ES2167769T3 - Procedimiento para la insercion de un grupo difluorometilo substituido. - Google Patents

Procedimiento para la insercion de un grupo difluorometilo substituido.

Info

Publication number
ES2167769T3
ES2167769T3 ES97935657T ES97935657T ES2167769T3 ES 2167769 T3 ES2167769 T3 ES 2167769T3 ES 97935657 T ES97935657 T ES 97935657T ES 97935657 T ES97935657 T ES 97935657T ES 2167769 T3 ES2167769 T3 ES 2167769T3
Authority
ES
Spain
Prior art keywords
group
substituted
difluorometilo
procedure
compound bearing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97935657T
Other languages
English (en)
Inventor
Gerard Forat
Jean-Manuel Mas
Laurent Saint-Jalmes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9609754A external-priority patent/FR2751961B1/fr
Priority claimed from FR9609753A external-priority patent/FR2751959B1/fr
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Application granted granted Critical
Publication of ES2167769T3 publication Critical patent/ES2167769T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/126—Microwaves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/06—Formation or introduction of functional groups containing sulfur of mercapto or sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02—Sulfinic acids; Derivatives thereof
    • C07C313/04—Sulfinic acids; Esters thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Graft Or Block Polymers (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Saccharide Compounds (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Hybrid Cells (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCEDIMIENTO PARA INJERTAR UN GRUPO DIFLUOROMETILO SUSTITUIDO EN UN COMPUESTO QUE COMPRENDE AL MENOS UNA FUNCION ELECTROFILICA, QUE CONSISTE EN LAS SIGUIENTES ETAPAS: I) PONER DICHO COMPUESTO QUE INCLUYE AL MENOS UNA FUNCION ELECTROFILA EN PRESENCIA DE UN REACTIVO NUCLEOFILO QUE COMPRENDE: A) UN ACIDO FLUOROCARBOXILICO DE FORMULA EA CF SUB,2 - COOH DONDE EA REPRESENTA UN ATOMO O UN GRUPO ELECTROATRAYENTE, AL MENOS PARCIALMENTE SALIFICADO POR UN CATION ORGANICO O MINERAL Y B) UN SOLVENTE APROTICO POLAR Y II) EXPONER EL MEDIO DE REACCION A LA ACCION DE MICROONDAS. ESTE PROCEDIMIENTO PERMITE PARTICULARMENTE FORMAR ACIDOS SULFINICOS O SULFONICOS FLUORADOS.
ES97935657T 1996-08-01 1997-07-30 Procedimiento para la insercion de un grupo difluorometilo substituido. Expired - Lifetime ES2167769T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9609754A FR2751961B1 (fr) 1996-08-01 1996-08-01 Procede pour la synthese de derives organiques oxysulfures et fluores
FR9609753A FR2751959B1 (fr) 1996-08-01 1996-08-01 Procede pour greffer un groupement difluoromethyle substitue sur un compose comportant au moins une fonction electrophile

Publications (1)

Publication Number Publication Date
ES2167769T3 true ES2167769T3 (es) 2002-05-16

Family

ID=26232898

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97935657T Expired - Lifetime ES2167769T3 (es) 1996-08-01 1997-07-30 Procedimiento para la insercion de un grupo difluorometilo substituido.

Country Status (14)

Country Link
US (1) US6203670B1 (es)
EP (1) EP0915814B1 (es)
JP (1) JP2001507332A (es)
KR (1) KR20000029759A (es)
CN (1) CN1230940A (es)
AT (1) ATE208752T1 (es)
AU (1) AU728097B2 (es)
BR (1) BR9710796A (es)
CA (1) CA2262499A1 (es)
DE (1) DE69708297T2 (es)
ES (1) ES2167769T3 (es)
PL (1) PL331419A1 (es)
RU (1) RU2192414C2 (es)
WO (1) WO1998005609A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU774290B2 (en) * 1999-05-26 2004-06-24 Personal Chemistry I Uppsala Ab Preparation and use of ionic liquids in microwave-assisted chemical transformations
FR2900403B1 (fr) * 2006-04-26 2008-07-11 Rhodia Recherches & Tech Procede de preparation de derives organiques oxysulfures et fluores
EA016304B1 (ru) * 2006-11-10 2012-04-30 Басф Се Способ сульфинилирования производной пиразола
CA2667559A1 (en) * 2006-11-10 2008-05-15 Basf Se Process for the sulfinylation of a pyrazole derivative
JP5450078B2 (ja) * 2006-11-10 2014-03-26 ビーエーエスエフ ソシエタス・ヨーロピア ピラゾール誘導体のスルフィニル化の方法
FR2924115B1 (fr) * 2007-11-27 2010-02-26 Rhodia Operations Procede de preparation d'un acide trifluoromethanesulfinique
MX2011003455A (es) * 2008-10-02 2011-05-23 Merial Ltd Metodo para producir y purificar acido trifluorometanosulfinico.
FR3010407B1 (fr) 2013-09-12 2015-09-04 Rhodia Operations Procede de preparation de derives oxysulfures et fluores par sulfination
CN106699615A (zh) * 2016-12-28 2017-05-24 江苏托球农化股份有限公司 一种三氟甲基亚磺酰氯的生产工艺
CN117326989A (zh) * 2023-09-26 2024-01-02 衢州市九洲化工有限公司 一种利用微通道反应装置将含氟羧酸钾盐直接硫化制备含氟亚磺酸盐的工艺技术

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2564829B1 (fr) * 1984-05-23 1987-08-14 Rhone Poulenc Spec Chim Procede de preparation d'acides trifluoromethyles
FR2593808B1 (fr) * 1986-02-06 1988-07-29 Rhone Poulenc Chimie Procede de preparation d'acides perhalogenomethanesulfiniques et sulfoniques et de leurs sels
FR2660923B1 (fr) * 1990-04-13 1992-07-03 Rhone Poulenc Chimie Reactif et procede de perhalogenoalkylation pour nucleophile utilisant de l'anhydride sulfureux.
GB9418305D0 (en) * 1994-09-10 1994-11-02 Solvay Interox Ltd Process for the introduction of fluoro substituents
SK286140B6 (sk) * 1995-03-24 2008-04-07 Rhone-Poulenc Agrochimie Reakčné činidlo na použitie pri príprave derivátov organických zlúčenín s oxidovanou sírnou skupinou a fluorovaných a spôsob ich prípravy

Also Published As

Publication number Publication date
US6203670B1 (en) 2001-03-20
CN1230940A (zh) 1999-10-06
WO1998005609A1 (fr) 1998-02-12
PL331419A1 (en) 1999-07-19
CA2262499A1 (fr) 1998-02-12
EP0915814A1 (fr) 1999-05-19
AU728097B2 (en) 2001-01-04
DE69708297T2 (de) 2002-08-22
ATE208752T1 (de) 2001-11-15
KR20000029759A (ko) 2000-05-25
RU2192414C2 (ru) 2002-11-10
JP2001507332A (ja) 2001-06-05
AU3855997A (en) 1998-02-25
DE69708297D1 (de) 2001-12-20
EP0915814B1 (fr) 2001-11-14
BR9710796A (pt) 2000-01-11

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