ES2151580T3 - Hoja extruida de una mezcla de copolimeros de etileno. - Google Patents
Hoja extruida de una mezcla de copolimeros de etileno.Info
- Publication number
- ES2151580T3 ES2151580T3 ES95304779T ES95304779T ES2151580T3 ES 2151580 T3 ES2151580 T3 ES 2151580T3 ES 95304779 T ES95304779 T ES 95304779T ES 95304779 T ES95304779 T ES 95304779T ES 2151580 T3 ES2151580 T3 ES 2151580T3
- Authority
- ES
- Spain
- Prior art keywords
- approximately
- interval
- film
- grams
- sup
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 229920001038 ethylene copolymer Polymers 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 3
- 208000035155 Mitochondrial DNA-associated Leigh syndrome Diseases 0.000 abstract 2
- 208000003531 maternally-inherited Leigh syndrome Diseases 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000012748 slip agent Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
Abstract
UNA PELICULA QUE CONSTA DE UNA MEZCLA DE COPOLIMEROS, QUE HA SIDO EXTRUIDA (I) A UNA PELICULA CON UNA ESTIMACION MENOR A APROXIMADAMENTE 1,8 MILS; UNA RESISTENCIA DE IMPACTO DE DARDO DE AL MENOS APROXIMADAMENTE 80 GRAMS POR MIL EN UNA DENSIDAD DE 0,926 GRAM POR CM{SUP.3}; Y UNA RESISTENCIA DE IMPACTO DE DARDO DE AL MENOS APROXIMADAMENTE 480 GRAMS POR MIL EN UNA DENSIDAD DE 0,918 POR CM{SUP.3} Y/O (II) A UNA PELICULA QUE TIENE UNA ESTIMACION MENOR A APROXIMADAMENTE 5 MILS, Y UNA FUERZA DE BLOQUEO MENOR A APROXIMADAMENTE 120 GRAMS Y UNA COF EN EL INTERVALO DE APROXIMADAMETNE 0,2 A 0,5; HABIENDO SIDO PRODUCIDA DICHA MEZCLA IN SITU CONTACTANDO ETILENO Y AL MENOS UN COMONOMREO ALFAOLEFINO CON UN SISTEMA CATALIZADOR DE BASE DE MAGNESIO/TITANIO EN CADA UNO DE LOS DOS REACTORES CONECTADOS EN SERIE, BAJO CONDICIONES DE POLIMERIZACION, DONDE EL POLIMERO FORMADO EN EL REACTOR DE ALTO PESO MOLECULAR TIENE UN INDICE DE FLUJO EN EL INTERVALO DE APROXIMADAMENTE 0,01 A APROXIMADAMENTE 30 GRAMS POR 10 MINUTOS Y UNA DENSIDAD EN EL AMBITO DE APROXIMADAMENTE 0,860 A 0,940 GRAM POR CM{SUP.3} Y EL POLIMERO FORMADO EN EL REACTOR DE BAJO PESO MOLECULAR TIENE UN INDICE DE FUNDICION EN EL INTERVALO DE APROXIMADAMENTE 50 A 3000 GRAMS POR 10 MINUTOS Y UNA DENSIDAD EN EL INTERVALO DE APROXIMADAMENTE 0,900 A 0,970 GRAM POR CM{SUP.3}; EL INDICE DE PESO DEL COPOLIMERO DEL REACTOR DE ALTO PESO MOLECULAR AL COPOLIMERO DEL REACTOR DE BAJO PESO MOLECULAR, ENCONTRANDOSE EN EL INTERVALO DE APROXIMADAMENTE 0,5:1 A APROXIMADAMENTE 2:1 CON LA CONDICION QUE PARA LA PELICULA (I) UTILIZADA EN EL REACTOR DE BAJO PESO MOLECULAR, ESTE PRESENTE EN EL MEZCLADO IN SITU EN UN INDICE DE PESO DE 1-BUTENO A LOS OTROS COMONOMERO(S) EN EL INTERVALO DE APROXIMADAMENTE 0,001:1 A 1,3:1, Y PARA LA PELICULA (II), LA PELICULA ESTA ESENCIALMENTE LIBRE DE AGENTES DE ANTIBLOQUEO Y DE RESBALADO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/272,260 US5503914A (en) | 1994-07-08 | 1994-07-08 | Film extruded from an in situ blend of ethylene copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2151580T3 true ES2151580T3 (es) | 2001-01-01 |
Family
ID=23039078
