ES2148933T3 - Acumulador alcalino con electrodo negativo de zinc. - Google Patents

Acumulador alcalino con electrodo negativo de zinc.

Info

Publication number
ES2148933T3
ES2148933T3 ES97904493T ES97904493T ES2148933T3 ES 2148933 T3 ES2148933 T3 ES 2148933T3 ES 97904493 T ES97904493 T ES 97904493T ES 97904493 T ES97904493 T ES 97904493T ES 2148933 T3 ES2148933 T3 ES 2148933T3
Authority
ES
Spain
Prior art keywords
negative electrode
electrolyte
separator
contact
alkaline accumulator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97904493T
Other languages
English (en)
Inventor
Guy Bronoel
Noelle Tassin
Alain Millot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Laboratoires Sorapec SA
Original Assignee
Laboratoires Sorapec SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laboratoires Sorapec SA filed Critical Laboratoires Sorapec SA
Application granted granted Critical
Publication of ES2148933T3 publication Critical patent/ES2148933T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/28—Construction or manufacture
    • H01M10/281—Large cells or batteries with stacks of plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/665—Composites
    • H01M4/667—Composites in the form of layers, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/26—Selection of materials as electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/28—Construction or manufacture
    • H01M10/287—Small-sized flat cells or batteries for portable equipment
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/30—Nickel accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/32—Silver accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/244—Zinc electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30—Arrangements for facilitating escape of gases
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/431—Inorganic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/463—Separators, membranes or diaphragms characterised by their shape
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H01M4/808—Foamed, spongy materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Hybrid Cells (AREA)
  • Secondary Cells (AREA)
  • Cell Separators (AREA)
  • Primary Cells (AREA)

Abstract

LA INVENCION SE REFIERE A UN ACUMULADOR ALCALINO QUE COMPRENDE AL MENOS UN ELECTRODO POSITIVO (4) Y UN ELECTRODO NEGATIVO (13) DE ZINC EN CONTACTO CON UN ELECTROLITO A TRAVES DE AL MENOS UN SEPARADOR (9I; 12) IMPREGNADO DE ELECTROLITO. AMBOS ELECTRODOS ESTAN PEGADOS RESPECTIVAMENTE A DOS PANTALLAS BIPOLARES (5 Y 14) SUJETAS POR UN MARCO DE ESTANCAMIENTO (8, 15). SE CARACTERIZA POR QUE EL ELECTRODO POSITIVO (4) ESTA EN CONTACTO CON UN PRIMER ELECTROLITO DE VOLUMEN Y COMPOSICION DETERMINADOS A TRAVES DE AL MENOS UN PRIMER SEPARADOR (9I), POR QUE EL ELECTRODO NEGATIVO (13) ESTA EN CONTACTO CON UN SEGUNDO ELECTROLITO DE VOLUMEN Y COMPOSICION DIFERENTES DEL PRIMERO A TRAVES DE AL MENOS UN SEGUNDO SEPARADOR (12), Y POR QUE EL PRIMER Y EL SEGUNDO ELECTROLITOS ESTAN SEPARADOS POR UNA MEMBRANA (10) QUE CONFORMA UN FILTRO CONTRA CINCATOS Y, EN SU CASO, ALUMINATOS, EN PARTICULAR UNA MEMBRANA DE CONDUCCION ANIONICA QUE DEFINE UN PRIMER Y UN SEGUNDO COMPARTIMIENTOS (11 Y 16).
ES97904493T 1996-03-08 1997-02-05 Acumulador alcalino con electrodo negativo de zinc. Expired - Lifetime ES2148933T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9602941A FR2745959B1 (fr) 1996-03-08 1996-03-08 Perfectionnements apportes a l'accumulateur ni-zn au moyen d'anolyte, de catholyte et de membrane remediant a la formation de dendrites

Publications (1)

Publication Number Publication Date
ES2148933T3 true ES2148933T3 (es) 2000-10-16

Family

ID=9489995

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97904493T Expired - Lifetime ES2148933T3 (es) 1996-03-08 1997-02-05 Acumulador alcalino con electrodo negativo de zinc.

Country Status (9)

