ES2155075T3 - Metodo de revestimiento por inmersion, auto-acelerante y auto-renovador, sin formaldehido. - Google Patents
Metodo de revestimiento por inmersion, auto-acelerante y auto-renovador, sin formaldehido.Info
- Publication number
- ES2155075T3 ES2155075T3 ES94104003T ES94104003T ES2155075T3 ES 2155075 T3 ES2155075 T3 ES 2155075T3 ES 94104003 T ES94104003 T ES 94104003T ES 94104003 T ES94104003 T ES 94104003T ES 2155075 T3 ES2155075 T3 ES 2155075T3
- Authority
- ES
- Spain
- Prior art keywords
- metal
- self
- compsn
- accelerating
- immersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/50—Electroplating: Baths therefor from solutions of platinum group metals
- C25D3/52—Electroplating: Baths therefor from solutions of platinum group metals characterised by the organic bath constituents used
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/24—Reinforcing of the conductive pattern
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/42—Plated through-holes or plated via connections
- H05K3/423—Plated through-holes or plated via connections characterised by electroplating method
- H05K3/424—Plated through-holes or plated via connections characterised by electroplating method by direct electroplating
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/03—Metal processing
- H05K2203/0392—Pretreatment of metal, e.g. before finish plating, etching
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/108—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by semi-additive methods; masks therefor
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/382—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal
- H05K3/383—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal by microetching
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Chemically Coating (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Electroplating Methods And Accessories (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electrodes Of Semiconductors (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
SE DESCRIBE UN PROCESO PARA APLICAR UNA REVESTIMIENTO METALICO A UN SUSTRATO NO CONDUCTOR SIN UN REVESTIMIENTO SIN ELECTRODOS. EL PROCESO INCLUYE LAS FASES DE: A. CONTACTAR EL CITADO SUSTRATO CON UN ACTIVADOR QUE COMPRENDE UN SOL (COLOIDE QUIMICO) METALICO DEL GRUPO IVA/METAL NOBLE, PARA OBTENER UN SUSTRATO TRATADO; B. CONTACTAR EL CITADO SUSTRATO CON UNA COMPOSICION METALICA DE INMERSION DE RELLENAMIENTO Y AUTOACELERACION, COMPRENDIENDO UNA SOLUCION DE: (I) UNA SAL METALICA SOLUBLE CUYO METAL SEA MAS NOBLE QUE EL METAL DEL GRUPO IVA; (II) UN HIDROXIDO METALICO DEL GRUPO I A; (III) UN AGENTE COMPLEXANTE (SUSTANCIA CAPAZ DE FORMAR IONES COMPLEJOS), COMPRENDIENDO UN MATERIAL ORGANICO QUE TIENE UN LOGARITMO K CONSTANTE DE FORMACION ACUMULATIVA ENTRE 0''73 Y 21''95, PARA UN ION DEL METAL DE LA CITADA SAL METALICA. EL METAL DEL GRUPO IVA SE EMPLEA EN UN EXCESO ESTEQUIOMETRICO, COMPARADO CON EL METAL NOBLE, ESTANDO EL EXCESO DEL METAL DEL