ES2136125T3 - Aplicacion de boruros refractarios para proteger componentes que contienen carbono de celdas de fabricacion de aluminio. - Google Patents
Aplicacion de boruros refractarios para proteger componentes que contienen carbono de celdas de fabricacion de aluminio.Info
- Publication number
- ES2136125T3 ES2136125T3 ES93915165T ES93915165T ES2136125T3 ES 2136125 T3 ES2136125 T3 ES 2136125T3 ES 93915165 T ES93915165 T ES 93915165T ES 93915165 T ES93915165 T ES 93915165T ES 2136125 T3 ES2136125 T3 ES 2136125T3
- Authority
- ES
- Spain
- Prior art keywords
- application
- containing components
- manufacturing cells
- components
- aluminum manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052782 aluminium Inorganic materials 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001722 carbon compounds Chemical class 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 238000007596 consolidation process Methods 0.000 abstract 1
- 229910001610 cryolite Inorganic materials 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000004570 mortar (masonry) Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5053—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials non-oxide ceramics
- C04B41/5062—Borides, Nitrides or Silicides
- C04B41/507—Borides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5053—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials non-oxide ceramics
- C04B41/5062—Borides, Nitrides or Silicides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/87—Ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/085—Cell construction, e.g. bottoms, walls, cathodes characterised by its non electrically conducting heat insulating parts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
- C25C3/125—Anodes based on carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Metals (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Laminated Bodies (AREA)
Abstract
UNOS COMPONENTES COMPUESTOS DE CARBONO (1,2,5) DE CELULAS PARA LA PRODUCCION DE ALUMINIO (8) MEDIANTE LA ELECTROLISIS DE ALUMINA DISUELTA EN UN ELECTROLITO FUNDIDO DE BASE CRIOLITA (7) ESTAN PROTEGIDOS DEL ATAQUE DE COMPONENTES LIQUIDOS Y/O GASEOSOS DEL ELECTROLITO (7) EN FORMA DE ELEMENTOS, IONES O COMPONENTES, MEDIANTE UN REVESTIMIENTO REFRACTARIO DE BORURO (9,10,11) APLICADO DESDE UN MORTERO COMPUESTO DE BORURO REFRACTARIO PARTICULADO PREFORMADO EN UN PORTADOR COLOIDAL QUE ESTA SECADO Y CALENTADO PARA CONSOLIDAR EL REVESTIMIENTO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/898,052 US5364513A (en) | 1992-06-12 | 1992-06-12 | Electrochemical cell component or other material having oxidation preventive coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2136125T3 true ES2136125T3 (es) | 1999-11-16 |
Family
ID=25408859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93915165T Expired - Lifetime ES2136125T3 (es) | 1992-06-12 | 1993-05-28 | Aplicacion de boruros refractarios para proteger componentes que contienen carbono de celdas de fabricacion de aluminio. |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5364513A (es) |
| EP (2) | EP0663022B1 (es) |
| AU (1) | AU664475B2 (es) |
| BR (1) | BR9306538A (es) |
| CA (1) | CA2137816C (es) |
| DE (2) | DE69325815T2 (es) |
| ES (1) | ES2136125T3 (es) |
| HU (1) | HU218031B (es) |
| RU (1) | RU2135643C1 (es) |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IS3943A (is) * | 1991-11-07 | 1993-05-08 | Comalco Aluminium Limited | Forskautsker þar sem fram fer stöðug forbrennsla eða -herðing |
