ES2167305T3 - Copolimeros de para-alquilestireno/isoolefina. - Google Patents

Copolimeros de para-alquilestireno/isoolefina.

Info

Publication number
ES2167305T3
ES2167305T3 ES89305395T ES89305395T ES2167305T3 ES 2167305 T3 ES2167305 T3 ES 2167305T3 ES 89305395 T ES89305395 T ES 89305395T ES 89305395 T ES89305395 T ES 89305395T ES 2167305 T3 ES2167305 T3 ES 2167305T3
Authority
ES
Spain
Prior art keywords
copolymers
copolimeros
produce
isoolefina
alquilestireno
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89305395T
Other languages
English (en)
Inventor
William Kenneth Powers
Hsien-Chang Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of ES2167305T3 publication Critical patent/ES2167305T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C08L23/283—Iso-olefin halogenated homopolymers or copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C08F8/22—Halogenation by reaction with free halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

COPOLIMEROS QUE SON EL PRODUCTO DE REACCION DE ISOOLEFINA CON 4 A 7 C Y PARA - ALQUILESTIRENO Y QUE TIENEN DESTILACION COMPOSIOCIONAL SUSTANCIALMENTE HOMOGENEA. ESTOS COPOLIMEROS SON PREFERIBLEMENTE COPOLIMEROS DE ISOBUTILENO Y PARA - METILESTIRENO, PREFERIBLEMENTE AL MENOS UN 95% EN PESO DEL COPOLIMERO TIENE UN CONTENIDO PARA -ALQUILESTIRENO DEL 10% EN PESO DEL CONTENIDO MEDIO DE PARA -ALQUILESTIRENO PARA LA COMPOSICION, E INCLUSO MAS PREFERIBLEMENTE EL INDICE REFRACTARIO DIFERENCIAL NORMALIZADO Y LAS CURVAS UV OBTENIDAS POR CROMATOGRAFIA DE FORMACION A TRAVES DE GEL PARA ESTOS COPOLIMEROS TAMBIEN PUEDEN SER HALOGENADOS Y EN UN ASPECTO PREFERIDO DE LA INVENCION SE PRESENTAN POLIMEROS SELECTIVAMENTE BROMADOS, CON CASI EXCLUSIVA SUSTITUCION, SOBRE EL GRUPO PARA - ALQUILO, ASI COMO PARA PRODUCIR UNA FUNCIONALIDAD DE HALOGENO BENCILICA. METODOS PARA PRODUCIR ESTOS COPOLIMEROS Y COPOLIMEROS HALOGENADOS.
ES89305395T 1988-05-27 1989-05-26 Copolimeros de para-alquilestireno/isoolefina. Expired - Lifetime ES2167305T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US19966588A 1988-05-27 1988-05-27

Publications (1)

Publication Number Publication Date
ES2167305T3 true ES2167305T3 (es) 2002-05-16

Family

ID=22738503

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89305395T Expired - Lifetime ES2167305T3 (es) 1988-05-27 1989-05-26 Copolimeros de para-alquilestireno/isoolefina.

Country Status (8)

Country Link
EP (1) EP0344021B1 (es)
JP (1) JP2796993B2 (es)
KR (1) KR0147373B1 (es)
AU (1) AU612845B2 (es)
BR (1) BR8902417A (es)
CA (1) CA1338546C (es)
DE (1) DE68929339T2 (es)
ES (1) ES2167305T3 (es)

Families Citing this family (63)

