ES2129648T3 - Estructura para destilacion catalitica. - Google Patents
Estructura para destilacion catalitica.Info
- Publication number
- ES2129648T3 ES2129648T3 ES94920020T ES94920020T ES2129648T3 ES 2129648 T3 ES2129648 T3 ES 2129648T3 ES 94920020 T ES94920020 T ES 94920020T ES 94920020 T ES94920020 T ES 94920020T ES 2129648 T3 ES2129648 T3 ES 2129648T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- bags
- gas permeable
- elements
- catalytic distillation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000004821 distillation Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 4
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004508 fractional distillation Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000011859 microparticle Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/32—Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/322—Basic shape of the elements
- B01J2219/32203—Sheets
- B01J2219/3221—Corrugated sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/322—Basic shape of the elements
- B01J2219/32203—Sheets
- B01J2219/32213—Plurality of essentially parallel sheets
- B01J2219/3222—Plurality of essentially parallel sheets with sheets having corrugations which intersect at an angle different from 90 degrees
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/322—Basic shape of the elements
- B01J2219/32203—Sheets
- B01J2219/32224—Sheets characterised by the orientation of the sheet
- B01J2219/32227—Vertical orientation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/324—Composition or microstructure of the elements
- B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S203/00—Distillation: processes, separatory
- Y10S203/06—Reactor-distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
UNA ESTRUCTURA DE DESTILACION CATALITICA (10) QUE TIENE UNA PLURALIDAD DE CATALIZADORES DISPUESTOS VERTICALMENTE Y ONDULADOS QUE CONTIENEN ELEMENTOS (12) SEPARADOS POR ELEMENTO ESPACIADORES INERTES (24). EL CATALIZADOR CONTIENE ELEMENTOS (12) QUE TIENEN CADA UNO DOS CAPAS DE MATERIAL PERMEABLE AL GAS (18,20) COMO UNA MALLA DE ALAMBRE, UNIDOS ENTRE SI EN INTERVALOS ESPACIADOS REGULARMENTE (13) PARA FORMAR UNA SOLA LAMINA (12) CON BOLSAS (22) DISPUESTAS EN LA SUPERFICIE. UN CATALIZADOR DE MICROPARTICULAS (26) SE ENCUENTRA DISPUESTO DENTRO DE LAS BOLSAS (22). ESTE PROPORCIONA UNA ZONA DE REACCION EN LA QUE LAS REACCIONES CATALITICAS PUEDEN PRODUCIRSE, Y LAS LAMINAS PERMEABLES AL GAS (18,22) PROPORCIONAN SUPERFICIES DE TRANSFERENCIA DE MASA PARA EFECTUAR UNA DESTILACION FRACCIONADA. LOS ELEMENTOS ESPACIADORES (14) PERMITEN UNA VARIACION DE LA DENSIDAD Y CARGA DEL CATALIZADOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/075,328 US5348710A (en) | 1993-06-11 | 1993-06-11 | Catalytic distillation structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2129648T3 true ES2129648T3 (es) | 1999-06-16 |
Family
ID=22124991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94920020T Expired - Lifetime ES2129648T3 (es) | 1993-06-11 | 1994-05-19 | Estructura para destilacion catalitica. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5348710A (es) |
| EP (1) | EP0703821B1 (es) |
| JP (1) | JP3589667B2 (es) |
| KR (1) | KR100299275B1 (es) |
| CN (1) | CN1051246C (es) |
| AU (1) | AU674596B2 (es) |
| DE (1) | DE69417556T2 (es) |
| ES (1) | ES2129648T3 (es) |