GRUPO IVA EN SU ESTADO DE OXIDACION MAS BAJO. TAMBIEN SE DESCRIBEN COMPOSICIONES METALICAS DE INMERSION NO FORMALDEHIDO DE RELLENAMIENTO Y AUTOACELERACION. LA COMPOSICION SE USA EN UN PROCESO DE DOS FASES PARA REVESTIR ELECTROLITICAMENTE UN SUSTRATO NO CONDUCTOR. EN LA PRIMERA FASE, LA CONDUCTIBILIDAD DEL SUSTRATO SE AUMENTA APLICANDO LA COMPOSICION A EL. EN LA SEGUNDA FASE, EL SUSTRATO TRATADO CON LA COMPOSICION SE REVISTE ELECTROLITICAMENTE CON UN METAL.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3448593A | 1993-03-18 | 1993-03-18 | |
| US12145593A | 1993-09-16 | 1993-09-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2155075T3 true ES2155075T3 (es) | 2001-05-01 |
Family
ID=26711015
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00117279T Expired - Lifetime ES2257987T3 (es) | 1993-03-18 | 1994-03-15 | Composicion y procedimiento para tratar una superficie revestida con un revestimiento de inmersion autoacelerante y autorenovador, sin formaldehido. |
| ES94104003T Expired - Lifetime ES2155075T3 (es) | 1993-03-18 | 1994-03-15 | Metodo de revestimiento por inmersion, auto-acelerante y auto-renovador, sin formaldehido. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00117279T Expired - Lifetime ES2257987T3 (es) | 1993-03-18 | 1994-03-15 | Composicion y procedimiento para tratar una superficie revestida con un revestimiento de inmersion autoacelerante y autorenovador, sin formaldehido. |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US5543182A (es) |
| EP (2) | EP1054081B1 (es) |
| JP (1) | JP3009326B2 (es) |
| KR (1) | KR100226178B1 (es) |
| AT (2) | ATE199413T1 (es) |
| CA (2) | CA2119050C (es) |
| CZ (2) | CZ287924B6 (es) |
| DE (2) | DE69434619T2 (es) |
| DK (1) | DK0616053T3 (es) |
| ES (2) | ES2257987T3 (es) |
| GR (1) | GR3035822T3 (es) |
| PT (1) | PT616053E (es) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9425030D0 (en) | 1994-12-09 | 1995-02-08 | Alpha Metals Ltd | Silver plating |
| GB9425031D0 (en) * | 1994-12-09 | 1995-02-08 | Alpha Metals Ltd | Printed circuit board manufacture |
| DE19510855C2 (de) * | 1995-03-17 | 1998-04-30 | Atotech Deutschland Gmbh | Verfahren zum selektiven oder partiellen elektrolytischen Metallisieren von Substraten aus nichtleitenden Materialien |
| US6905587B2 (en) | 1996-03-22 | 2005-06-14 | Ronald Redline | Method for enhancing the solderability of a surface |
| US6544397B2 (en) | 1996-03-22 | 2003-04-08 | Ronald Redline | Method for enhancing the solderability of a surface |
| EP0905285B1 (en) * | 1997-02-03 | 2000-12-27 | Okuno Chemical Industries Co., Ltd. | Method for electroplating nonconductive material |
| EP0913502B1 (en) | 1997-04-07 | 2006-05-31 | Okuno Chemical Industries Co., Ltd. | Method of electroplating nonconductive plastic molded product |
| US6121678A (en) * | 1997-12-19 | 2000-09-19 | Stmicroelectronics, Inc. | Wrap-around interconnect for fine pitch ball grid array |
| US6555170B2 (en) | 1998-01-30 | 2003-04-29 | Duratech Industries, Inc. | Pre-plate treating system |
