ES2163842T3 - Recuperacion de ozono por zeolitas adsorbentes. - Google Patents

Recuperacion de ozono por zeolitas adsorbentes.

Info

Publication number
ES2163842T3
ES2163842T3 ES98303552T ES98303552T ES2163842T3 ES 2163842 T3 ES2163842 T3 ES 2163842T3 ES 98303552 T ES98303552 T ES 98303552T ES 98303552 T ES98303552 T ES 98303552T ES 2163842 T3 ES2163842 T3 ES 2163842T3
Authority
ES
Spain
Prior art keywords
zeolite
zone
ozone
adsorbent
ozone recovery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98303552T
Other languages
English (en)
Inventor
Edward Landis Weist Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Application granted granted Critical
Publication of ES2163842T3 publication Critical patent/ES2163842T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10—Preparation of ozone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/14—Ozone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/402—Further details for adsorption processes and devices using two beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407—Constructional details of adsorbing systems
    • B01D53/0423—Beds in columns
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y10S95/902—Molecular sieve

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

LA INVENCION SE REFIERE A LA RECUPERACION DE OZONO PROCEDENTE DE UNA MEZCLA OZONO-OXIGENO, MEDIANTE ADSORCION, UTILIZANDO UN ADSORBENTE QUE COMPRENDE UNA ZEOLITA SELECCIONADA A PARTIR DE: (I) ZEOLITA DE TIPO L CON INTERCAMBIO DE AMONIO, ZEOLITA DE TIPO Y, ZSM-5 O MORDENITA E (II) ZEOLITA DE TIPO L CON INTERCAMBIO DE PROTONES, EN LA QUE AL MENOS EL 90 % DEL CONTENIDO DE CATION SUSTITUIBLE ESTA EN LA FORMA AMONIO DE LA ZEOLITA (I) O EN LA FORMA PROTONICA DE LA ZEOLITA (II) Y LA RELACION MOLAR DE POTASIO A ALUMINIO ES INFERIOR A 0,25.
ES98303552T 1997-05-09 1998-05-05 Recuperacion de ozono por zeolitas adsorbentes. Expired - Lifetime ES2163842T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/853,965 US5846298A (en) 1997-05-09 1997-05-09 Ozone recovery by zeolite adsorbents

Publications (1)

Publication Number Publication Date
ES2163842T3 true ES2163842T3 (es) 2002-02-01

Family

ID=25317372

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98303552T Expired - Lifetime ES2163842T3 (es) 1997-05-09 1998-05-05 Recuperacion de ozono por zeolitas adsorbentes.

Country Status (6)

Country Link
US (1) US5846298A (es)
EP (1) EP0876994B1 (es)
BR (1) BR9801576A (es)
CA (1) CA2236611C (es)
DE (1) DE69801544T2 (es)
ES (1) ES2163842T3 (es)

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US5951957A (en) * 1996-12-10 1999-09-14 Competitive Technologies Of Pa, Inc. Method for the continuous destruction of ozone
GB9712165D0 (en) * 1997-06-11 1997-08-13 Air Prod & Chem Processes and apparatus for producing a gaseous product
US6099619A (en) * 1997-10-09 2000-08-08 Uop Llc Purification of carbon dioxide
KR100307344B1 (ko) * 1998-04-02 2001-09-24 마스다 노부유키 고농도 오존 가스의 제조 방법 및 그 장치
JP3692237B2 (ja) * 1998-04-03 2005-09-07 三菱重工業株式会社 オゾンの貯蔵方法及びその装置
JP3434197B2 (ja) 1998-04-03 2003-08-04 三菱重工業株式会社 オゾン吸着剤、オゾン吸着用成形体及びその製造方法
US6511528B1 (en) 1999-03-26 2003-01-28 Uop Llc Purification of carbon dioxide
US6136284A (en) * 1999-12-09 2000-10-24 The Boc Group, Inc. Process for the removal of nitrogen oxides from gas streams
JP3829600B2 (ja) * 2000-01-31 2006-10-04 マツダ株式会社 吸着剤とそれを用いた吸着装置及びその他の物品並びに吸着方法
JP2001248794A (ja) * 2000-03-02 2001-09-14 Kansai Electric Power Co Inc:The オゾン貯蔵方法および装置
DE10012224A1 (de) * 2000-03-14 2001-09-27 Xcellsis Gmbh Verfahren zur Verkürzung der Startzeit von CO-Oxidationskatalysatoren in mobilen Brennstoffzellensystemen
TWI238079B (en) * 2001-11-27 2005-08-21 Nippon Oxygen Co Ltd Method and device for separating gas
GB0209232D0 (en) * 2002-04-23 2002-06-05 Univ Bradford Adsorbents
US6916359B2 (en) * 2002-04-25 2005-07-12 The Boc Group, Inc. Ozone production processes
US20040149234A1 (en) * 2002-12-04 2004-08-05 Mathur Ashok N. Decentralized oxygen supply system for aquaculture
US6837917B2 (en) * 2003-05-22 2005-01-04 Guild Associates, Inc. Process for the removal of ethylene oxide from air
TWI294871B (en) * 2003-12-17 2008-03-21 Tokyo Electron Ltd Ozone processing apparatus and ozone processing method
US7392657B2 (en) * 2004-06-09 2008-07-01 American Air Liquide, Inc. Methods of dissolving ozone in a cryogen
US7766995B2 (en) * 2006-05-01 2010-08-03 Linde Llc Ozone production processes and its use in industrial processes
JP5427412B2 (ja) * 2006-11-24 2014-02-26 岩谷産業株式会社 オゾンガス濃縮方法及びその装置
CN101878182B (zh) * 2007-11-30 2013-01-09 三菱电机株式会社 臭氧浓缩装置
US7819947B2 (en) * 2008-02-12 2010-10-26 Air Products And Chemical, Inc. Ozone production by pressure swing adsorption using a protective adsorbed component
JP2009286683A (ja) * 2008-06-02 2009-12-10 Kyuchaku Gijutsu Kogyo Kk 吸着剤を利用したオゾンの製造・貯蔵方法
US8029603B2 (en) * 2009-01-23 2011-10-04 Air Products And Chemicals, Inc. Pressure swing adsorption cycle for ozone production
US8337674B2 (en) * 2009-01-23 2012-12-25 Air Products And Chemicals, Inc. Ozone production by pressure swing adsorption using a noble gas additive
JP5888908B2 (ja) * 2011-09-09 2016-03-22 岩谷産業株式会社 オゾンガスの濃縮方法
US9126855B2 (en) 2012-06-14 2015-09-08 Air Products And Chemicals, Inc. Methods for using ozone to enhance anaerobic digestion
CN105498686B (zh) * 2014-09-23 2017-11-14 中国石油化工股份有限公司 一种分子筛改性提高吸附性能的方法
GB2545759A (en) * 2015-12-21 2017-06-28 Linde Ag Methods for producing ozone
CN109865409A (zh) * 2017-12-05 2019-06-11 钟多琳 在常温常压下降低臭氧浓度和/或消除臭氧的方法
CN113582139B (zh) * 2021-07-01 2023-11-21 光大水务科技发展（南京）有限公司 一种空气氧气交替吹扫式臭氧分离变压吸附系统及其方法

