ES2155111T3 - Procedimiento para preparar catalizadores para la obtencion de oxido de etileno. - Google Patents

Procedimiento para preparar catalizadores para la obtencion de oxido de etileno.

Info

Publication number
ES2155111T3
ES2155111T3 ES95203469T ES95203469T ES2155111T3 ES 2155111 T3 ES2155111 T3 ES 2155111T3 ES 95203469 T ES95203469 T ES 95203469T ES 95203469 T ES95203469 T ES 95203469T ES 2155111 T3 ES2155111 T3 ES 2155111T3
Authority
ES
Spain
Prior art keywords
support
procedure
ethylene oxide
amount
renio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95203469T
Other languages
English (en)
Inventor
Richard A Kemp
Wayne E Evans
Marek Matusz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27408317&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2155111(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of ES2155111T3 publication Critical patent/ES2155111T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

ESTA INVENCION SE REFIERE A UN PROCEDIMIENTO PARA LA PREPARACION DE UN CATALIZADOR DE OXIDO DE ETILENO QUE TIENE UNA ESTABILIDAD DE SELECTIVIDAD MEJORADA, DICHO PROCESO CONSISTE EN DEPOSITAR UNA CANTIDAD PROMOTORA DE UN ELEMENTO DEL GRUPO I SELECCIONADO DEL GRUPO QUE CONSISTE EN POTASIO, LITIO Y MEZCLAS DE LOS MISMOS, SOBRE UN SOPORTE REFRACTARIO POROSO, SECAR AL MENOS PARCIALMENTE EL SOPORTE, TRAS LO CUAL SE DEPOSITA UNA CANTIDAD CATALITICAMENTE EFECTIVA DE PLATA, UNA CANTIDAD PROMOTORA DE METAL ALCALINO, UNA CANTIDAD PROMOTORA DE RENIO Y, OPCIONALMENTE, UNA CANTIDAD PROMOTORA DE UN COPROMOTOR DE RENIO SELECCIONADO DEL AZUFRE, MOLIBDENO, TUNGSTENO, CROMO, FOSFORO, BORO Y MEZCLAS DE LOS MISMOS, SOBRE EL SOPORTE, Y SECAR POSTERIORMENTE EL SOPORTE.
ES95203469T 1994-12-15 1995-12-13 Procedimiento para preparar catalizadores para la obtencion de oxido de etileno. Expired - Lifetime ES2155111T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US35762194A 1994-12-15 1994-12-15
US35762094A 1994-12-15 1994-12-15
US43951295A 1995-05-11 1995-05-11

Publications (1)

Publication Number Publication Date
ES2155111T3 true ES2155111T3 (es) 2001-05-01

Family

ID=27408317

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95203469T Expired - Lifetime ES2155111T3 (es) 1994-12-15 1995-12-13 Procedimiento para preparar catalizadores para la obtencion de oxido de etileno.

Country Status (4)