| JP2000096252A (ja) * | 1998-09-18 | 2000-04-04 | C Uyemura & Co Ltd | ハードディスク基板へのめっき方法 |
| USRE45842E1 (en) | 1999-02-17 | 2016-01-12 | Ronald Redline | Method for enhancing the solderability of a surface |
| DE19918833C2 (de) * | 1999-04-22 | 2002-10-31 | Atotech Deutschland Gmbh | Verfahren zum elektrolytischen Abscheiden einer Metallschicht auf Oberflächen eines elektrisch nichtleitenden Substrats und Anwendung des Verfahrens |
| AU2001234935A1 (en) * | 2000-02-08 | 2001-08-20 | Duratech Industries, Inc. | Pre-plate treating system |
| DE10054544A1 (de) | 2000-11-01 | 2002-05-08 | Atotech Deutschland Gmbh | Verfahren zum chemischen Metallisieren von Oberflächen |
| KR20030026470A (ko) * | 2001-09-25 | 2003-04-03 | 전정식 | 비전도성 물질의 금 도금을 위한 전처리 방법 |
| US6645557B2 (en) | 2001-10-17 | 2003-11-11 | Atotech Deutschland Gmbh | Metallization of non-conductive surfaces with silver catalyst and electroless metal compositions |
| US20050006339A1 (en) | 2003-07-11 | 2005-01-13 | Peter Mardilovich | Electroless deposition methods and systems |
| US7078816B2 (en) * | 2004-03-31 | 2006-07-18 | Endicott Interconnect Technologies, Inc. | Circuitized substrate |
| US20060024481A1 (en) * | 2004-07-29 | 2006-02-02 | Eastman Kodak Company | Jet printing of patterned metal |
| CN1876891B (zh) * | 2005-06-10 | 2013-07-03 | 恩通公司 | 使不导电基底直接金属化的方法 |
| JP4970909B2 (ja) | 2005-11-30 | 2012-07-11 | テクノポリマー株式会社 | ダイレクト鍍金用樹脂組成物、成形品及び鍍金成形品 |
| JP2007239003A (ja) * | 2006-03-07 | 2007-09-20 | Univ Nagoya | Auメッキ方法及びAuメッキによるAu回路の製造方法 |
| ES2395736T3 (es) | 2007-05-03 | 2013-02-14 | Atotech Deutschland Gmbh | Procedimiento para aplicar un revestimiento metálico a un substrato no conductor |
| US8440916B2 (en) * | 2007-06-28 | 2013-05-14 | Intel Corporation | Method of forming a substrate core structure using microvia laser drilling and conductive layer pre-patterning and substrate core structure formed according to the method |
| US8877565B2 (en) * | 2007-06-28 | 2014-11-04 | Intel Corporation | Method of forming a multilayer substrate core structure using sequential microvia laser drilling and substrate core structure formed according to the method |
| EP2180770A1 (en) | 2008-10-21 | 2010-04-28 | Atotech Deutschland Gmbh | Method to form solder deposits on substrates |
| EP2244285A1 (en) | 2009-04-24 | 2010-10-27 | ATOTECH Deutschland GmbH | Method to form solder deposits on substrates |
| JP5371393B2 (ja) | 2008-11-27 | 2013-12-18 | ユーエムジー・エービーエス株式会社 | めっき用樹脂組成物、及び樹脂めっき製品 |
| WO2010073903A1 (ja) * | 2008-12-26 | 2010-07-01 | 富士フイルム株式会社 | 表面金属膜材料、表面金属膜材料の作製方法、金属パターン材料の作製方法、及び金属パターン材料 |
| EP2305856A1 (en) * | 2009-09-28 | 2011-04-06 | ATOTECH Deutschland GmbH | Process for applying a metal coating to a non-conductive substrate |
| PT2360294E (pt) | 2010-02-12 | 2013-06-28 | Atotech Deutschland Gmbh | Processo para a metalização de objectos apresentando no mínimo duas matérias plásticas diferentes à superfície |
