ES2134496T3 - Procedimiento de polimerizacion por radicales libres. - Google Patents

Procedimiento de polimerizacion por radicales libres.

Info

Publication number
ES2134496T3
ES2134496T3 ES95933503T ES95933503T ES2134496T3 ES 2134496 T3 ES2134496 T3 ES 2134496T3 ES 95933503 T ES95933503 T ES 95933503T ES 95933503 T ES95933503 T ES 95933503T ES 2134496 T3 ES2134496 T3 ES 2134496T3
Authority
ES
Spain
Prior art keywords
carbon atoms
pct
ring
group
polymerisation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95933503T
Other languages
English (en)
Inventor
David Mark Haddleton
Andrew Victor Graham Muir
Stephen William Leeming
John Patrick O'donnell
Stuart Nicholas Richards
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syngenta Ltd
Original Assignee
Zeneca Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB9421771A external-priority patent/GB9421771D0/en
Priority claimed from GBGB9508625.2A external-priority patent/GB9508625D0/en
Application filed by Zeneca Ltd filed Critical Zeneca Ltd
Application granted granted Critical
Publication of ES2134496T3 publication Critical patent/ES2134496T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/022—Boron compounds without C-boron linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Lubricants (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO DE POLIMERIZACION RADICALAR, DE MONOMERO(S) OLEFINICAMENTE INSATURADO(S), UTILIZANDO UN INICIADOR DE RADICALES LIBRES, REALIZANDOSE A CABO LA POLIMERIZACION EN PRESENCIA DE UN COMPUESTO RESPONSABLE DEL CONTROL DEL PESO MOLECULAR, SIENDO DICHO COMPUESTO UN QUELATO DE COII, DE FORMULA (I), DONDE CADA GRUPO X, INDEPENDIENTEMENTE EN CADA CICLO Y EN DIFERENTES CICLOS, ES UN SUSTITUYENTE SELECCIONADO ENTRE ALQUILO DE 1 A 14 ATOMOS DE CARBONO, Y CICLOALQUILO DE 6 A 14 ATOMOS DE CARBONO; N, INDEPENDIENTEMENTE EN CADA CICLO, ES DE 0 A 5, A CONDICION DE QUE, EN UN CICLO AL MENOS, SEA DE 1 A 5; Z, INDEPENDIENTEMENTE EN CADA ATOMO DE BORO, SE SELECCIONA ENTRE F, CL, BR, OH, ALCOXI DE 1 A 12 ATOMOS DE CARBONO, ARILOXI DE 6 A 12 ATOMOS DE CARBONO, ALQUILO DE 1 A 12 ATOMOS DE CARBONO, Y ARILO DE 6 A 12 ATOMOS DE CARBONO; O BIEN, DOS GRUPOS Z UNIDOS, PROPORCIONAN EN UNO O AMBOS ATOMOS DE BORO UN GRUPO -O-(Q)-O-, DONDE Q ES UN ARILO DIVALENTE O UN GRUPO DE UNION ALICICLICO O UNGRUPO DE UNION ALQUILENO; O DOS GRUPOS Z UNIDOS, SOBRE UNO O AMBOS ATOMOS DE BORO, PROPORCIONAN UN GRUPO DE UNION 1,5CICLOOCTANODIIL. DICHO COMPUESTO DE CONTROL DEL PESO MOLECULAR, PUEDE SER TAMBIEN UN ANALOGO DE COIII DE DICHO QUELATO DE COII DE FORMULA (I), EN EL CUAL EL ATOMO DE COBALTO ESTA UNIDO ADICIONALMENTE DE FORMA COVALENTE, EN UNA ORIENTACION QUE FORMA ANGULOS RECTOS CON EL SISTEMA CICLICO DEL QUELATO MACROCICLICO, A H, HALURO, U OTRO ANION, O A UN GRUPO ORGANICO DISOCIABLE HOMOLITICAMENTE; Y DONDE, OPCIONALMENTE, AL MENOS UN LIGANDO ADICIONAL ESTA COORDINADO CON EL ATOMO DE COII O COIII, SIENDO UN LIGANDO TAL QUE NO MODIFIQUE LA VALENCIA DEL CO. ASIMISMO, SE DESCRIBEN LOS QUELATOS UTILIZADOS EN DICHO PROCEDIMIENTO DE POLIMERIZACION, UN PROCEDIMIENTO DE PRODUCCION DE LOS MISMOS, Y LA UTILIZACION DE LOS OLIGOMEROS OBTENIDOS MEDIANTE DICHO PROCEDIMIENTO, EN DIVERSAS APLICACIONES.
ES95933503T 1994-10-28 1995-10-09 Procedimiento de polimerizacion por radicales libres. Expired - Lifetime ES2134496T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9421771A GB9421771D0 (en) 1994-10-28 1994-10-28 Free radical polymerisation process
GBGB9508625.2A GB9508625D0 (en) 1995-04-28 1995-04-28 Free radical polymerisation process

