ES2140579T3 - Sistemas catalizadores de amidinato para la polimerizacion de olefinas. - Google Patents

Sistemas catalizadores de amidinato para la polimerizacion de olefinas.

Info

Publication number
ES2140579T3
ES2140579T3 ES95108696T ES95108696T ES2140579T3 ES 2140579 T3 ES2140579 T3 ES 2140579T3 ES 95108696 T ES95108696 T ES 95108696T ES 95108696 T ES95108696 T ES 95108696T ES 2140579 T3 ES2140579 T3 ES 2140579T3
Authority
ES
Spain
Prior art keywords
sup
group
metal
polymerization
amidinate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95108696T
Other languages
English (en)
Inventor
Ruger Dr Schlund
Martin Dr Lux
Frank Prof Dr Edelmann
Ulrike Reissmann
Wolfgang Dr Rohde
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4420783A external-priority patent/DE4420783A1/de
Priority claimed from DE4428636A external-priority patent/DE4428636A1/de
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2140579T3 publication Critical patent/ES2140579T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA INVENCION SE REFIERE A UN SISTEMA DE CATALIZADOR QUE ES APROPIADO PARA LA POLIMERIZACION DE HIDROCARBUROS NO SATURADOS OLEFINICAMENTE, CONTENIENDO COMO COMPONENTES ACTIVOS A) UN COMPLEJO METAL-AMIDINATO DE LA FORMULA GENERAL A EN DONDE LOS SUSTITUYENTES E INDICES TIENEN LOS SIGUIENTES SIGNIFICADOS: M ES UN METAL A PARTIR DEL GRUPO SECUNDARIO III., IV., V. O VI. DEL SISTEMA PERIODICO DE ELEMENTOS O UN METAL DEL GRUPO DE LANTANOIDES X ES UN ATOMO DE PARTIDA NEGATIVO O UN GRUPO DE PARTIDA DE GRUPO NEGATIVO, DONDE EN EL CASO DE (N - M) > 1 LOS RESTOS X PUEDEN SER IGUALES O DIFERENTES. R{SUP,1}, R{SUP,2}, R{SUP,3} SON RESTO C ORGANICO O RESTO SI ORGANICO N ES LA VALENCIA DE M EN EL COMPLEJO METALICO A M ES UN VALOR DE 1 HASTA 5 CON LA CONDICION DE QUE: Y EVENTUALMENTE B) UN COMPUESTO ACEPTADOR PARA EL SUSTITUYENTE X DEL COMPONENTE A COMO ACTIVADOR.
ES95108696T 1994-06-15 1995-06-07 Sistemas catalizadores de amidinato para la polimerizacion de olefinas. Expired - Lifetime ES2140579T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4420783A DE4420783A1 (de) 1994-06-15 1994-06-15 Amidinato-Katalysatorsysteme zur Polymerisation von Olefinen
DE4428636A DE4428636A1 (de) 1994-08-12 1994-08-12 Amidinato-Katalysatorsysteme zur Polymerisation von Olefinen
US08/469,356 US5707913A (en) 1994-06-15 1995-06-06 Amidinato catalyst systems for the polymerization of olefins

Publications (1)

Publication Number Publication Date
ES2140579T3 true ES2140579T3 (es) 2000-03-01

Family

ID=27206483

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95108696T Expired - Lifetime ES2140579T3 (es) 1994-06-15 1995-06-07 Sistemas catalizadores de amidinato para la polimerizacion de olefinas.

Country Status (4)

Country Link
US (2) US5707913A (es)
EP (1) EP0687693B1 (es)
DE (1) DE59507307D1 (es)
ES (1) ES2140579T3 (es)