| US8497359B2 (en) * | 2010-02-26 | 2013-07-30 | Ppg Industries Ohio, Inc. | Cationic electrodepositable coating composition comprising lignin |
| DE102010012204B4 (de) * | 2010-03-19 | 2019-01-24 | MacDermid Enthone Inc. (n.d.Ges.d. Staates Delaware) | Verbessertes Verfahren zur Direktmetallisierung von nicht leitenden Substraten |
| EP2405469B1 (en) | 2010-07-05 | 2016-09-21 | ATOTECH Deutschland GmbH | Method to form solder alloy deposits on substrates |
| EP2405468A1 (en) | 2010-07-05 | 2012-01-11 | ATOTECH Deutschland GmbH | Method to form solder deposits on substrates |
| EP2416634A1 (en) | 2010-08-02 | 2012-02-08 | ATOTECH Deutschland GmbH | Method to form solder deposits on substrates |
| US20130105329A1 (en) | 2010-08-02 | 2013-05-02 | Atotech Deutschland Gmbh | Method to form solder deposits and non-melting bump structures on substrates |
| EP2506690A1 (en) | 2011-03-28 | 2012-10-03 | Atotech Deutschland GmbH | Method to form solder deposits and non-melting bump structures on substrates |
| EP2603558B1 (en) | 2010-08-09 | 2015-04-15 | Styrolution Europe GmbH | Thermoplastic moulding compositions with improved adhesion of electroplated metal layer |
| EP2652035B1 (en) | 2010-12-16 | 2024-03-27 | INEOS Styrolution Europe GmbH | Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact |
| EP2602357A1 (en) | 2011-12-05 | 2013-06-12 | Atotech Deutschland GmbH | Novel adhesion promoting agents for metallization of substrate surfaces |
| CA2860596C (en) | 2012-02-01 | 2020-08-18 | Atotech Deutschland Gmbh | Electroless nickel plating bath |
| EP2639334A1 (de) | 2012-03-15 | 2013-09-18 | Atotech Deutschland GmbH | Verfahren zum Metallisieren nichtleitender Kunststoffoberflächen |
| EP2644744A1 (en) | 2012-03-29 | 2013-10-02 | Atotech Deutschland GmbH | Method for promoting adhesion between dielectric substrates and metal layers |
| ES2573137T3 (es) | 2012-09-14 | 2016-06-06 | Atotech Deutschland Gmbh | Método de metalización de sustratos de célula solar |
| EP2937447B1 (en) | 2012-12-21 | 2018-10-10 | Okuno Chemical Industries Co., Ltd. | Conductive coating film forming bath |
| KR102165629B1 (ko) * | 2013-09-25 | 2020-10-15 | 아토테크더치랜드게엠베하 | 배리어 층에 구리 시드 층을 증착하기 위한 방법 및 구리 도금 욕 |
| CN114107984A (zh) | 2013-09-26 | 2022-03-01 | 德国艾托特克公司 | 用于衬底表面金属化的新颖粘着促进方法 |
| CN105765104A (zh) | 2014-01-27 | 2016-07-13 | 奥野制药工业株式会社 | 导电膜形成浴 |
| ES2785400T3 (es) | 2014-04-01 | 2020-10-06 | Atotech Deutschland Gmbh | Composición y procedimiento para metalizar superficies de plástico no conductor |
| CN104668232A (zh) * | 2015-03-05 | 2015-06-03 | 苏州市凯业金属制品有限公司 | 一种塑胶制品表面处理方法 |
| CN105112966A (zh) * | 2015-09-22 | 2015-12-02 | 太仓市金鹿电镀有限公司 | 一种高耐磨洗衣机门圈表面环保塑料电镀工艺 |
| JP6270927B2 (ja) | 2016-07-08 | 2018-01-31 | 日本エイアンドエル株式会社 | めっき用樹脂組成物及びめっき成形品 |
| CN110115116B (zh) | 2016-12-23 | 2022-05-27 | 德国艾托特克公司 | 在接触垫上形成可焊接焊料沉积物的方法 |
| KR20220002555A (ko) | 2019-05-01 | 2022-01-06 | 후지필름 일렉트로닉 머티리얼스 유.에스.에이., 아이엔씨. | 에칭 조성물 |
| CN114258424B (zh) * | 2019-06-13 | 2023-07-04 | 富士胶片电子材料美国有限公司 | 蚀刻组合物 |