Country Link
EP (1) EP0716884B2 (es)
JP (1) JP4172827B2 (es)
DE (1) DE69520409T3 (es)
ES (1) ES2155111T3 (es)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4206404B2 (ja) * 1995-09-25 2009-01-14 三菱化学株式会社 酸化エチレン製造用触媒
US5705661A (en) * 1995-09-25 1998-01-06 Mitsubishi Chemical Corporation Catalyst for production of ethylene oxide
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
RU2234370C2 (ru) * 1998-09-14 2004-08-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения катализаторов с улучшенными каталитическими свойствами
US7504525B2 (en) 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
ID28790A (id) 1998-09-14 2001-07-05 Shell Int Research Bahan pembawa katalis epoksidasi, pembuatan dan penggunaannya
US7232918B2 (en) 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
US7232786B2 (en) 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
US6750173B2 (en) 2002-04-08 2004-06-15 Scientific Design Company, Inc. Ethylene oxide catalyst
AU2003243757A1 (en) 2002-06-28 2004-01-19 Shell Oil Company A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
MX245604B (es) 2002-06-28 2007-05-04 Shell Int Research Metodo para iniciar un proceso de epoxidacion y proceso de epoxidacion de una olefina.
WO2004039790A1 (en) * 2002-10-28 2004-05-13 Shell Internationale Research Maatschappij B.V. Olefin oxide catalysts
TWI346574B (en) 2003-03-31 2011-08-11 Shell Int Research A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition
US7348444B2 (en) 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US6846774B2 (en) 2003-04-23 2005-01-25 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040224841A1 (en) 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
CA2524890C (en) 2003-05-07 2012-09-11 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver­containing catalysts, and the use thereof
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
TW200600190A (en) 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
RU2007115405A (ru) 2004-09-24 2008-10-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ выбора формированных частиц, способ сборки системы, способ реагирования газообразного сырья в такой системе, компьютерный программный продукт и компьютерная система
JP2007301554A (ja) * 2006-04-10 2007-11-22 Mitsubishi Chemicals Corp 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
EP1955766A4 (en) * 2006-04-10 2013-02-13 Mitsubishi Chem Corp CATALYST FOR ETHYLENE OXIDE GENERATION, PRODUCTION METHOD AND METHOD FOR PRODUCING ETHYLENE OXIDE
JP4978277B2 (ja) * 2006-04-10 2012-07-18 三菱化学株式会社 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
CN101360562B (zh) * 2006-04-10 2013-02-06 三菱化学株式会社 环氧乙烷制造用催化剂及其制造方法、以及环氧乙烷的制造方法
US8501664B2 (en) 2006-11-20 2013-08-06 Shell Oil Company Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
TWI446964B (zh) 2007-05-09 2014-08-01 Shell Int Research 環氧化催化劑，製備該催化劑之方法及製備烯烴氧化物、１，２-二醇、１，２-二醇醚、１，２-碳酸酯或烷醇胺之方法
CN102056909B (zh) 2008-05-07 2014-03-05 国际壳牌研究有限公司 环氧化工艺的开车方法及环氧乙烷、1，2-二醇、1，2-二醇醚、1，2-碳酸酯或链烷醇胺的制备方法
JP5868703B2 (ja) 2008-05-07 2016-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー オレフィンオキシド、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートまたはアルカノールアミンの製造方法
CN102099346A (zh) 2008-07-14 2011-06-15 巴斯夫欧洲公司 制备环氧乙烷的方法
US8524927B2 (en) 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
US8987482B2 (en) 2011-10-28 2015-03-24 Basf Se Process for producing a supported silver catalyst
JP5797143B2 (ja) * 2012-03-26 2015-10-21 株式会社日本触媒 エチレンオキシド製造用触媒およびそれを用いたエチレンオキシド製造方法。
EP3548471B1 (en) 2016-12-02 2021-05-19 Shell Internationale Research Maatschappij B.V. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide
CN111655368A (zh) 2018-02-07 2020-09-11 巴斯夫欧洲公司 制备银浸渍溶液的方法
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
CN111437826B (zh) * 2019-01-16 2022-07-12 中国石油化工股份有限公司 一种负载型银催化剂及其制备方法和应用
CN111905733B (zh) * 2019-05-09 2022-10-18 中国石油化工股份有限公司 活化银催化剂的方法和应用
EP3885038A1 (en) 2020-03-27 2021-09-29 Basf Se Process for producing an epoxidation catalyst
JP7805320B2 (ja) 2020-06-26 2026-01-23 ビーエーエスエフ ソシエタス・ヨーロピア 多孔質アルファ－アルミナ触媒支持体を生成する方法
WO2021260140A1 (en) 2020-06-26 2021-12-30 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
US20230256420A1 (en) 2020-06-26 2023-08-17 Basf Se Shaped catalyst body for the production of ethylene oxide
CN116723893A (zh) 2021-01-26 2023-09-08 巴斯夫欧洲公司 环氧化催化剂
CN117545552A (zh) 2021-06-25 2024-02-09 巴斯夫欧洲公司 高纯度压片阿尔法氧化铝催化剂载体
EP4601789A1 (en) 2022-10-12 2025-08-20 Basf Se Epoxidation catalyst
WO2026027443A1 (en) 2024-07-29 2026-02-05 Basf Se Blended catalyst mix for epoxidation