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US6013727A (en) * 1988-05-27 2000-01-11 Exxon Chemical Patents, Inc. Thermoplastic blend containing engineering resin
US5013793A (en) * 1990-07-26 1991-05-07 Exxon Chemical Patents Inc. Dynamically cured thermoplastic olefin polymers and process for producing the same
BR8907906A (pt) * 1989-10-03 1992-07-21 Exxon Chemical Patents Inc Copolimero de enxerto,processo para a compatibilizacao de uma mistura de polimeros,e mistura de polimeros
ATE143981T1 (de) * 1989-10-03 1996-10-15 Exxon Chemical Patents Inc Durch nukleophile substitution hergestellte funktionalisierte copolymere von para-alkylstyrol und isoolefinen
US5187013A (en) * 1989-12-13 1993-02-16 Lisco, Inc. Golf ball compositions
US5338610A (en) * 1989-12-13 1994-08-16 Lisco, Inc. Golf ball compositions
US5780540A (en) * 1990-01-16 1998-07-14 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5633415A (en) * 1990-01-16 1997-05-27 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5637783A (en) * 1990-01-16 1997-06-10 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5244996A (en) * 1990-04-18 1993-09-14 Mitsui Petrochemical Industries, Ltd. Hot-melt adhesive
US5246778A (en) * 1990-05-14 1993-09-21 Exxon Chemical Patents Inc. Hose composition
EP0530250B1 (en) * 1990-05-14 1995-07-19 Exxon Chemical Patents Inc. Hose composition
US5063268A (en) * 1990-06-08 1991-11-05 Exxon Chemical Patents Inc. Composition for tire treads (E-235)
WO1991019761A1 (en) * 1990-06-15 1991-12-26 Exxon Chemical Patents Inc. Composition for dynamic means
USH1475H (en) * 1990-07-02 1995-08-01 Newman Neil F Process for halogenating para-alkyl styrene/isoolefin copolymers
CA2086837C (en) * 1990-07-18 1997-11-25 Bernard Jean Costemalle Tire innerliner composition
US5333662A (en) * 1990-07-18 1994-08-02 Exxon Chemical Patents Inc. Tire innerliner composition
US5532312A (en) * 1990-08-15 1996-07-02 Exxon Chemical Patents, Inc. Tire sidewall composition
EP0543940B1 (en) * 1990-08-15 1996-12-27 Exxon Chemical Patents Inc. Tire sidewall composition
JPH06504078A (ja) * 1990-12-20 1994-05-12 エクソン・ケミカル・パテンツ・インク コーティング用途向けｕｖ／ｅｂ硬化性ブチルコポリマー
JPH06504628A (ja) * 1990-12-20 1994-05-26 エクソン・ケミカル・パテンツ・インク リソグラフィー及び腐食防止コーティング用途向けのｕｖ／ｅｂ硬化性ブチルコポリマー
US5227426A (en) * 1990-12-27 1993-07-13 Exxon Chemical Patents Inc. Adhesives based on elastomeric copolymers having theromplastic polymer grafts
US5206303A (en) * 1990-12-27 1993-04-27 Exxon Chemical Patents Inc. Entanglement-inhibited macromolecules
BR9205806A (pt) * 1991-03-21 1994-09-27 Exxon Chemical Patents Inc Composiçao para elementos de cura em molde.
CA2106490C (en) * 1991-03-25 1996-03-19 Donald Andrew White Grafted polymers of an isomonoolefin and an alkylstyrene
JPH06506972A (ja) * 1991-04-30 1994-08-04 エクソン・ケミカル・パテンツ・インク イソオレフィンとアルキルスチレンのスルホン化共重合体
JP2530764B2 (ja) * 1991-05-10 1996-09-04 横浜ゴム株式会社 エア―コンデョショナ―の冷媒輸送用ホ―ス
US5238990A (en) * 1991-06-05 1993-08-24 Exxon Chemical Patents Inc. High modulus toughened polyamide composition
US5244961A (en) * 1991-09-19 1993-09-14 Exxon Chemical Patents Inc. Thermoplastic compositions and process for preparing the same
US5281368A (en) * 1992-03-31 1994-01-25 Exxon Chemical Patents Inc. Norbornene polymerization initiators and process for preparing same
US6303691B1 (en) 1992-07-31 2001-10-16 Exxon Mobil Chemical Patents Inc. Impact modification of polyamides
US5728311A (en) * 1994-09-28 1998-03-17 The Goodyear Tire & Rubber Company Tire cure bladders containing polytetrafluoroethylene powder and use thereof