| CN111018273A (zh) * | 2020-01-16 | 2020-04-17 | 泉州南京大学环保产业研究院 | 一种电催化-生物联合处理甲醛废水的方法 |
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| JPH0544075A (ja) * | 1991-08-15 | 1993-02-23 | Nippon Riironaale Kk | 無電解銅めつき代替銅ストライクめつき方法 |
| US5376248A (en) * | 1991-10-15 | 1994-12-27 | Enthone-Omi, Inc. | Direct metallization process |
-
1994
- 1994-03-15 EP EP00117279A patent/EP1054081B1/en not_active Expired - Lifetime
- 1994-03-15 CA CA002119050A patent/CA2119050C/en not_active Expired - Lifetime
- 1994-03-15 DE DE69434619T patent/DE69434619T2/de not_active Expired - Lifetime
- 1994-03-15 EP EP94104003A patent/EP0616053B9/en not_active Expired - Lifetime
- 1994-03-15 DK DK94104003T patent/DK0616053T3/da active
- 1994-03-15 ES ES00117279T patent/ES2257987T3/es not_active Expired - Lifetime
- 1994-03-15 PT PT94104003T patent/PT616053E/pt unknown
- 1994-03-15 AT AT94104003T patent/ATE199413T1/de active
- 1994-03-15 DE DE69426732T patent/DE69426732T3/de not_active Expired - Lifetime
- 1994-03-15 AT AT00117279T patent/ATE317026T1/de not_active IP Right Cessation
- 1994-03-15 ES ES94104003T patent/ES2155075T3/es not_active Expired - Lifetime
- 1994-03-15 CA CA002222158A patent/CA2222158C/en not_active Expired - Lifetime
- 1994-03-17 KR KR1019940005301A patent/KR100226178B1/ko not_active Expired - Fee Related
- 1994-03-18 CZ CZ1994641A patent/CZ287924B6/cs not_active IP Right Cessation
- 1994-03-18 JP JP6072801A patent/JP3009326B2/ja not_active Expired - Lifetime
-
1995
- 1995-02-16 US US08/389,565 patent/US5543182A/en not_active Expired - Lifetime
-
1996
- 1996-05-14 US US08/645,743 patent/US5725640A/en not_active Expired - Lifetime
-
2000
- 2000-08-30 CZ CZ20003161A patent/CZ290390B6/cs not_active IP Right Cessation
-
2001
- 2001-04-30 GR GR20010400670T patent/GR3035822T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CZ287924B6 (cs) | 2001-03-14 |
| EP0616053B9 (en) | 2010-09-15 |
| US5725640A (en) | 1998-03-10 |
| EP0616053A1 (en) | 1994-09-21 |
| DE69426732T3 (de) | 2010-11-25 |
| DE69426732D1 (de) | 2001-04-05 |
| EP1054081A3 (en) | 2001-12-05 |
| CA2119050C (en) | 1999-11-23 |
| CA2222158A1 (en) | 1994-09-19 |
| EP0616053B3 (en) | 2010-05-05 |
| KR940021765A (ko) | 1994-10-19 |
| ATE317026T1 (de) | 2006-02-15 |
| CZ64194A3 (en) | 1995-08-16 |
| CZ290390B6 (cs) | 2002-07-17 |
| KR100226178B1 (ko) | 1999-10-15 |
| GR3035822T3 (en) | 2001-07-31 |
| EP0616053B1 (en) | 2001-02-28 |
| PT616053E (pt) | 2001-07-31 |
| US5543182A (en) | 1996-08-06 |
| ES2257987T3 (es) | 2006-08-16 |
| DE69434619T2 (de) | 2006-08-17 |
| EP1054081A2 (en) | 2000-11-22 |
| EP1054081B1 (en) | 2006-02-01 |
| JP3009326B2 (ja) | 2000-02-14 |
| ATE199413T1 (de) | 2001-03-15 |
| CA2119050A1 (en) | 1994-09-19 |
| CA2222158C (en) | 2001-01-30 |
| JPH0711487A (ja) | 1995-01-13 |
| DE69434619D1 (de) | 2006-04-13 |
| DK0616053T3 (da) | 2001-06-18 |
| DE69426732T2 (de) | 2001-06-13 |
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