| RU (1) | RU2165290C2 (es) |
| TW (1) | TW262389B (es) |
| WO (1) | WO1994029010A1 (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5364829A (en) * | 1991-08-30 | 1994-11-15 | Matsushita Electric Industrial Co., Ltd. | Rewritable recording medium and a method of recording in the same |
| US5321163A (en) * | 1993-09-09 | 1994-06-14 | Chemical Research & Licensing Company | Multi-purpose catalytic distillation column and eterification process using same |
| US5730843A (en) * | 1995-12-29 | 1998-03-24 | Chemical Research & Licensing Company | Catalytic distillation structure |
| US5684213A (en) * | 1996-03-25 | 1997-11-04 | Chemical Research & Licensing Company | Method for the preparation of dialkyl ethers |
| US5925685A (en) * | 1996-11-18 | 1999-07-20 | Catalytic Distillation Technologies | Method for carrying out heterogeneous catalysis |
| US5942456A (en) * | 1996-12-09 | 1999-08-24 | Catalytic Distillation Technologies | Multi-functional catalytic distillation structure |
| US6045762A (en) * | 1997-01-22 | 2000-04-04 | Governors Of The University Of Alberta | Apparatus for catalytic distillation |
| DE29807007U1 (de) * | 1998-04-18 | 1998-07-30 | Górak, Andrzej, Prof. Dr.-Ing., 58454 Witten | Packung für Stoffaustauschkolonnen |
| US6000685A (en) * | 1998-06-29 | 1999-12-14 | Catalytic Distillation Technologies | Gas/liquid contact structure |
| US6414205B1 (en) | 2000-03-24 | 2002-07-02 | Catalytic Distillation Technologies | Process for the removal of MAPD from hydrocarbon streams |
| DE10159821A1 (de) * | 2001-12-06 | 2003-06-18 | Basf Ag | Vorrichtung und Verfahren zur Durchführung von heterogen katalysierter Reaktivdestillationen, insbesondere zur Herstellung von Pseudoionen |
| US20040000472A1 (en) * | 2002-03-15 | 2004-01-01 | Catalytic Distillation Technologies | Distillation system |
| DE10238370A1 (de) * | 2002-08-22 | 2004-03-04 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Isobuten aus technischen Methyl-tert.-butylether |
| US6846959B2 (en) | 2002-10-07 | 2005-01-25 | Air Products And Chemicals, Inc. | Process for producing alkanolamines |
| JP2007521298A (ja) * | 2003-06-30 | 2007-08-02 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | アルキルベンゼンの生成方法 |
| US7358411B2 (en) * | 2003-06-30 | 2008-04-15 | Shell Oil Company | Hydrocracking of diphenylalkanes |
| US7193093B2 (en) * | 2003-06-30 | 2007-03-20 | Shell Oil Company | Process for producing alkylene oxide |
| WO2005056503A1 (en) * | 2003-12-12 | 2005-06-23 | University Of Waterloo | Composite catalyst for the selective oligomerization of lower alkenes and the production of high octane products |
| US20070095725A1 (en) * | 2005-10-31 | 2007-05-03 | Catalytic Distillation Technologies | Processing of FCC naphtha |
| US20080146856A1 (en) * | 2006-12-19 | 2008-06-19 | Leyshon David W | Propylene production |
| US7816572B2 (en) * | 2007-08-07 | 2010-10-19 | Lyondell Chemical Technology, L.P. | Propylene and isoprene production |
| US9139503B2 (en) * | 2007-09-10 | 2015-09-22 | Lummus Technology Inc. | Method for the production of dimethyl ether |
| US20090183981A1 (en) * | 2008-01-23 | 2009-07-23 | Catalytic Distillation Technologies | Integrated pyrolysis gasoline treatment process |
| US8492603B2 (en) * | 2009-01-12 | 2013-07-23 | Catalytic Distillation Technologies | Selectivated isoolefin dimerization using metalized resins |