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702259A (en) 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4010115A (en) 1972-01-07 1977-03-01 Shell Oil Company Catalyst for the oxidation of ethylene to ethylene oxide
US4356312A (en) 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US3962136A (en) 1972-01-07 1976-06-08 Shell Oil Company Catalyst for production of ethylene oxide
GB1491447A (en) † 1973-12-05 1977-11-09 Ici Ltd Alkylene oxide production and catalysts therefor
US4207210A (en) * 1973-10-26 1980-06-10 Shell Oil Company Process for preparing an ethylene oxide catalyst
US4916243A (en) † 1979-03-20 1990-04-10 Union Carbide Chemicals And Plastics Company Inc. New catalyst composition and process for oxidation of ethylene to ethylene oxide
IN170003B (es) * 1985-06-28 1992-01-25 Shell Int Research
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst
US4766105A (en) 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
IN169589B (es) † 1986-10-31 1991-11-16 Shell Int Research
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
JP2561678B2 (ja) * 1987-11-06 1996-12-11 三菱化学株式会社 エチレンオキシド製造用銀触媒
US5102848A (en) † 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
JP3233652B2 (ja) † 1991-05-21 2001-11-26 株式会社日本触媒 エチレンオキシド製造用銀触媒

Also Published As

Publication number Publication date
EP0716884B1 (en) 2001-03-21
EP0716884A3 (en) 1996-11-27
EP0716884A2 (en) 1996-06-19
DE69520409T3 (de) 2010-02-18
JP4172827B2 (ja) 2008-10-29
DE69520409D1 (de) 2001-04-26
JPH08224477A (ja) 1996-09-03
DE69520409T2 (de) 2001-09-06
EP0716884B2 (en) 2009-09-23

Similar Documents

Publication Publication Date Title
ES2155111T3 (es) Procedimiento para preparar catalizadores para la obtencion de oxido de etileno.
ES2166468T3 (es) Procedimiento para preparar catalizadores de epoxidacion.
ES2099758T3 (es) Procedimiento para preparar catalizadores para polimerizacion por adicion mediante oxidacion del nucleo metalico.
BG81605A (bg) Катализатор и метод за каталитично получаване на етиленов окис
ES2158133T3 (es) Catalizador para la obtencion de oxido de etileno, y procedimiento para su obtencion.
ES2185930T3 (es) Tdamices moleculares cataliticos no zeoliticos de poros pequeños que contienen metales alcalino-terreos y su uso en la conversion de compuestos oxigenados.
TR200003273A2 (tr) Olefinler'den katalitik olarak aldehit imalatına yönelik usul
BR0016380B1 (pt) complexo metálico, processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica.
BR0002178B1 (pt) processo para a realização catalìtica de reações de fases mútiplas de hidroformilação de olefinas e o uso de aldeìdos por ele produzidos.
DK1097158T3 (da) Ligander til metaller og metalkatalyserede metoder
ES2123343T3 (es) Oxidos metalicos mixtos microporosos, amorfos, para catalisis selectiva para una forma.
ES2118551T3 (es) Catalizador de epoxidacion y su procedimiento de preparacion.
BR0014779B1 (pt) equipamento para remoção de pelo menos um óxido de nitrogênio a partir de um fluido.
ES2033889T3 (es) Paquete de catalizador para la oxidacion de amoniaco.
DE69203881D1 (de) Verbesserte keramische Beschichtung für katalysatorträger.
TR199900709A3 (tr) Seçici parafin amoksidasyonu için molibden yükselticili vanadyum-antimon-oksit bazli katalizör.
NO875393D0 (no) Fremgangsmaate for fjernelse av metaller, spesielt tungmetaller, fra spillvann.
AR017429A1 (es) Catalizador de acetato de vinilo que comprende paladio, oro, cobre y un cuarto metal y proceso para la produccion de acetato de vinilo por reaccion de etileno, oxigeno o acido acetico como reactivos
ES2068419T3 (es) Catalizador y procedimiento de deshidrogenacion y deshidrociclacion.
ES2034586T3 (es) Procedimiento para la hidrogenacion de clorofluoroalquenos.
AR015979A1 (es) Catalizador de acetato de vinilo que comprende paladio, oro y cualquiera de ciertos metales terciarios.
BR0212571A (pt) compósito catalìtico; método de fabricação de um compósito catalìtico; e método de desproteger cataliticamente um composto orgánico que tem um grupo funcional protegido
AR028067A1 (es) Un soporte de catalizador y un catalizador de metal soportado, un proceso para su preparacion y la utilizacion del catalizador
BR9406918A (pt) Catalisador adequado para a epoxidaçao de olefinas e processo para preparar o mesmo
DE69817282D1 (de) Neue Katalysatoren für die Umwandlungsreaktionen von organischen Verbindungen

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 716884

Country of ref document: ES