ES2154544B1 - Anodo para el desprendimiento de oxigeno en electrolitos que contienen fluoruros o aniones fluoruro-complejos. - Google Patents
Anodo para el desprendimiento de oxigeno en electrolitos que contienen fluoruros o aniones fluoruro-complejos.Info
- Publication number
- ES2154544B1 ES2154544B1 ES009800813A ES9800813A ES2154544B1 ES 2154544 B1 ES2154544 B1 ES 2154544B1 ES 009800813 A ES009800813 A ES 009800813A ES 9800813 A ES9800813 A ES 9800813A ES 2154544 B1 ES2154544 B1 ES 2154544B1
- Authority
- ES
- Spain
- Prior art keywords
- fluoride
- anode
- oxygen
- release
- complex anions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052760 oxygen Inorganic materials 0.000 title abstract 3
- 239000001301 oxygen Substances 0.000 title abstract 3
- 150000001450 anions Chemical class 0.000 title abstract 2
- 239000003792 electrolyte Substances 0.000 title abstract 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title 1
- 150000002222 fluorine compounds Chemical class 0.000 abstract 2
- 239000011229 interlayer Substances 0.000 abstract 2
- 230000001681 protective effect Effects 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 229910000765 intermetallic Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- -1 platinum group metals Chemical class 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Conductive Materials (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
Abstract
Ánodo para el desprendimiento de oxígeno en electrolitos que contienen fluoruros o aniones fluoruro-complejos, incluso en altas concentraciones. El ánodo comprende un sustrato de titanio provisto de una intercapa protectora resistente a la acción agresiva de los fluoruros, y un revestimiento electrocatalítico para el desprendimiento de oxígeno. La intercapa protectora está hecha de tungsteno, óxidos u oxifluoruros, opcionalmente conteniendo metales del grupo del platino en cantidades menores, compuestos metalocerámicos y compuestos intermetálicos, bien per se o bien como óxidos mixtos.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT97MI000908A IT1291604B1 (it) | 1997-04-18 | 1997-04-18 | Anodo per l'evoluzione di ossigeno in elettroliti contenenti fluoruri o loro derivati |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2154544A1 ES2154544A1 (es) | 2001-04-01 |
| ES2154544B1 true ES2154544B1 (es) | 2001-11-01 |
Family
ID=11376953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES009800813A Expired - Fee Related ES2154544B1 (es) | 1997-04-18 | 1998-04-17 | Anodo para el desprendimiento de oxigeno en electrolitos que contienen fluoruros o aniones fluoruro-complejos. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6019878A (es) |
| JP (1) | JPH10298792A (es) |
| AU (1) | AU736944B2 (es) |
| CA (1) | CA2234209A1 (es) |
| DE (1) | DE19817559A1 (es) |
| ES (1) | ES2154544B1 (es) |
| IT (1) | IT1291604B1 (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY144574A (en) * | 1998-09-14 | 2011-10-14 | Ibiden Co Ltd | Printed circuit board and method for its production |
| US6589405B2 (en) * | 2000-05-15 | 2003-07-08 | Oleh Weres | Multilayer oxide coated valve metal electrode for water purification |
| US20050011755A1 (en) * | 2001-08-14 | 2005-01-20 | Vladimir Jovic | Electrolytic cell and electrodes for use in electrochemical processes |
| FR2909390B1 (fr) * | 2006-11-30 | 2009-12-11 | Electro Rech | Anode pour dispositif d'electrodeposition de revetements metalliques anticorrosion ou cosmetique quelconque sur une piece metallique |
| DE102010043085A1 (de) * | 2010-10-28 | 2012-05-03 | Bayer Materialscience Aktiengesellschaft | Elektrode für die elektrolytische Chlorherstellung |
| WO2015198958A1 (ja) * | 2014-06-25 | 2015-12-30 | 新日鐵住金株式会社 | バスケット型アノード |
| US11426818B2 (en) | 2018-08-10 | 2022-08-30 | The Research Foundation for the State University | Additive manufacturing processes and additively manufactured products |
| CN109534460B (zh) * | 2018-12-25 | 2021-11-23 | 广东省稀有金属研究所 | 一种钛电极及其制备方法与应用 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62284095A (ja) * | 1986-06-02 | 1987-12-09 | Permelec Electrode Ltd | 耐久性を有する電解用電極及びその製造方法 |
| WO1989001994A1 (en) * | 1987-09-02 | 1989-03-09 | Moltech Invent S.A. | Molten salt electrolysis with non-consumable anode |
| US5314601A (en) * | 1989-06-30 | 1994-05-24 | Eltech Systems Corporation | Electrodes of improved service life |
-
1997
- 1997-04-18 IT IT97MI000908A patent/IT1291604B1/it active IP Right Grant
-
1998
- 1998-04-03 CA CA002234209A patent/CA2234209A1/en not_active Abandoned
- 1998-04-06 US US09/055,660 patent/US6019878A/en not_active Expired - Fee Related
- 1998-04-08 AU AU60713/98A patent/AU736944B2/en not_active Ceased
- 1998-04-17 JP JP10107218A patent/JPH10298792A/ja active Pending
- 1998-04-17 ES ES009800813A patent/ES2154544B1/es not_active Expired - Fee Related
- 1998-04-20 DE DE19817559A patent/DE19817559A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| DE19817559A1 (de) | 1998-10-22 |
| CA2234209A1 (en) | 1998-10-18 |
| ITMI970908A1 (it) | 1998-10-18 |
| US6019878A (en) | 2000-02-01 |
| AU736944B2 (en) | 2001-08-09 |
| AU6071398A (en) | 1998-10-22 |
| ES2154544A1 (es) | 2001-04-01 |
| IT1291604B1 (it) | 1999-01-11 |
| JPH10298792A (ja) | 1998-11-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EC2A | Search report published |
Date of ref document: 20010401 Kind code of ref document: A1 Effective date: 20010401 |
|
| FD1A | Patent lapsed |
Effective date: 20040419 |