| US6001236A (en) | 1992-04-01 | 1999-12-14 | Moltech Invent S.A. | Application of refractory borides to protect carbon-containing components of aluminium production cells |
| US5651874A (en) | 1993-05-28 | 1997-07-29 | Moltech Invent S.A. | Method for production of aluminum utilizing protected carbon-containing components |
| ES2141764T3 (es) * | 1992-04-01 | 2000-04-01 | Moltech Invent Sa | Prevencion de la oxidacion de materiales carbonosos y otros a temperaturas elevadas. |
| US5534119A (en) * | 1992-06-12 | 1996-07-09 | Sekhar; Jainagesh A. | Method of reducing erosion of carbon-containing components of aluminum production cells |
| US5413689A (en) * | 1992-06-12 | 1995-05-09 | Moltech Invent S.A. | Carbon containing body or mass useful as cell component |
| US5590383A (en) * | 1993-03-12 | 1996-12-31 | Micropyretics Heaters International, Inc. | Porous membranes and methods for making |
| PL311202A1 (en) * | 1993-04-19 | 1996-02-05 | Moltech Invent Sa | Method of conditioning components of chambers used in aluminium production processes |
| US5486278A (en) * | 1993-06-02 | 1996-01-23 | Moltech Invent S.A. | Treating prebaked carbon components for aluminum production, the treated components thereof, and the components use in an electrolytic cell |
| US5679224A (en) * | 1993-11-23 | 1997-10-21 | Moltech Invent S.A. | Treated carbon or carbon-based cathodic components of aluminum production cells |
| CA2162027A1 (en) * | 1994-03-03 | 1995-09-08 | Osaka Gas Company Limited | Binder composition for friction materials, and friction material |
| US5534130A (en) * | 1994-06-07 | 1996-07-09 | Moltech Invent S.A. | Application of phosphates of aluminum to carbonaceous components of aluminum production cells |
| JP3399650B2 (ja) * | 1994-08-11 | 2003-04-21 | 邦雄 平石 | 耐熱・耐酸化被覆材の被覆処理方法 |
| CA2199288C (en) | 1994-09-08 | 2008-06-17 | Vittorio De Nora | Aluminium electrowinning cell with improved carbon cathode blocks |
| US5472578A (en) * | 1994-09-16 | 1995-12-05 | Moltech Invent S.A. | Aluminium production cell and assembly |
| US5492604A (en) * | 1994-12-28 | 1996-02-20 | Aluminum Company Of America | Coating composition for carbon electrodes |
| US5594931A (en) * | 1995-05-09 | 1997-01-14 | Newcomer Products, Inc. | Layered composite carbide product and method of manufacture |
| US5753163A (en) | 1995-08-28 | 1998-05-19 | Moltech. Invent S.A. | Production of bodies of refractory borides |
| US5753382A (en) * | 1996-01-10 | 1998-05-19 | Moltech Invent S.A. | Carbon bodies resistant to deterioration by oxidizing gases |
| EP0798280B1 (en) * | 1996-03-29 | 2001-09-12 | Kabushiki Kaisha Toshiba | Ceramic matrix composite and method of manufacturing the same |
| CA2268931A1 (en) * | 1996-10-18 | 1998-04-30 | Moltech Invent S.A. | The start-up of aluminium electrowinning cells |
| US5985114A (en) * | 1997-09-15 | 1999-11-16 | Moltech Invent S.A. | Carbon bodies resistant to deterioration by oxidizing gases |
| US20040069454A1 (en) * | 1998-11-02 | 2004-04-15 | Bonsignore Patrick V. | Composition for enhancing thermal conductivity of a heat transfer medium and method of use thereof |
| CA2384285A1 (en) * | 1999-10-26 | 2001-05-03 | Moltech Invent S.A. | Drained-cathode aluminium electrowinning cell with improved electrolyte circulation |
| US20010046605A1 (en) * | 2000-02-16 | 2001-11-29 | Jean-Paul Huni | Refractory coating for components of an aluminium electrolysis cell |
| US6475358B2 (en) * | 2000-02-16 | 2002-11-05 | Alcan International Limited | Method for providing a protective coating for carbonaceous components of an electrolysis cell |