Publications (1)

Publication Number Publication Date
ES2134496T3 true ES2134496T3 (es) 1999-10-01

Family

ID=26305889

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95933503T Expired - Lifetime ES2134496T3 (es) 1994-10-28 1995-10-09 Procedimiento de polimerizacion por radicales libres.

Country Status (11)

Country Link
US (1) US5962609A (es)
EP (1) EP0788518B1 (es)
JP (1) JP3587530B2 (es)
AT (1) ATE180791T1 (es)
AU (1) AU701611B2 (es)
BR (1) BR9509535A (es)
DE (1) DE69510079T2 (es)
DK (1) DK0788518T3 (es)
ES (1) ES2134496T3 (es)
MX (1) MX9702791A (es)
WO (1) WO1996013527A1 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AUPM930494A0 (en) * 1994-11-09 1994-12-01 Commonwealth Scientific And Industrial Research Organisation Polymerization in aqueous media
KR970027117A (ko) * 1995-11-10 1997-06-24 고사이 아끼오 스티렌 기재 중합체의 제조 방법
DE69725557T2 (de) * 1996-02-23 2004-04-29 E.I. Du Pont De Nemours And Co., Wilmington Synthese verzweigter polymerer
US6624261B1 (en) 1997-02-18 2003-09-23 E. I. Du Pont Nemours And Company Catalytic polymerization process
US6121181A (en) * 1998-08-07 2000-09-19 Equistar Chemicals, L.P. Cyclic oligomeric oxo- and imido- metal complexes as olefin polymerization catalysts
US6180690B1 (en) * 1998-11-04 2001-01-30 E. I. Du Pont De Nemours And Company Alkoxysilane binders as additives in ink jet inks
JP3744246B2 (ja) * 1998-12-08 2006-02-08 住友化学株式会社 ポリ（ｐ−ｔ−ブトキシスチレン）の製造法
JP2001131472A (ja) * 1999-11-01 2001-05-15 Kansai Paint Co Ltd カチオン電着塗料用樹脂組成物
US20040220329A1 (en) * 2003-04-29 2004-11-04 Solomon Robert David Aqueous polymer composition and coating produced therefrom
US7022792B2 (en) 2004-03-16 2006-04-04 E. I. Dupont De Nemours And Company Initiation of polymerization by hydrogen atom donation
GB0409448D0 (en) 2004-04-28 2004-06-02 Avecia Bv Free radical polymerisation process
US7402646B2 (en) * 2005-05-27 2008-07-22 E. I. Du Pont De Nemours And Company Polymerization of diisopropenylbenzene
TWI437009B (zh) 2007-04-24 2014-05-11 Solvay Solexis Spa １，１－二氟乙烯共聚物類
JP5465397B2 (ja) 2007-07-12 2014-04-09 ローム アンド ハース カンパニー ポリマーフィルム
JP5404222B2 (ja) * 2009-07-14 2014-01-29 三菱レイヨン株式会社 ビニル系ポリマーの製造方法
CN104893411A (zh) 2009-12-17 2015-09-09 帝斯曼知识产权资产管理有限公司 聚合物组合物
JP5637500B2 (ja) * 2011-02-01 2014-12-10 三菱レイヨン株式会社 ビニル系ポリマーの製造方法及びビニル系ポリマー
JP5835613B2 (ja) * 2011-12-06 2015-12-24 三菱レイヨン株式会社 末端二重結合を有する化合物の製造法
EP2792691B1 (en) * 2011-12-14 2016-12-07 Mitsubishi Rayon Co., Ltd. Methacrylic acid ester polymer, method for producing same, active energy ray-curable composition, and optical recording medium