Country Link
US (1) US6183900B1 (es)
EP (1) EP0885463B1 (es)
JP (1) JP2001500661A (es)
KR (1) KR19990087631A (es)
CA (1) CA2248191A1 (es)
DE (1) DE69701866T2 (es)
ES (1) ES2148933T3 (es)
FR (1) FR2745959B1 (es)
WO (1) WO1997033325A1 (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2799309B1 (fr) * 1999-09-30 2002-01-25 Sorapec Perfectionnements apportes a l'accumulateur ni-zn
FR2835656A1 (fr) * 2002-05-13 2003-08-08 Commissariat Energie Atomique Pile du type metal-oxygene comprenant un electrolyte apte a limiter, du cote cathodique, le passage de cations
US7344801B2 (en) * 2002-05-24 2008-03-18 Shao-An Cheng High-voltage dual electrolyte electrochemical power sources
FR2903529B1 (fr) * 2006-07-05 2008-10-17 Conseil Et De Prospective Scie Nouvelle electrode positive d'argent pour accumulateurs alcalins
JP5812403B2 (ja) * 2011-09-02 2015-11-11 日産自動車株式会社 アルカリ二次電池
CN104067437B (zh) * 2012-02-06 2015-06-17 日本碍子株式会社 锌二次电池
EP3144999A1 (de) * 2012-07-18 2017-03-22 VARTA Microbattery GmbH Verwendung elektrochemischer zellen mit einer elektrode aus zink oder aus einer zinklegierung und einem anteil an aluminiumhydroxid und/oder an mindestens einem aluminat
WO2016006349A1 (ja) * 2014-07-09 2016-01-14 日本碍子株式会社 ニッケル亜鉛電池
WO2016006348A1 (ja) * 2014-07-09 2016-01-14 日本碍子株式会社 ニッケル亜鉛電池
WO2016006350A1 (ja) 2014-07-09 2016-01-14 日本碍子株式会社 ニッケル亜鉛電池
CN106463784B (zh) * 2014-07-09 2019-03-08 日本碍子株式会社 镍锌电池
EP3203546B1 (en) 2014-10-01 2019-06-19 NGK Insulators, Ltd. Battery using layered double hydroxide
CN107078357B (zh) * 2014-11-13 2020-03-06 日本碍子株式会社 使用氢氧化物离子传导性陶瓷隔板的二次电池
JP5940237B1 (ja) * 2014-11-25 2016-06-29 日本碍子株式会社 水酸化物イオン伝導性セラミックスセパレータを用いた二次電池
DE102015203101B4 (de) * 2015-02-20 2017-07-27 Technische Universität Dresden Batteriezellenaufbau mit dauerhaft voneinander getrennten Elektrodenräumen
CN107615559B (zh) * 2015-06-15 2020-09-01 日本碍子株式会社 镍锌电池单元电池包及使用了该镍锌电池单元电池包的电池组
JP6664195B2 (ja) * 2015-11-16 2020-03-13 日本碍子株式会社 亜鉛二次電池
JP6784694B2 (ja) * 2015-11-16 2020-11-11 日本碍子株式会社 電極カートリッジ及びそれを用いた亜鉛二次電池
JP6731589B2 (ja) * 2016-03-31 2020-07-29 株式会社Ｇｓユアサ 蓄電池
JP6873767B2 (ja) 2017-03-17 2021-05-19 株式会社東芝 二次電池、電池パック及び車両
KR102217449B1 (ko) 2017-11-01 2021-02-22 주식회사 엘지화학 이차전지
WO2020086838A1 (en) * 2018-10-24 2020-04-30 Urban Electric Power Inc. Porous zn metal electrode for zn batteries
JP7408287B2 (ja) * 2019-03-15 2024-01-05 株式会社東芝 電池、電池パック、車両及び定置用電源
CN112164832B (zh) * 2020-03-19 2021-12-28 山东合泰新能源有限公司 一种电解液的配制方法及其应用的锌镍电池
JP7037002B1 (ja) 2020-11-30 2022-03-15 日本碍子株式会社 層状複水酸化物様化合物を用いた電池

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US2965697A (en) * 1956-11-05 1960-12-20 Electric Storage Battery Co Battery diaphragm
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USB730525I5 (es) * 1958-04-24
FR1214394A (fr) * 1958-11-27 1960-04-08 Electric Storage Battery Co Batterie d'accumulateurs rechargeables du type alcalin
US3558358A (en) * 1969-03-10 1971-01-26 Eagle Picher Ind Inc Nickel-zinc secondary battery
GB1420710A (en) * 1973-01-31 1976-01-14 Furukawa Electric Co Ltd Furukawa battery co ltd rechargeable galvanic cell with zinc anode
JPS50102832A (es) * 1974-01-16 1975-08-14
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US4348465A (en) * 1980-11-10 1982-09-07 Universal Fuel Systems, Inc. Nitrogen metal fuel cell
JPS58165243A (ja) * 1982-03-25 1983-09-30 Japan Storage Battery Co Ltd ニツケル亜鉛電池
US4592973A (en) * 1983-10-05 1986-06-03 Castle Technology Corp. Supported liquid membrane electrochemical separators
JPS60117568A (ja) * 1983-11-29 1985-06-25 Shin Kobe Electric Mach Co Ltd ニッケル・カドミウム蓄電池
US4567119A (en) * 1984-03-12 1986-01-28 Hughes Aircraft Company Nickel-hydrogen bipolar battery
JPS60225372A (ja) * 1984-04-20 1985-11-09 Sanyo Electric Co Ltd アルカリ亜鉛蓄電池
US4789609A (en) * 1987-12-14 1988-12-06 W. R. Grace & Co.-Conn. Battery separator
DE3907741A1 (de) * 1989-03-10 1990-09-20 Schoell Guenter Akkumulatoren-batterie
WO1992012544A1 (fr) * 1990-12-28 1992-07-23 Yuasa Battery Co., Ltd. Separateur pour accumulateurs a zinc alcalin
US5196276A (en) * 1991-05-17 1993-03-23 Eltech Systems Corporation Reserve battery
CA2110391A1 (fr) * 1991-06-13 1992-12-23 Guy Bronoel Accumulateur alcalin a electrodes bipolaires et procedes de fabrication
US5143799A (en) * 1992-01-21 1992-09-01 Battery Technologies International, Ltd. Sealed batteries with zinc electrode
US5382482A (en) * 1992-08-07 1995-01-17 Nippon Oil Company, Limited Zinc electrode for alkaline storage battery
FR2708382A1 (fr) * 1993-07-28 1995-02-03 Sorapec Séparateur pour accumulateur Ni-Zn étanche.

Also Published As

Publication number Publication date
FR2745959B1 (fr) 1998-07-10
DE69701866D1 (de) 2000-06-08
KR19990087631A (ko) 1999-12-27
JP2001500661A (ja) 2001-01-16
CA2248191A1 (fr) 1997-09-12
EP0885463A1 (fr) 1998-12-23
DE69701866T2 (de) 2000-12-07
US6183900B1 (en) 2001-02-06
FR2745959A1 (fr) 1997-09-12
EP0885463B1 (fr) 2000-05-03
WO1997033325A1 (fr) 1997-09-12

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