ES2156880T3 - Procedimiento de epoxidacion asimetrica utilizando complejos de manganeso opticamente activos. - Google Patents

Procedimiento de epoxidacion asimetrica utilizando complejos de manganeso opticamente activos.

Info

Publication number
ES2156880T3
ES2156880T3 ES94103924T ES94103924T ES2156880T3 ES 2156880 T3 ES2156880 T3 ES 2156880T3 ES 94103924 T ES94103924 T ES 94103924T ES 94103924 T ES94103924 T ES 94103924T ES 2156880 T3 ES2156880 T3 ES 2156880T3
Authority
ES
Spain
Prior art keywords
group
optically active
active manganese
rent
hydrogen atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94103924T
Other languages
English (en)
Inventor
Tsutomu Katsuki
Ryo Irie
Hidehiko Sasaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Application granted granted Critical
Publication of ES2156880T3 publication Critical patent/ES2156880T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005—Compounds without a metal-carbon linkage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN COMPLEJO DE MANGANESO OPTICAMENTE ACTIVOS DE LA FORMULA I O I'': EN DONDE R1, R2, R3 Y R4 REPRESENTAN INDEPENDIENTEMENTE ATOMO DE HIDROGENO, GRUPO ALQUILO C1-C4, GRUPO FENILO QUE PUEDE ESTAR SUSTITUIDO POR UN ATOMO HALOGENO, GRUPO ALQUILO C1-C4, GRUPO ALCOXILO C1-C4, GRUPO CIANO O GRUPO NITRO; Y DOS CUALESQUIERA DE R1, R2, R3 Y R4 JUNTOS FORMAN EL ANILLO C4-C8, XREPRESENTA UN CONTRA ANION QUE PUEDE FORMAR UNA SAL, Y REPRESENTA ATOMO DE HIDROGENO, ATOMO HALOGENO, GRUPO ALQUILO C1-C4, GRUPO ALCOXILO C1-C4, GRUPO NITRO O GRUPO CIANO, R REPRESENTA ATOMO DE HIDROGENO, GRUPO ALQUILO C1-C4, GRUPO FENILO QUE PUEDE ESTAR SUSTITUIDO POR ATOMO HALOGENO, GRUPO ALQUILO C1-C4 O GRUPO ALCOXILO C1-C4, O GRUPO SILILO SUSTITUIDO Y UN PROCESO PARA PRODUCIR COMPUESTOS EPOXIDICOS QUE USA EL COMPLEJO COMO UN CATALIZADOR.
ES94103924T 1994-02-23 1994-03-14 Procedimiento de epoxidacion asimetrica utilizando complejos de manganeso opticamente activos. Expired - Lifetime ES2156880T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2533794 1994-02-23

Publications (1)

Publication Number Publication Date
ES2156880T3 true ES2156880T3 (es) 2001-08-01

Family

ID=12163108

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94103924T Expired - Lifetime ES2156880T3 (es) 1994-02-23 1994-03-14 Procedimiento de epoxidacion asimetrica utilizando complejos de manganeso opticamente activos.

Country Status (5)

Country Link
US (1) US5420314A (es)
EP (1) EP0669339B1 (es)
CA (1) CA2119002C (es)
DE (1) DE69427278T2 (es)
ES (1) ES2156880T3 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3322877B2 (ja) * 1992-08-06 2002-09-09 スミスクライン・ビーチャム・パブリック・リミテッド・カンパニー キラル触媒およびその触媒によるエポキシ化反応
CZ24499A3 (cs) * 1996-07-26 1999-05-12 Nissan Chemical Industries, Ltd. Derivát chromanu a farmaceutický prostředek, který ho obsahuje
US5744620A (en) * 1997-07-10 1998-04-28 Bayer Corporation Catalytic oxidation of cyclic olefins
US5998606A (en) * 1997-11-10 1999-12-07 Grandics; Peter Mn(IV)-mediated crosslinking and functionalization of chromatography media
US6486178B1 (en) 1998-06-03 2002-11-26 Nissan Chemical Industries, Ltd. Indane derivatives
EP1214307B1 (en) 1999-09-24 2004-04-07 Nissan Chemical Industries, Ltd. 4-oxybenzopyran derivative
US6677371B1 (en) 1999-10-05 2004-01-13 Nissan Chemical Industries, Ltd. 4-oxybenzopyran derivative
EP1401823B1 (en) * 2001-06-25 2005-10-05 Nissan Chemical Industries, Ltd. Substituted benzopyran derivatives against arrhythmia

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2876712B2 (ja) * 1989-07-17 1999-03-31 日産化学工業株式会社 光学活性ピラノベンゾオキサジアゾール誘導体
US5097037A (en) * 1989-07-17 1992-03-17 Nissan Chemical Industries, Ltd. Process for the optical resolution of pyranobenzoxadiazole compounds
JPH05301878A (ja) * 1991-08-30 1993-11-16 Nissan Chem Ind Ltd 不斉エポキシ化反応
US5352814A (en) * 1991-08-30 1994-10-04 Nissan Chemical Industries, Ltd. Asymmetric epoxidation reaction

Also Published As

Publication number Publication date
EP0669339B1 (en) 2001-05-23
EP0669339A1 (en) 1995-08-30
CA2119002C (en) 1999-01-19
DE69427278T2 (de) 2001-10-25
CA2119002A1 (en) 1995-08-24
DE69427278D1 (de) 2001-06-28
US5420314A (en) 1995-05-30

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