WO2013113937A1 (en) 2012-02-03 2013-08-08 Dsm Ip Assets B.V. Polymer, process and composition
ES2688532T3 (es) 2013-01-18 2018-11-05 Basf Se Composiciones de recubrimiento a base de dispersión acrílica
EA028352B1 (ru) * 2013-03-28 2017-11-30 Сауди Бейсик Индастриз Корпорейшн Способ полимеризации высокого давления для получения полиэтилена
ES2665813T3 (es) 2013-11-04 2018-04-27 Lubrizol Advanced Materials, Inc. Dispersantes acrílicos con grupos de anclaje imida aromáticos fusionados
JP6713322B2 (ja) * 2016-03-31 2020-06-24 株式会社クラレ ポリビニルエステルの製造方法およびポリビニルアルコールの製造方法
WO2023068375A1 (ja) 2021-10-22 2023-04-27 三菱ケミカル株式会社 樹脂組成物、樹脂組成物の製造方法、成形材料、及び物品
EP4481000B1 (en) 2022-02-15 2026-07-15 Mitsubishi Chemical Corporation Thermoplastic resin composition, molded material, and molded body
JPWO2024262460A1 (es) 2023-06-21 2024-12-26
CN121605155A (zh) 2023-09-19 2026-03-03 三菱化学株式会社 树脂组合物、成型材料、树脂成型体以及膜及其制造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4526945A (en) * 1984-03-21 1985-07-02 Scm Corporation Low molecular weight polymers and copolymers
US4680352A (en) * 1985-03-01 1987-07-14 E. I. Du Pont De Nemours And Company Cobalt (II) chelates as chain transfer agents in free radical polymerizations
US4694054A (en) * 1985-03-01 1987-09-15 E. I. Du Pont De Nemours And Company Cobalt(II) chelates as chain transfer agents in free radical polymerizations
WO1987003605A1 (en) * 1985-12-03 1987-06-18 Commonwealth Scientific And Industrial Research Or Oligomerization process
US4680354A (en) * 1986-05-21 1987-07-14 The Glidden Company Low molecular weight polymers and copolymers
GB9316221D0 (en) * 1993-08-05 1993-09-22 Zeneca Ltd Production of polymer emulsions
GB9316525D0 (en) * 1993-08-09 1993-09-22 Zeneca Ltd Free radical polymerisation process
EP0739359B1 (en) * 1993-12-20 2000-03-22 Avecia Limited Free radical polymerisation process
GB9407129D0 (en) * 1994-04-11 1994-06-01 Zeneca Ltd Free radical polymerisation process

Also Published As

Publication number Publication date
AU701611B2 (en) 1999-02-04
DK0788518T3 (da) 1999-12-27
JP3587530B2 (ja) 2004-11-10
ATE180791T1 (de) 1999-06-15
WO1996013527A1 (en) 1996-05-09
US5962609A (en) 1999-10-05
AU3613595A (en) 1996-05-23
DE69510079T2 (de) 1999-10-14
DE69510079D1 (de) 1999-07-08
JPH10508333A (ja) 1998-08-18
EP0788518B1 (en) 1999-06-02
MX9702791A (es) 1997-06-28
EP0788518A1 (en) 1997-08-13
BR9509535A (pt) 1997-09-30

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