ES2145471T3 - Procedimiento y dispositivo para la obtencion de poliisocianatos (ciclo)alifaticos que contienen grupos biuret. - Google Patents

Procedimiento y dispositivo para la obtencion de poliisocianatos (ciclo)alifaticos que contienen grupos biuret.

Info

Publication number
ES2145471T3
ES2145471T3 ES96925694T ES96925694T ES2145471T3 ES 2145471 T3 ES2145471 T3 ES 2145471T3 ES 96925694 T ES96925694 T ES 96925694T ES 96925694 T ES96925694 T ES 96925694T ES 2145471 T3 ES2145471 T3 ES 2145471T3
Authority
ES
Spain
Prior art keywords
cycle
procedure
obtaining
aliphatic polyisocyanates
biuret groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96925694T
Other languages
English (en)
Inventor
Wolfgang Heider
Stefan Wolff
Bernd Bruchmann
Klaus Bittins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2145471T3 publication Critical patent/ES2145471T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00—Preparation of derivatives of isocyanic acid
    • C07C263/18—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/006—Baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
    • C07C273/1863—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety from urea
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1872—Preparation of compounds comprising a -N-C(O)-N-C(O)-N- moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
    • C07C275/58—Y being a hetero atom
    • C07C275/62—Y being a nitrogen atom, e.g. biuret
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00768—Baffles attached to the reactor wall vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00777—Baffles attached to the reactor wall horizontal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00779—Baffles attached to the stirring means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

ES UN PROCEDIMIENTO Y UN DISPOSITIVO PARA LA PREPARACION DE POLIISOCIANATOS QUE CONTIENEN COMO REACTIVOS GRUPOS BIURET (CICLO)ALIFATICOS A PARTIR DE DIISOCIANATOS (CICLO)ALIFATICOS Y VAPOR DE AGUA O UNA SUSTANCIA DESHIDRATANTE, SIENDO MEZCLADOS ENTRE SI EN UN REACTOR DE AGITACION, LOS REACTIVOS SON CONDUCIDOS EN CONTRACORRIENTE POR UN REACTOR DE AGITACION EN CASCADA QUE CONSTA DE AL MENOS DOS FASES. CON ELLO, SE INTENSIFICA LA DISTRIBUCION DEL REACTIVO GASEOSO EN EL REACTIVO LIQUIDO A TRAVES DE UNOS ELEMENTOS PERTURBADORES QUE HAY INSTALADOS EN EL REACTOR DE AGITACION. COMO ELEMENTOS PERTURBADORES SE UTILIZAN UNAS ARANDELAS PROVISTAS DE UNOS ORIFICIOS Y DISPUESTAS A DISTANCIA UNAS DE OTRAS Y/O LISTONES DE PERTURBACION QUE DISCURREN EN DIRECCION LONGITUDINAL DEL REACTOR DE AGITACION.
ES96925694T 1995-07-12 1996-07-09 Procedimiento y dispositivo para la obtencion de poliisocianatos (ciclo)alifaticos que contienen grupos biuret. Expired - Lifetime ES2145471T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19525474A DE19525474A1 (de) 1995-07-12 1995-07-12 Verfahren und Vorrichtung zur Herstellung von (cyclo)aliphatische Biuretgruppen enthaltenden Polyisocyananten

Publications (1)

Publication Number Publication Date
ES2145471T3 true ES2145471T3 (es) 2000-07-01

Family

ID=7766691

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96925694T Expired - Lifetime ES2145471T3 (es) 1995-07-12 1996-07-09 Procedimiento y dispositivo para la obtencion de poliisocianatos (ciclo)alifaticos que contienen grupos biuret.

Country Status (10)

