ES2170045T3 - Composiciones de organopolisiloxano curables. - Google Patents

Composiciones de organopolisiloxano curables.

Info

Publication number
ES2170045T3
ES2170045T3 ES00114997T ES00114997T ES2170045T3 ES 2170045 T3 ES2170045 T3 ES 2170045T3 ES 00114997 T ES00114997 T ES 00114997T ES 00114997 T ES00114997 T ES 00114997T ES 2170045 T3 ES2170045 T3 ES 2170045T3
Authority
ES
Spain
Prior art keywords
silyl
phenylethynyl
substituent
phenyl ring
siloxysilyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00114997T
Other languages
English (en)
Inventor
Armin Dr Fehn
Frank Dr Achenbach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wacker Chemie AG
Original Assignee
Wacker Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie AG filed Critical Wacker Chemie AG
Application granted granted Critical
Publication of ES2170045T3 publication Critical patent/ES2170045T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2286Alkynes, e.g. acetylides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086Platinum compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/56Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14Other (co) polymerisation, e.g. of lactides or epoxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/828Platinum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/12Polysiloxanes containing silicon bound to hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/20Polysiloxanes containing silicon bound to unsaturated aliphatic groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Silicon Polymers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

Composiciones de organopolisiloxano curables, que contienen (A) compuestos que contienen radicales con enlaces múltiples alifáticos carbono-carbono, (B) organopolisiloxanos con átomos de hidrógeno unidos a Si o, en lugar (A) y (B) (C) organopolisiloxanos, que contienen radicales unidos a SiC con enlaces múltiples alifáticos carbonocarbono y átomos de hidrógeno unidos a Si, y (D) un catalizador de platino, seleccionado del grupo constituido por compuestos de la fórmula **fórmula**(III), y/o compuestos oligómeros o polímeros, que se componen de unidades estructurales de la fórmula general **fórmula**(V) y opcionalmente unidades estructurales de la fórmula general R 9 rSiO(4-r)=2 (VI), donde R 2 significa un dieno opcionalmente sustituido, que está unido con platino por un enlace ¡ como mínimo y representa una cadena no ramificada o ramificada con 4 a 18 átomos de carbono o un anillo cíclico con6 a 28átomos de carbono, R 3 puede ser igual o diferente y significa átomo de hidrógeno, átomo de halógeno, -SiR 4 3 o, -OR 6 o radicales hidrocarburo monovalentes opcionalmente sustituidos que tienen 1 a 24 átomos de carbono, con la condición de que en los compuestos de la fórmula (III) como mínimo un radical R 3 tiene el significado de -SiR 4 3, R 4 puede ser igual o diferente y significa hidrógeno, átomo de halógeno, -OR 6 o radicales hidrocarburo monovalentes opcionalmente sustituidos que tienen 1 a 24 átomos de carbono, R 6 puede ser igual o diferente y es átomo de hidrógeno, -SiR 4 3 o un radical hidrocarburo monovalente opcionalmente sustituido que tiene 1 a 20 átomos de carbono, R 7 puede ser igual o diferente y significa átomo de hidrógeno, átomo de halógeno, -SiR 4 3, -SiR 4 (3-t) [R 8 SiR 9 sO(3-s)=2 ]t, -OR 6 o radicales hidrocarburo monovalentes opcionalmente sustituidos que tienen1 a 24 átomos de carbono, con la condición de que en la fórmula (V) como mínimo un radical R 7 tiene el signicado de -SiR 4 (3-t) [R 8 SiR 9 sO(3-s)=2 ]t, R 8 puede ser igual o diferente y signica oxígeno o radicales hidrocarburo bivalentes opcionalmente sustituidos que tienen 1 a 24 átomos de carbono, que pueden estar unidos al silicio a través de un átomo de oxígeno, R 9 puede ser igual o diferente y signica hidrógeno o un radical orgánico, res0, 1, 2ó 3, s signica 0, 1, 2 ó 3y t es1,2ó 3.
ES00114997T 1999-08-13 2000-07-21 Composiciones de organopolisiloxano curables. Expired - Lifetime ES2170045T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19938338A DE19938338A1 (de) 1999-08-13 1999-08-13 Härtbare Organopolysiloxanmassen

Publications (1)

Publication Number Publication Date
ES2170045T3 true ES2170045T3 (es) 2002-08-01

Family

ID=7918246

Family Applications (1)

Application Number Title Priority Date Filing Date
ES00114997T Expired - Lifetime ES2170045T3 (es) 1999-08-13 2000-07-21 Composiciones de organopolisiloxano curables.

Country Status (6)

Country Link
US (1) US6359098B1 (es)
EP (1) EP1077226B1 (es)
JP (1) JP3507778B2 (es)
AT (1) ATE212365T1 (es)
DE (2) DE19938338A1 (es)
ES (1) ES2170045T3 (es)