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99100242T Expired - Lifetime ES2212393T3 (es) | 1994-07-08 | 1995-07-07 | Pelicula extruida a partir de una mezcla in situ de copolimeros de etileno. |
| ES95304779T Expired - Lifetime ES2151580T3 (es) | 1994-07-08 | 1995-07-07 | Hoja extruida de una mezcla de copolimeros de etileno. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99100242T Expired - Lifetime ES2212393T3 (es) | 1994-07-08 | 1995-07-07 | Pelicula extruida a partir de una mezcla in situ de copolimeros de etileno. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5503914A (es) |
| EP (2) | EP0916693B1 (es) |
| JP (1) | JP3113549B2 (es) |
| AT (2) | ATE260314T1 (es) |
| AU (1) | AU681033B2 (es) |
| BR (1) | BR9503246A (es) |
| CA (1) | CA2153434C (es) |
| DE (2) | DE69532614T2 (es) |
| ES (2) | ES2212393T3 (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19515678B4 (de) * | 1995-04-28 | 2007-12-27 | Basell Polyolefine Gmbh | Rohr aus Polyethylen mit verbesserten mechanischen Eigenschaften |
| US5665818A (en) * | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5718974A (en) * | 1996-06-24 | 1998-02-17 | Union Carbide Chemicals & Plastics Technology Corporation | Cable jacket |
| US5731082A (en) * | 1996-06-24 | 1998-03-24 | Union Carbide Chemicals & Plastics Technology Corporation | Tree resistant cable |
| US5736237A (en) * | 1996-11-25 | 1998-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Geomembranes |
| CA2291106A1 (en) * | 1997-05-20 | 1998-11-26 | Sandra Ann Kupperblatt | A process for preparing an in situ polyethylene blend |
| BR9816010A (pt) * | 1998-09-11 | 2001-06-05 | Union Carbide Chemcials & Plas | Composição de pelìcula de polietileno |
| FI990003L (fi) | 1999-01-04 | 2000-07-05 | Borealis Polymers Oy | Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot |
| US6187866B1 (en) | 1999-06-04 | 2001-02-13 | Union Carbide Chemicals & Plastics Technology Corporation | Staged reactor process |
| US6248831B1 (en) * | 1999-12-06 | 2001-06-19 | Union Carbide Chemicals & Plastics Technology Corporation | High strength polyethylene film |
| FI111954B (fi) * | 2000-02-21 | 2003-10-15 | Borealis Tech Oy | Menetelmä polyeteenipäällysteen valmistamiseksi substraatille |
| CN1195796C (zh) * | 2001-04-23 | 2005-04-06 | 三井化学株式会社 | 制备乙烯聚合物组合物的方法,乙烯聚合物组合物的颗粒和由该颗粒制成的膜 |
| WO2003016366A1 (en) * | 2001-08-17 | 2003-02-27 | Idemitsu Petrochemical Co., Ltd. | Ethylenic copolymer and film comprising the same |
| ATE287420T1 (de) | 2002-02-04 | 2005-02-15 | Borealis Tech Oy | Film mit hoher schlagfestigkeit |
| DE60203707T2 (de) * | 2002-06-24 | 2006-03-02 | Borealis Technology Oy | Verfahren zur Herstellung einer Lldpe Zusammensetzung |
| TW200504093A (en) | 2003-05-12 | 2005-02-01 | Dow Global Technologies Inc | Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom |
| GB0315275D0 (en) * | 2003-06-30 | 2003-08-06 | Borealis Tech Oy | Extrusion coating |
| GB0317012D0 (en) | 2003-07-21 | 2003-08-27 | Borealis Tech Oy | Injection moulding polymer |
| BRPI0512760A (pt) | 2004-07-07 | 2008-04-08 | Dow Global Technologies Inc | processo para produzir uma composição de polìmero de etileno em múltiplos estágios, composição de polìmero de etileno, artigo de manufatura e composição |