| US20040206941A1 (en) * | 2000-11-22 | 2004-10-21 | Gurin Michael H. | Composition for enhancing conductivity of a carrier medium and method of use thereof |
| NZ527308A (en) * | 2001-03-07 | 2005-03-24 | Moltech Invent S | Cell for the electrowinning of alumimium operating with metal-based anodes with a series of plates made of aluminium wettable reticulated porous material |
| US6645629B2 (en) * | 2001-03-15 | 2003-11-11 | Mikuni Color, Ltd. | Conductive antioxidant paint and graphite electrode |
| US6632762B1 (en) * | 2001-06-29 | 2003-10-14 | The United States Of America As Represented By The Secretary Of The Navy | Oxidation resistant coating for carbon |
| RU2222641C2 (ru) * | 2001-10-04 | 2004-01-27 | Открытое акционерное общество "Братский алюминиевый завод" | Способ производства алюминия электролизом расплавленных солей |
| AU2002348943A1 (en) * | 2002-09-11 | 2004-04-30 | Moltech Invent S.A. | Non-carbon anodes for aluminium electrowinning and other oxidation resistant components with iron oxide-containing coatings |
| US7153179B2 (en) * | 2002-11-07 | 2006-12-26 | Advanced Lighting Technologies, Inc. | Oxidation-protected metallic foil and method |
| US8277274B2 (en) * | 2002-11-07 | 2012-10-02 | Advanced Lighting Technologies, Inc. | Apparatus and methods for use of refractory abhesives in protection of metallic foils and leads |
| US7462271B2 (en) * | 2003-11-26 | 2008-12-09 | Alcan International Limited | Stabilizers for titanium diboride-containing cathode structures |
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| JP5647107B2 (ja) | 2008-05-19 | 2014-12-24 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co.KGaA | 金属基体用の弱アルカリ性薄膜無機腐食保護コーティング |
| FR2932176B1 (fr) * | 2008-06-06 | 2012-02-03 | Snecma Propulsion Solide | Procede de realisation d'une couche auto-cicatrisante sur une piece en materiau composite c/c |
| RU2371523C1 (ru) * | 2008-06-23 | 2009-10-27 | Федеральное государственное образовательное учреждение высшего профессионального образования "Сибирский федеральный университет" | Композиционный материал для смачиваемого катода алюминиевого электролизера |
| FR2937726B1 (fr) * | 2008-10-24 | 2010-12-17 | Snecma | Procede pour installer et proteger un capteur sur un substrat |
| US8137802B1 (en) * | 2009-02-05 | 2012-03-20 | Sandia Corporation | Multilayer ultra-high-temperature ceramic coatings |
| RU2412283C1 (ru) * | 2010-02-24 | 2011-02-20 | Федеральное государственное образовательное учреждение высшего профессионального образования "Сибирский федеральный университет" | Материал для смачиваемого катода алюминиевого электролизера |
| DE102011004013A1 (de) * | 2011-02-11 | 2012-08-16 | Sgl Carbon Se | Graphitierter Kathodenblock mit einer abrasionsbeständigen Oberfläche |
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| US10906203B2 (en) * | 2016-07-15 | 2021-02-02 | University of Pittsburgh—of the Commonwealth System of Higher Education | Apparatus and method for joining of carbide ceramics |
| EP3601640A4 (en) * | 2017-03-31 | 2021-01-06 | Alcoa USA Corp. | SYSTEMS AND PROCESSES FOR ELECTROLYTIC ALUMINUM PRODUCTION |
| US20200270182A1 (en) * | 2019-02-27 | 2020-08-27 | Hamilton Sundstrand Corporation | Oxidation protection of composites |
| US12281050B2 (en) | 2019-10-18 | 2025-04-22 | Ghislain Gonthier | Process for drying anode coating |
| CN111172555B (zh) * | 2020-01-22 | 2022-11-08 | 核工业第八研究所 | 一种制氟用碳阳极板 |
| CN111792950B (zh) * | 2020-07-11 | 2022-09-06 | 浙江锋锂新能源科技有限公司 | 一种石榴石固体电解质粉体烧结容器 |