| US8378150B2 (en) | 2009-08-12 | 2013-02-19 | Catalytic Distillation Technologies | Process for the production of dimethyl ether |
| US9272965B2 (en) * | 2009-12-22 | 2016-03-01 | Catalytic Distillation Technologies | Process for the conversion of alcohols to olefins |
| DE102010028788B4 (de) | 2010-05-10 | 2022-03-31 | Tutech Innovation Gmbh | Ein in der Reaktivrektifikation einsetzbarer, einen Biokatalysator aufweisender Kolonneneinbau und dessen Verwendung in der Reaktivrektifikation |
| WO2011143215A2 (en) | 2010-05-10 | 2011-11-17 | Catalytic Distillation Technologies | Production of jet and other heavy fuels from isobutanol |
| WO2012065969A1 (de) * | 2010-11-18 | 2012-05-24 | Bayer Materialscience Ag | Chemischer reaktor mit drahtgestrick-maschenware als halteeinrichtung für partikel |
| KR101489098B1 (ko) * | 2012-01-25 | 2015-02-02 | 아사히 가세이 케미칼즈 가부시키가이샤 | 분리 방법 |
| CN102824890B (zh) * | 2012-09-18 | 2014-10-22 | 天津大学 | 一种具有交替流动结构的催化精馏填料 |
| CN104324683A (zh) * | 2014-10-27 | 2015-02-04 | 汤恩旗 | 一种可加工的催化丝网带 |
| CN104587945A (zh) * | 2015-01-24 | 2015-05-06 | 福州大学 | 一种催化精馏塔塔内规整催化填料及其制备方法 |
| CN105126735A (zh) * | 2015-08-04 | 2015-12-09 | 福州大学 | 一种催化精馏塔塔内催化填料及其制备方法 |
| US10655074B2 (en) * | 2017-02-12 | 2020-05-19 | Mag{hacek over (e)}m{hacek over (a)} Technology LLC | Multi-stage process and device for reducing environmental contaminates in heavy marine fuel oil |
| US12071592B2 (en) * | 2017-02-12 | 2024-08-27 | Magēmā Technology LLC | Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil |
| US10604709B2 (en) * | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| CN106943981A (zh) * | 2017-05-04 | 2017-07-14 | 凯瑞环保科技股份有限公司 | 一种甲醇氧化用的设备 |
| WO2020041696A1 (en) | 2018-08-23 | 2020-02-27 | Lummus Technology Llc | Process for the production of high purity isobutylene |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH477902A (de) * | 1967-08-16 | 1969-09-15 | Sulzer Ag | Verfahren zur Herstellung von für Stoffaustauschkolonnen bestimmten Packungskörpern |
| CH578371A5 (es) * | 1973-05-23 | 1976-08-13 | Sulzer Ag | |
| CH608380A5 (en) * | 1976-01-16 | 1979-01-15 | Sulzer Ag | Packing body in rectifying columns |
| CH617357A5 (es) * | 1977-05-12 | 1980-05-30 | Sulzer Ag | |
| US4302356A (en) * | 1978-07-27 | 1981-11-24 | Chemical Research & Licensing Co. | Process for separating isobutene from C4 streams |
| DE2967531D1 (en) * | 1978-07-27 | 1985-11-21 | Chemical Res & Licensin | Catalytic distillation process and catalyst |
| US4215011A (en) * | 1979-02-21 | 1980-07-29 | Chemical Research And Licensing Company | Catalyst system for separating isobutene from C4 streams |
| CH656321A5 (de) * | 1981-07-30 | 1986-06-30 | Sulzer Ag | Einbauelement fuer eine vorrichtung fuer stoff- und/oder direkten waermeaustausch oder mischen. |
| CH653566A5 (de) * | 1981-07-30 | 1986-01-15 | Sulzer Ag | Kolonne fuer stoff- und direkten waermeaustausch. |
| EP0070915A1 (de) * | 1981-07-30 | 1983-02-09 | GebràDer Sulzer Aktiengesellschaft | Einbauelement für eine Vorrichtung für Stoff- und direkten Wärmeaustausch und Mischen |
| CH653565A5 (de) * | 1981-07-30 | 1986-01-15 | Sulzer Ag | Vorrichtung zum stoff- und/oder direkten waermeaustausch oder mischen. |
| CH653909A5 (de) * | 1981-07-30 | 1986-01-31 | Sulzer Ag | Kolonne fuer stoff- und/oder waermeaustauschverfahren. |