| EP1674490A1 (en) * | 2004-12-23 | 2006-06-28 | Borealis Technology Oy | Copolymer |
| DE102005040390A1 (de) * | 2005-08-25 | 2007-03-01 | Basell Polyolefine Gmbh | Multimodale Polyethylen Formmasse zur Herstellung von Rohren mit verbesserten mechanischen Eigenschaften |
| EP1961557B1 (en) * | 2007-02-26 | 2017-04-05 | Borealis Technology Oy | Multilayer film structure |
| WO2009071323A1 (en) * | 2007-12-05 | 2009-06-11 | Borealis Technology Oy | Multi-modal linear low density polyethylene polymer |
| EP2067799A1 (en) | 2007-12-05 | 2009-06-10 | Borealis Technology OY | Polymer |
| EP2883887A1 (en) | 2013-12-13 | 2015-06-17 | Borealis AG | Multistage process for producing polyethylene compositions |
| EP2883885A1 (en) | 2013-12-13 | 2015-06-17 | Borealis AG | Multistage process for producing polyethylene compositions |
| CN108026297B (zh) * | 2015-06-10 | 2020-12-18 | 博里利斯股份公司 | 乙烯和至少两种α-烯烃共聚单体的多峰共聚物及其制成的最终制品 |
| EP3307813B1 (en) | 2015-06-10 | 2019-12-25 | Borealis AG | Multimodal polyethylene copolymer |
| ES2707391T3 (es) | 2015-06-23 | 2019-04-03 | Borealis Ag | Procedimiento para la producción de resinas de LLDPE |
| HUE047424T2 (hu) * | 2016-09-12 | 2020-04-28 | Thai Polyethylene Co Ltd | Multimodális polietilén vékony film |
| CN109963713B (zh) | 2016-11-25 | 2021-09-14 | 博里利斯股份公司 | 聚烯烃膜组合物的制备方法及由其制成的膜 |
| CN111902467B (zh) | 2018-02-05 | 2022-11-11 | 埃克森美孚化学专利公司 | 通过添加超高分子量高密度聚乙烯增强的lldpe的加工性 |
| EP3902850A1 (en) | 2018-12-28 | 2021-11-03 | Borealis AG | A process for producing polyolefin film composition and films prepared thereof |
| EP3902851A1 (en) | 2018-12-28 | 2021-11-03 | Borealis AG | A process for producing polyolefin film composition and films prepared thereof |
| CN117480191B (zh) | 2021-06-11 | 2026-07-17 | 博里利斯股份公司 | 一种生产多峰乙烯聚合物的方法以及由其制备的薄膜 |
| CN114307672A (zh) * | 2021-12-13 | 2022-04-12 | 天津大学浙江研究院 | 一种二维晶种层介导共价有机框架膜及其制备和应用 |
| EP4344869A1 (en) | 2022-09-30 | 2024-04-03 | Borealis AG | Multimodal ethylene copolymer composition and films comprising the same |
| WO2024144127A1 (ko) * | 2022-12-29 | 2024-07-04 | 주식회사 엘지화학 | 폴리에틸렌 수지 조성물 |
| WO2024143973A1 (ko) * | 2022-12-29 | 2024-07-04 | 주식회사 엘지화학 | 폴리에틸렌 수지 조성물 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4302565A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
| US4438238A (en) * | 1981-01-30 | 1984-03-20 | Sumitomo Chemical Company, Limited | Low density copolymer composition of two ethylene-α-olefin copolymers |
| JPS588712A (ja) * | 1981-07-08 | 1983-01-18 | Showa Denko Kk | エチレン系共重合体の製造方法 |
| US5082902A (en) * | 1988-07-22 | 1992-01-21 | Mobil Oil Corporation | Method for reducing cycle time and improving molded part impact energy and ESCR of linear high density polyethylene using a blend of two linear polyethylenes of different densities |
| US5126398A (en) * | 1988-11-16 | 1992-06-30 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the in situ blending of polymers |
| US5047468A (en) | 1988-11-16 | 1991-09-10 | Union Carbide Chemicals And Plastics Technology Corporation | Process for the in situ blending of polymers |