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| CN114042911B (zh) * | 2021-11-22 | 2023-11-24 | 河北京津冀再制造产业技术研究有限公司 | 一种复合粉末、复合涂层及其制备方法和应用 |
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| CN117344298B (zh) * | 2023-09-13 | 2025-08-12 | 西北工业大学 | 一种TiB2改性Mo-Si-B复合涂层及其制备方法和应用 |
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| GB2103246A (en) * | 1981-07-01 | 1983-02-16 | Diamond Shamrock Corp | Electrolytic production of aluminum |
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| DE3375030D1 (en) * | 1982-07-22 | 1988-02-04 | Commw Aluminium Corp | Improved cell for electrolytic production of aluminum |
| US4487804A (en) * | 1982-08-02 | 1984-12-11 | Nalco Chemical Company | Coating to prevent the oxidation of electrodes during electric furnace steel making |
| US4567103A (en) * | 1983-07-28 | 1986-01-28 | Union Carbide Corporation | Carbonaceous articles having oxidation prohibitive coatings thereon |
| US4559270A (en) * | 1983-07-28 | 1985-12-17 | Union Carbide Corporation | Oxidation prohibitive coatings for carbonaceous articles |
| US4535035A (en) * | 1984-01-17 | 1985-08-13 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Oxidation resistant slurry coating for carbon-based materials |
| US4726995A (en) * | 1985-11-13 | 1988-02-23 | Union Carbide Corporation | Oxidation retarded graphite or carbon electrode and method for producing the electrode |
| US4921731A (en) * | 1986-02-25 | 1990-05-01 | University Of Florida | Deposition of ceramic coatings using sol-gel processing with application of a thermal gradient |
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| US5028301A (en) * | 1989-01-09 | 1991-07-02 | Townsend Douglas W | Supersaturation plating of aluminum wettable cathode coatings during aluminum smelting in drained cathode cells |
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-
1992
- 1992-06-12 US US07/898,052 patent/US5364513A/en not_active Expired - Fee Related
-
1993
- 1993-05-28 RU RU94046228A patent/RU2135643C1/ru not_active IP Right Cessation
- 1993-05-28 DE DE69325815T patent/DE69325815T2/de not_active Expired - Fee Related
- 1993-05-28 EP EP93915165A patent/EP0663022B1/en not_active Expired - Lifetime
- 1993-05-28 DE DE69330618T patent/DE69330618T2/de not_active Expired - Fee Related
- 1993-05-28 HU HU9403565A patent/HU218031B/hu not_active IP Right Cessation
- 1993-05-28 CA CA002137816A patent/CA2137816C/en not_active Expired - Fee Related
- 1993-05-28 ES ES93915165T patent/ES2136125T3/es not_active Expired - Lifetime
- 1993-05-28 EP EP98116542A patent/EP0892085B1/en not_active Expired - Lifetime
- 1993-05-28 BR BR9306538A patent/BR9306538A/pt not_active IP Right Cessation
- 1993-05-28 AU AU45253/93A patent/AU664475B2/en not_active Ceased
-
1996
- 1996-04-30 US US08/640,115 patent/US6455107B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0892085A2 (en) | 1999-01-20 |
| BR9306538A (pt) | 1998-09-15 |
| CA2137816C (en) | 1999-07-06 |
| DE69325815D1 (de) | 1999-09-02 |
| EP0892085A3 (en) | 1999-07-21 |
| HU218031B (hu) | 2000-05-28 |
| US6455107B1 (en) | 2002-09-24 |
| RU2135643C1 (ru) | 1999-08-27 |
| US5364513A (en) | 1994-11-15 |
| AU4525393A (en) | 1994-01-04 |
| AU664475B2 (en) | 1995-11-16 |
| RU94046228A (ru) | 1996-12-27 |
| DE69330618D1 (de) | 2001-09-20 |
| CA2137816A1 (en) | 1993-12-23 |
| EP0892085B1 (en) | 2001-08-16 |
| EP0663022A4 (en) | 1996-12-27 |
| EP0663022B1 (en) | 1999-07-28 |
| DE69325815T2 (de) | 2000-02-17 |
| EP0663022A1 (en) | 1995-07-19 |
| DE69330618T2 (de) | 2002-07-04 |
| HUT72817A (en) | 1996-05-28 |
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