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FI102476B (fi) * 1996-05-31 1998-12-15 Borealis As Uudet siirtymämetallikompleksit ja menetelmä niiden valmistamiseksi
KR100361088B1 (ko) * 1996-06-27 2003-02-17 삼성종합화학주식회사 올레핀중합용킬레이트촉매및그제조방법
DE19642353A1 (de) * 1996-10-14 1998-04-16 Basf Ag Katalysatorsysteme, enthaltend Metallkomplexe mit adamantanähnlicher Struktur
DE19642354A1 (de) * 1996-10-14 1998-04-16 Basf Ag Metalkomplexe mit adamantanähnlicher Struktur
US5851945A (en) * 1997-02-07 1998-12-22 Exxon Chemical Patents Inc. Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state
US6228794B1 (en) 1997-03-14 2001-05-08 University Of Iowa Research Foundation Cationic group 13 complexes incorporating bidentate ligands as polymerization catalysts
US5777120A (en) * 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts
US5780698A (en) * 1997-03-31 1998-07-14 Chevron Chemical Company Olefin oligomerization catalyst and process employing and preparing same
AU6953898A (en) * 1997-04-04 1998-10-30 Damon R. Click Polymerization catalysts containing electron-withdrawing amide ligands
US6096676A (en) * 1997-07-02 2000-08-01 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
IL122115A (en) 1997-07-27 2007-06-17 Technion Res & Dev Foundation Alpha polymerization method - olefins and polymers, copolymers and elastomers prepared by this method
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
US6180788B1 (en) * 1997-12-16 2001-01-30 Exxon Research And Engineering Company Catalyst compositions
US6037297A (en) * 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
US5932670A (en) * 1998-03-30 1999-08-03 Phillips Petroleum Company Polymerization catalysts and processes therefor
US6150295A (en) * 1998-03-30 2000-11-21 Phillips Petroleum Company Polymerization catalysts and processes therefor
US6121181A (en) * 1998-08-07 2000-09-19 Equistar Chemicals, L.P. Cyclic oligomeric oxo- and imido- metal complexes as olefin polymerization catalysts
US6255414B1 (en) * 1998-09-01 2001-07-03 E. I. Du Pont De Nemours And Company Polymerization of olefins
CA2248463A1 (en) 1998-09-28 2000-03-28 Scott Collins Iminophosphonamide complexes for olefin polymerization
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
CN1192033C (zh) * 1998-10-08 2005-03-09 陶氏化学公司 桥连的金属配合物
US6538115B2 (en) * 1999-08-17 2003-03-25 The Governors Of The University Of Alberta Phosphorus supported carbene transition metal complexes
US6060568A (en) * 1998-12-18 2000-05-09 The Governors Of The University Of Alberta Carbene transition metal catalysts
US6204216B1 (en) * 1999-04-15 2001-03-20 Equistar Chemicals, L.P. Olefin polymerization catalysts containing amine derivatives
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6417304B1 (en) * 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
JP5258077B2 (ja) * 1999-11-01 2013-08-07 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット オレフィン重合用の活性を持った三配座不均一担持触媒
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
WO2001055227A2 (en) * 2000-01-27 2001-08-02 Technion Research And Development Foundation Ltd. Process for the production of stereoregular polymers and elastomers of alpha-olefins and certain novel catalysts therefor
US6501000B1 (en) 2000-04-04 2002-12-31 Exxonmobil Research And Engineering Company Late transition metal catalyst complexes and oligomers therefrom
US6689928B2 (en) 2000-04-04 2004-02-10 Exxonmobil Research And Engineering Company Transition metal complexes and oligomers therefrom
US6476245B1 (en) 2000-07-26 2002-11-05 The Governors Of The University Of Alberta Phosphinimine methanide transition metal catalysts
MXPA03003389A (es) * 2000-10-19 2004-01-26 Exxonmobil Chem Patents Inc Sistema catalizador del grupo 3 cationico.
AU2002246614A1 (en) 2000-10-25 2002-08-06 Exxonmobil Chemical Patents Inc. Cationic catalyst system
US6686490B1 (en) * 2000-11-06 2004-02-03 Ramot University Authority For Applied Research & Industrial Development Ltd. Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers
US7196148B2 (en) * 2001-10-25 2007-03-27 Exxon Mobil Chemical Patents Inc. Cationic catalyst system
US7199255B2 (en) * 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
US6919467B2 (en) * 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
EP1515997A1 (en) 2002-06-21 2005-03-23 ExxonMobil Chemical Patents Inc. Yttrium-based ethylene polymerization catalysts with bulky amidinate ancillary ligands
EP1568716A1 (en) * 2004-02-24 2005-08-31 Stichting Dutch Polymer Institute Catalyst system comprising magnesium halide
US7816550B2 (en) * 2005-02-10 2010-10-19 Praxair Technology, Inc. Processes for the production of organometallic compounds
US7547631B2 (en) * 2006-07-31 2009-06-16 Rohm And Haas Electronic Materials Llc Organometallic compounds
WO2012106695A2 (en) * 2011-02-05 2012-08-09 Bridgestone Corporation Metal complex catalysts and polymerization methods employing same
WO2012155022A1 (en) * 2011-05-12 2012-11-15 Dow Global Technologies Llc Non-cyclopentadienyl-based chromium catalysts for olefin polymerization
US20130131294A1 (en) * 2011-11-21 2013-05-23 John R. Hagadorn Amidinate Catalyst Compounds, Process for Their Use and Polymers Produced Therefrom

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US3374256A (en) * 1963-08-16 1968-03-19 Monsanto Res Corp Complex phosphorus salts
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
ATE135358T1 (de) * 1990-12-27 1996-03-15 Exxon Chemical Patents Inc Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen
JP3332051B2 (ja) * 1992-12-18 2002-10-07 出光興産株式会社 重合用触媒及び該触媒系を用いる重合体の製造方法
US5502128A (en) * 1994-12-12 1996-03-26 University Of Massachusetts Group 4 metal amidinate catalysts and addition polymerization process using same
US5527752A (en) * 1995-03-29 1996-06-18 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the production of polyolefins
US5777120A (en) * 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts

Also Published As

Publication number Publication date
US5707913A (en) 1998-01-13
EP0687693A1 (de) 1995-12-20
DE59507307D1 (de) 2000-01-05
US6262198B1 (en) 2001-07-17
EP0687693B1 (de) 1999-12-01

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