| US5102955A (en) * | 1989-12-29 | 1992-04-07 | Mobil Oil Corporation | Broad distribution, high molecular weight low density polyethylene and method of making thereof |
| US5106926A (en) | 1990-12-11 | 1992-04-21 | Union Carbide Chemicals & Plastics Technology Corporation | Preparation of ethylene/1-octene copolymers of very low density in a fluidized bed reactor |
| EP0503791B1 (en) * | 1991-03-06 | 1997-04-16 | Mobil Oil Corporation | Process for producing bimodal ethylene polymers in tandem reactors |
| EP0528523B1 (en) * | 1991-07-24 | 2001-10-10 | Mobil Oil Corporation | Improved ethylene polymer film resins |
| US5250612A (en) * | 1991-10-07 | 1993-10-05 | The Dow Chemical Company | Polyethylene films exhibiting low blocking force |
| US5290745A (en) | 1992-08-10 | 1994-03-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing ethylene polymers having reduced hexane extractable content |
| US5284613A (en) * | 1992-09-04 | 1994-02-08 | Mobil Oil Corporation | Producing blown film and blends from bimodal high density high molecular weight film resin using magnesium oxide-supported Ziegler catalyst |
| JPH06136195A (ja) * | 1992-09-08 | 1994-05-17 | Mitsui Petrochem Ind Ltd | エチレン系共重合体組成物 |
-
1994
- 1994-07-08 US US08/272,260 patent/US5503914A/en not_active Expired - Lifetime
-
1995
- 1995-07-07 DE DE69532614T patent/DE69532614T2/de not_active Expired - Lifetime
- 1995-07-07 ES ES99100242T patent/ES2212393T3/es not_active Expired - Lifetime
- 1995-07-07 EP EP99100242A patent/EP0916693B1/en not_active Expired - Lifetime
- 1995-07-07 DE DE69518591T patent/DE69518591T2/de not_active Expired - Lifetime
- 1995-07-07 AT AT99100242T patent/ATE260314T1/de not_active IP Right Cessation
- 1995-07-07 JP JP07194008A patent/JP3113549B2/ja not_active Expired - Fee Related
- 1995-07-07 EP EP95304779A patent/EP0691367B1/en not_active Expired - Lifetime
- 1995-07-07 BR BR9503246A patent/BR9503246A/pt not_active Application Discontinuation
- 1995-07-07 ES ES95304779T patent/ES2151580T3/es not_active Expired - Lifetime
- 1995-07-07 AT AT95304779T patent/ATE195959T1/de not_active IP Right Cessation
- 1995-07-07 CA CA002153434A patent/CA2153434C/en not_active Expired - Fee Related
- 1995-07-07 AU AU24898/95A patent/AU681033B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DE69532614D1 (de) | 2004-04-01 |
| EP0691367B1 (en) | 2000-08-30 |
| ATE195959T1 (de) | 2000-09-15 |
| JPH0859910A (ja) | 1996-03-05 |
| EP0691367A1 (en) | 1996-01-10 |
| EP0916693B1 (en) | 2004-02-25 |
| AU2489895A (en) | 1996-01-18 |
| AU681033B2 (en) | 1997-08-14 |
| CA2153434C (en) | 1999-03-23 |
| US5503914A (en) | 1996-04-02 |
| JP3113549B2 (ja) | 2000-12-04 |
| BR9503246A (pt) | 1996-04-23 |
| ATE260314T1 (de) | 2004-03-15 |
| EP0916693A3 (en) | 1999-11-10 |
| DE69518591T2 (de) | 2001-04-26 |
| ES2212393T3 (es) | 2004-07-16 |
| CA2153434A1 (en) | 1996-01-09 |
| EP0916693A2 (en) | 1999-05-19 |
| DE69532614T2 (de) | 2004-08-12 |
| DE69518591D1 (de) | 2000-10-05 |
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