US5538218A (en) * 1994-09-28 1996-07-23 The Goodyear Tire & Rubber Company Tire curing bladder with improved release from the tire innerliner
US6013218A (en) * 1994-09-28 2000-01-11 The Goodyear Tire & Rubber Company Tire cure bladders cured with brominated phenolic resigns and containing PTFE and/or graphite
CA2138590C (en) 1994-09-30 2005-05-10 George Philemon Patitsas Tire cure bladders containing polytetrafluoroethylene powder and use thereof
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JP2000026542A (ja) 1998-07-07 2000-01-25 Yokohama Rubber Co Ltd:The 硫黄加硫可能なブチルゴムおよびそれを含むゴム組成物
CA2282900C (en) * 1999-09-20 2011-02-01 Bayer Inc. Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer
DE60332866D1 (de) * 2002-12-20 2010-07-15 Exxonmobil Chem Patents Inc Polymere mit neuen sequenzverteilungen
JP5166882B2 (ja) * 2004-12-29 2013-03-21 エクソンモービル・ケミカル・パテンツ・インク 選択エラストマーブレンドおよびそれらの製品における利用
US8158721B2 (en) 2008-06-13 2012-04-17 Exxonmobil Chemical Patents Inc. Process for preparing dynamically vulcanized alloys
US9079990B2 (en) * 2010-06-01 2015-07-14 Exxonmobil Chemical Patents Inc. Methods of production of alkylstyrene/isoolefin polymers
EP2935409B1 (en) 2012-12-20 2023-12-20 ExxonMobil Chemical Patents Inc. Process for preparing dynamically vulcanized alloys
US10894443B2 (en) 2014-12-19 2021-01-19 Exxonmobil Chemical Patents Inc. Expansible barrier film assemblies
JP6827919B2 (ja) 2015-05-26 2021-02-10 株式会社カネカ 熱可塑性エラストマーの製造方法及び熱可塑性エラストマー
US20180057674A1 (en) 2015-05-29 2018-03-01 ExxonMobil Chemical Company - Law Technology Dynamically Vulcanized Alloys
WO2017002625A1 (ja) * 2015-07-01 2017-01-05 株式会社カネカ ハロゲン化イソオレフィン系重合体の製造方法
CN105859925B (zh) * 2016-05-30 2018-05-01 广西锦华新材料科技有限公司 氯化聚乙烯生产系统
WO2018164776A1 (en) 2017-03-10 2018-09-13 Exxonmobil Chemical Patents Inc. Graft polymers for dispersing graphene and graphite
CN110573537B (zh) 2017-03-10 2022-05-03 埃克森美孚化学专利公司 用于分散石墨烯和石墨的接枝聚合物
JP2020152739A (ja) * 2017-07-13 2020-09-24 株式会社カネカ 臭素化ポリイソブチレン系重合体および製造方法
US10752722B2 (en) 2017-07-24 2020-08-25 Exxonmobil Chemical Patents Inc. Compositions of isobutylene, styrene and styrene with graft-on pendant double bonds
CA3122592A1 (en) * 2018-12-21 2020-06-25 Arlanxeo Singapore Pte. Ltd. Halogen recovery in a wet process for halogenating unsaturated isoolefin copolymer
CN111434697B (zh) * 2019-01-14 2022-12-09 中国石油化工股份有限公司 共聚物溴化的方法
CN111434696B (zh) * 2019-01-14 2022-12-13 中国石油化工股份有限公司 将共聚物进行溴化方法
CN111434695B (zh) * 2019-01-14 2023-02-28 中国石油化工股份有限公司 一种改进的共聚物溴化的方法
CN111393556B (zh) * 2020-05-15 2023-04-07 山东京博中聚新材料有限公司 一种异单烯烃-烷基苯乙烯共聚物及其制备方法
KR20240115831A (ko) * 2021-12-13 2024-07-26 아란세오 싱가포르 프라이빗 리미티드 불포화 이소올레핀 공중합체를 할로겐화하는 공정에서의 산화제 및 상 전이 촉매를 이용한 할로겐 회수
CN114349890B (zh) * 2022-01-28 2024-03-08 长兴（广州）光电材料有限公司 一种超高交联树脂及其制备方法与应用
CN117820574B (zh) * 2022-09-27 2025-02-25 中国石油天然气股份有限公司 聚合物及其制备方法以及溴化支化丁基橡胶及其制备方法和应用

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Also Published As

Publication number Publication date
DE68929339D1 (de) 2001-12-13
DE68929339T2 (de) 2002-07-25
BR8902417A (pt) 1990-01-16
JP2796993B2 (ja) 1998-09-10
AU612845B2 (en) 1991-07-18
KR890017274A (ko) 1989-12-15
AU3521989A (en) 1989-11-30
JPH02150408A (ja) 1990-06-08
KR0147373B1 (ko) 1998-08-17
EP0344021A2 (en) 1989-11-29
EP0344021A3 (en) 1992-01-22
CA1338546C (en) 1996-08-20
EP0344021B1 (en) 2001-11-07

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