| US4443559A (en) * | 1981-09-30 | 1984-04-17 | Chemical Research & Licensing Company | Catalytic distillation structure |
| US4536373A (en) * | 1982-06-21 | 1985-08-20 | Chemical Research & Licensing Company | Contact structure for use in catalytic distillation |
| DE3574937D1 (de) * | 1985-05-14 | 1990-02-01 | Sulzer Ag | Reaktor zum durchfuehren von heterogenen, katalysierten chemischen reaktionen. |
| SU1576193A1 (ru) * | 1988-05-25 | 1990-07-07 | Московский Институт Химического Машиностроения | Каталитический элемент дл неподвижного сло катализатора в каналах гетерогенно-каталитических реакторов |
| SU1595558A1 (ru) * | 1988-08-04 | 1990-09-30 | Институт органической химии Уральского отделения АН СССР | Способ приготовлени носител дл катализатора сотовой структуры |
| EP0396650B2 (de) * | 1988-09-02 | 1995-04-12 | GebràDer Sulzer Aktiengesellschaft | Vorrichtung zur durchführung katalysierter reaktionen |
| US5073236A (en) * | 1989-11-13 | 1991-12-17 | Gelbein Abraham P | Process and structure for effecting catalytic reactions in distillation structure |
| US5073296A (en) * | 1990-04-17 | 1991-12-17 | Isp Investments Inc. | Preparation of discrete microdroplets of an oil in water |
| US5057468A (en) * | 1990-05-21 | 1991-10-15 | Chemical Research & Licensing Company | Catalytic distillation structure |
| EP0466954A1 (en) * | 1990-07-17 | 1992-01-22 | CHEMICAL RESEARCH & LICENSING COMPANY | Catalytic distillation |
| FR2671492B1 (fr) * | 1991-01-11 | 1994-07-22 | Benzaria Jacques | Conteneur pour materiaux solides granulaires, sa fabrication et ses applications notamment en catalyse et en adsorption. |
| US5189001A (en) * | 1991-09-23 | 1993-02-23 | Chemical Research & Licensing Company | Catalytic distillation structure |
-
1993
- 1993-06-11 US US08/075,328 patent/US5348710A/en not_active Expired - Lifetime
-
1994
- 1994-05-19 WO PCT/US1994/005621 patent/WO1994029010A1/en not_active Ceased
- 1994-05-19 ES ES94920020T patent/ES2129648T3/es not_active Expired - Lifetime
- 1994-05-19 JP JP50180895A patent/JP3589667B2/ja not_active Expired - Fee Related
- 1994-05-19 AU AU70949/94A patent/AU674596B2/en not_active Ceased
- 1994-05-19 DE DE69417556T patent/DE69417556T2/de not_active Expired - Fee Related
- 1994-05-19 CN CN94192878A patent/CN1051246C/zh not_active Expired - Fee Related
- 1994-05-19 RU RU96102598/04A patent/RU2165290C2/ru not_active IP Right Cessation
- 1994-05-19 EP EP94920020A patent/EP0703821B1/en not_active Expired - Lifetime
- 1994-05-19 KR KR1019950705651A patent/KR100299275B1/ko not_active Expired - Fee Related
- 1994-06-17 TW TW083105505A patent/TW262389B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CN1051246C (zh) | 2000-04-12 |
| RU2165290C2 (ru) | 2001-04-20 |
| AU674596B2 (en) | 1997-01-02 |
| JP3589667B2 (ja) | 2004-11-17 |
| DE69417556D1 (de) | 1999-05-06 |
| KR100299275B1 (ko) | 2001-10-22 |
| EP0703821A4 (en) | 1997-03-05 |
| WO1994029010A1 (en) | 1994-12-22 |
| US5348710A (en) | 1994-09-20 |
| JPH09501864A (ja) | 1997-02-25 |
| DE69417556T2 (de) | 1999-08-12 |
| EP0703821A1 (en) | 1996-04-03 |
| AU7094994A (en) | 1995-01-03 |
| KR960703034A (ko) | 1996-06-19 |
| EP0703821B1 (en) | 1999-03-31 |
| TW262389B (es) | 1995-11-11 |
| CN1127480A (zh) | 1996-07-24 |
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