Country Link
US (1) US6066759A (es)
EP (1) EP0840722B1 (es)
JP (1) JP4036271B2 (es)
KR (1) KR100417358B1 (es)
CN (1) CN1192730A (es)
CA (1) CA2223641A1 (es)
DE (2) DE19525474A1 (es)
ES (1) ES2145471T3 (es)
WO (1) WO1997003044A1 (es)
ZA (1) ZA965880B (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19633404A1 (de) 1996-08-19 1998-02-26 Basf Ag Verfahren zur Herstellung von Biuretgruppen enhaltenden Polyisocyanaten aus (cyclo)aliphatischen Diisocyanaten
DE19653079A1 (de) * 1996-12-19 1998-06-25 Basf Ag Verfahren zur Gasphasenpolymerisation von C¶2¶-C¶8¶-Alk-1-enen mittels Ziegler -Natta- oder Metallocen-Katalysatorsystemen
DE19710112A1 (de) * 1997-03-12 1998-09-17 Henkel Kgaa Verfahren zur kontinuierlichen Herstellung von Alkyl- und/oder Alkenyloligoglykosiden
WO2001006217A1 (en) 1999-07-16 2001-01-25 Pohang Iron & Steel Co., Ltd. Apparatus and method for measuring the molten metal level in electromagnetic continuous casting
DE19938574A1 (de) * 1999-08-17 2001-02-22 Stockhausen Chem Fab Gmbh Verfahren und Vorrichtung zur Entfernung von Sauerstoff aus wässrigen Monomerenlösungen
DE10025301A1 (de) 2000-05-22 2001-11-29 Bayer Ag Verfahren zur Herstellung von Polyisocyanaten mit Biuretstruktur
JP4225784B2 (ja) * 2001-02-19 2009-02-18 ビーエーエスエフ ソシエタス・ヨーロピア 薄い、吸収性表面構造体を製造するための乾燥流動床の使用法
BR0212992A (pt) * 2001-09-21 2004-09-21 Du Pont Processo para a preparação de poliisocianatos, composição dos mesmos, composição de revestimento, substrato revestido e substrato automotivo
US20080064829A1 (en) * 2002-09-20 2008-03-13 Adams Jerome T Preparation and use of biuret-containing polyisocyanates as cross-linking agents for coatings
JP5542305B2 (ja) * 2004-12-13 2014-07-09 ビーエーエスエフ ソシエタス・ヨーロピア 無色の、貯蔵安定性のビウレット基含有のポリイソシアナートの製造方法
DE102004060120A1 (de) * 2004-12-13 2006-06-14 Basf Ag Verfahren zur Herstellung von (cyclo)aliphatischen Polyisocyanaten
JP5316291B2 (ja) 2008-08-05 2013-10-16 三菱マテリアル株式会社 トリクロロシラン製造装置及び製造方法
JP5316290B2 (ja) * 2008-08-05 2013-10-16 三菱マテリアル株式会社 トリクロロシラン製造装置及び製造方法
DE102009038463A1 (de) * 2009-08-21 2011-02-24 Bayer Materialscience Ag Verfahren zur Herstellung von Polyisocyanaten mit Biuretstruktur
KR200469030Y1 (ko) * 2012-09-14 2013-09-12 엘에스산전 주식회사 차단기의 핸들 인터록 장치
CN103709076B (zh) * 2013-12-20 2015-09-16 万华化学集团股份有限公司 一种连续制备缩二脲多异氰酸酯的方法
CN105348486A (zh) * 2015-12-09 2016-02-24 青岛科技大学 一种水蒸汽法制备六亚甲基二异氰酸酯缩二脲的方法
CN105622462B (zh) * 2016-03-03 2017-09-19 万华化学集团股份有限公司 一种制备缩二脲多异氰酸酯的方法
CN105664812A (zh) * 2016-04-07 2016-06-15 江苏浩特隆搅拌设备有限公司 搪瓷釜挡板装置

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL279113A (es) * 1962-05-30
US3358010A (en) * 1964-03-11 1967-12-12 Mobay Chemical Corp Biuret polyisocyanates
NO123123B (es) * 1969-06-19 1971-09-27 Dynamit Nobel Ag
US4374093A (en) * 1981-02-20 1983-02-15 Mobil Oil Corporation Continuous-stream upflow zeolite crystallization apparatus
US4438074A (en) * 1981-07-21 1984-03-20 Phillips Petroleum Company Continuous polymerization reactor
DE3403277A1 (de) * 1984-01-31 1985-08-01 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von polyisocyanaten mit biuretstruktur
FR2601007B1 (fr) * 1986-07-04 1988-11-10 Rhone Poulenc Chim Base Procede de preparation de polyisocyanate a groupement biuret
FR2603278B1 (fr) * 1986-09-03 1988-11-18 Rhone Poulenc Chimie Procede de preparation de polyisocyanate a groupement biuret
US5211924A (en) * 1988-02-29 1993-05-18 Amoco Corporation Method and apparatus for increasing conversion efficiency and reducing power costs for oxidation of an aromatic alkyl to an aromatic carboxylic acid
US5102630A (en) * 1988-03-17 1992-04-07 Amoco Corporation Apparatus for increasing yield and product quality while reducing power costs in oxidation of an aromatic alkyl to an aromatic carboxylic acid

Also Published As

Publication number Publication date
DE59604897D1 (de) 2000-05-11
EP0840722A1 (de) 1998-05-13
ZA965880B (en) 1998-01-12
JPH11508600A (ja) 1999-07-27
CN1192730A (zh) 1998-09-09
EP0840722B1 (de) 2000-04-05
KR100417358B1 (ko) 2004-03-19
WO1997003044A1 (de) 1997-01-30
CA2223641A1 (en) 1997-01-30
DE19525474A1 (de) 1997-01-16
JP4036271B2 (ja) 2008-01-23
KR19990028920A (ko) 1999-04-15
US6066759A (en) 2000-05-23

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