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GB976644A (en) * 1961-11-22 1964-12-02 Gewerk Eisenhuette Westfalia Advancing mine roof support systems
US3393156A (en) * 1965-09-20 1968-07-16 Union Oil Co Pelleted zeolite compositions
JPS5547202A (en) * 1978-09-29 1980-04-03 Osaka Oxgen Ind Ltd Treating method for ozone contained in gas
US4778946A (en) * 1982-09-28 1988-10-18 Exxon Research And Engineering Company Process for separating ethylbenzene from feedstream containing metaxylene using a zeolite adsorbent
FR2580271B1 (fr) * 1985-04-16 1994-07-08 Air Liquide Procede de production d'ozone
JPS61271095A (ja) * 1985-05-27 1986-12-01 Mitsui Constr Co Ltd 有機性物質を含む廃水の資源化処理方法
US4775396A (en) * 1987-11-05 1988-10-04 Union Carbide Corporation Selective adsorption of CO2 on zeolites
JPH01149505A (ja) * 1987-12-07 1989-06-12 Hitachi Ltd 平面形クロスバーミクサ
JPH0316638A (ja) * 1989-06-14 1991-01-24 Mitsubishi Heavy Ind Ltd オゾン吸着済及びオゾン吸蔵装置
AT392256B (de) * 1989-06-26 1991-02-25 Voest Alpine Ind Anlagen Verfahren zur herstellung von sauerstoff und/oder ozon
JP3038353B2 (ja) * 1990-12-21 2000-05-08 石川島播磨重工業株式会社 オゾンの保存方法
JPH05241192A (ja) * 1992-02-27 1993-09-21 Sanyo Electric Co Ltd 液晶表示装置
GB9207298D0 (en) * 1992-03-31 1992-05-13 Boc Group Plc Treating materials with ozone
JPH05321850A (ja) * 1992-05-15 1993-12-07 Toyota Autom Loom Works Ltd スクロール型圧縮機
CA2132902A1 (en) * 1993-09-27 1995-03-28 Kazuhide Terada Highly active zsm-5 zeolite and process for producing the same
US5417742A (en) * 1993-12-03 1995-05-23 The Boc Group, Inc. Removal of perfluorocarbons from gas streams
US5425242A (en) * 1994-04-14 1995-06-20 Uop Process for recovery and purification of refrigerants with solid sorbents
US5417950A (en) * 1994-07-07 1995-05-23 The Boc Group, Inc. Process for the purification of nitric oxide
JP3016638U (ja) 1995-04-05 1995-10-09 繁子 望月 室内装飾用置物
US5616170A (en) * 1995-08-11 1997-04-01 The Boc Group, Inc. Adsorptive separation of nitrogen from other gases
US5810910A (en) * 1995-10-06 1998-09-22 Air Products And Chemicals, Inc. Adsorbents for ozone recovery from gas mixtures

Also Published As

Publication number Publication date
DE69801544T2 (de) 2002-06-06
EP0876994A1 (en) 1998-11-11
EP0876994B1 (en) 2001-09-05
CA2236611A1 (en) 1998-11-09
US5846298A (en) 1998-12-08
BR9801576A (pt) 1999-08-03
DE69801544D1 (de) 2001-10-11
CA2236611C (en) 2001-08-14

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