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* Cited by examiner, † Cited by third party
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DE10062181A1 (de) 2000-12-14 2002-07-04 Wacker Chemie Gmbh Härtbare Organopolysiloxanmassen
US7005460B2 (en) * 2001-01-25 2006-02-28 Kettenbach Gmbh & Co. Kg Two-step curable mixer-suitable materials
EP1353625B1 (de) * 2001-01-25 2009-03-04 Kettenbach GmbH & Co. KG Zweistufig härtbare mischergängige materialien
DE10121513A1 (de) 2001-05-03 2002-11-14 Wacker Chemie Gmbh Hochviskose alkenyl-terminierte Polydiorganosiloxane enthaltende additionsvernetzbare Siliconmassen
US6841647B2 (en) * 2001-11-06 2005-01-11 National Starch And Chemical Investment Holding Corporation Fluid resistant silicone encapsulant
DE10214137A1 (de) 2002-03-28 2003-10-16 Wacker Chemie Gmbh Siliconmassen mit verbesserter Hitzestabilität
DE10242798A1 (de) * 2002-09-14 2004-04-01 Degussa Ag Silikonkautschuk
EP1498457B1 (de) 2003-07-04 2005-08-10 Wacker-Chemie GmbH Lagerstabile Siliconmassen
US7211637B2 (en) * 2004-06-03 2007-05-01 Therm-O-Disc, Incorporated Sterically hindered reagents for use in single component siloxane cure systems
JP4647941B2 (ja) * 2004-06-23 2011-03-09 東レ・ダウコーニング株式会社 シリコーンレジンとシリコーンゴムの一体化成形体、その製造方法および硬化性シリコーンレジン組成物
DE102004050128A1 (de) * 2004-10-14 2006-04-20 Wacker Chemie Ag Siliconkautschuk Zusammensetzung mit verbesserter Haltbarkeit
DE102004050129A1 (de) * 2004-10-14 2006-04-20 Wacker Chemie Ag Siliconkautschuk Zusammensetzung enthaltend unbehandeltes Aluminiumhydroxid als Füllstoff
DE102005014018B4 (de) * 2004-10-21 2007-01-11 J. S. Staedtler Gmbh & Co. Kg Verwendung einer ofenhärtbaren Masse
DE102004060934A1 (de) 2004-12-17 2006-06-29 Wacker Chemie Ag Vernetzbare Polyorganosiloxanmassen
DE102005022106A1 (de) 2005-05-12 2006-11-16 Wacker Chemie Ag Hochviskose Polydiorganosiloxane enthaltende additionsvernetzbare Siliconmassen
US20070044788A1 (en) * 2005-08-26 2007-03-01 Wacker Chemical Corporation Method for mounting ceramic cooktops in appliance
DE102005045336A1 (de) * 2005-09-22 2007-03-29 Wacker Chemie Ag Siliconmassen mit hervorragender Viskositätsstabilität
US8012420B2 (en) * 2006-07-18 2011-09-06 Therm-O-Disc, Incorporated Robust low resistance vapor sensor materials
DE102007007569A1 (de) 2007-02-15 2008-08-21 Wacker Chemie Ag Additionsvernetzbare Siliconmassen mit geringen Reibungskoeffizienten
DE102007047212A1 (de) * 2007-10-02 2009-04-09 Wacker Chemie Ag Härtbare Siliconzusammensetzungen
US8691390B2 (en) * 2007-11-20 2014-04-08 Therm-O-Disc, Incorporated Single-use flammable vapor sensor films
DE102008041940A1 (de) * 2008-09-10 2010-03-11 Wacker Chemie Ag Siliconelastomere mit verbesserter Einreissfestigkeit
DE102009027847A1 (de) 2009-07-20 2011-01-27 Wacker Chemie Ag Härtbare Siliconzusammensetzungen
DE102010062139A1 (de) * 2010-11-29 2012-05-31 Wacker Chemie Ag Einkomponentige Organopolysiloxanmassen mit hoher relativer Permittivität
CN103619861A (zh) * 2011-06-29 2014-03-05 道康宁公司 硅氢加成反应可固化组合物及其制备和使用方法
DE102011088146A1 (de) 2011-12-09 2013-07-25 Wacker Chemie Ag Zu Elastomeren vernetzbare Siliconmasse mit einvernetzbaren Polyglykolethern
DE102012213260A1 (de) 2012-07-27 2014-01-30 Wacker Chemie Ag Additionsvernetzende Siliconzusammensetzung mit niedrigem Druckverformungsrest
CN103122243B (zh) * 2013-01-28 2015-01-28 宁波大学 一种铂化合物荧光材料及其制备方法
DE102014203613A1 (de) 2014-02-27 2015-08-27 Wacker Chemie Ag Additionsvernetzende Siliconzusammensetzung mit hohem Wasseraufnahmevermögen
DE102014222685A1 (de) 2014-11-06 2016-05-12 Wacker Chemie Ag Verfahren zur Herstellung von Siliconelastomerteilen
KR101969257B1 (ko) 2015-11-09 2019-04-15 와커 헤미 아게 탄도학적 방법에 의해 엘라스토머 성형품을 제조하기 위한 실리콘 조성물
WO2017089496A1 (de) 2015-11-26 2017-06-01 Wacker Chemie Ag Hochviskose siliconzusammensetzungen zur herstellung elastomerer formteile mittels ballistischer generativer verfahren
CN105797777B (zh) * 2016-03-31 2018-03-20 中科院广州化学有限公司南雄材料生产基地 一种二氧化硅固载含铂硅氢加成催化剂及制备方法与应用

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Also Published As

Publication number Publication date
ATE212365T1 (de) 2002-02-15
EP1077226A1 (de) 2001-02-21
DE50000101D1 (de) 2002-03-14
US6359098B1 (en) 2002-03-19
EP1077226B1 (de) 2002-01-23
JP2001064512A (ja) 2001-03-13
JP3507778B2 (ja) 2004-03-15
DE19938338A1 (de) 2001-02-22

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