07-04 | The United States Of America As Represented By The Secretary Of The Interior | Process for treating AB5 nickel-metal hydride battery scrap |
| US5728355A (en) * | 1995-09-27 | 1998-03-17 | Santoku Metal Industry Co., Ltd. | Method for recovering reusable rare earth compounds |
-
1994
- 1994-12-20 DE DE4445495A patent/DE4445495A1/de not_active Withdrawn
-
1995
- 1995-12-01 ES ES95941642T patent/ES2128795T3/es not_active Expired - Lifetime
- 1995-12-01 AT AT95941642T patent/ATE175526T1/de not_active IP Right Cessation
- 1995-12-01 JP JP51945796A patent/JPH10510879A/ja active Pending
- 1995-12-01 WO PCT/EP1995/004736 patent/WO1996019841A1/de not_active Ceased
- 1995-12-01 DK DK95941642T patent/DK0806059T3/da active
- 1995-12-01 EP EP95941642A patent/EP0806059B1/de not_active Expired - Lifetime
- 1995-12-01 DE DE59504764T patent/DE59504764D1/de not_active Expired - Lifetime
- 1995-12-01 CN CN95196981A patent/CN1171171A/zh active Pending
- 1995-12-01 CA CA 2208320 patent/CA2208320A1/en not_active Abandoned
-
1997
- 1997-06-16 US US08/876,345 patent/US6110433A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE59504764D1 (de) | 1999-02-18 |
| DE4445495A1 (de) | 1996-06-27 |
| DK0806059T3 (da) | 1999-08-30 |
| ATE175526T1 (de) | 1999-01-15 |
| CN1171171A (zh) | 1998-01-21 |
| WO1996019841A1 (de) | 1996-06-27 |
| EP0806059A1 (de) | 1997-11-12 |
| US6110433A (en) | 2000-08-29 |
| CA2208320A1 (en) | 1996-06-27 |
| EP0806059B1 (de) | 1999-01-07 |
| JPH10510879A (ja) | 1998-10-20 |
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