ES2170375T3 - Terminacion de polimerizaciones en fase gaseosa de dienos conjugagos, compuestos aromaticos sustituidos con vinilo y sus mezclas. - Google Patents

Terminacion de polimerizaciones en fase gaseosa de dienos conjugagos, compuestos aromaticos sustituidos con vinilo y sus mezclas.

Info

Publication number
ES2170375T3
ES2170375T3 ES97911857T ES97911857T ES2170375T3 ES 2170375 T3 ES2170375 T3 ES 2170375T3 ES 97911857 T ES97911857 T ES 97911857T ES 97911857 T ES97911857 T ES 97911857T ES 2170375 T3 ES2170375 T3 ES 2170375T3
Authority
ES
Spain
Prior art keywords
termination
vinyl
mixtures
dienos
conjugagos
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97911857T
Other languages
English (en)
Inventor
Maria Angelica Apecetche
Kevin Joseph Cann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Application granted granted Critical
Publication of ES2170375T3 publication Critical patent/ES2170375T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

LA INVENCION PROPORCIONA UN PROCEDIMIENTO DE TERMINACION DE UNA POLMERIZACION EN FASE GASEOSA DE UN GRUPO FORMADO POR DIENO CONJUGADO, UN COMPUESTO AROMATICO SUSTITUIDO POR VINILO, Y MEZCLAS DE LOS MISMOS, EN UN RECIPIENTE DE POLIMERIZACION, EN PRESENCIA DE UN CATALIZADOR Y, OPCIONALMENTE EN PRESENCIA DE UN MATERIAL PARTICULADO INERTE. DICHO PROCEDIMIENTO CONSISTE EN INTRODUCIR UN AGENTE NEUTRALIZANTE SELECCIONADO A PARTIR DE UN GRUPO FORMADO POR UN ALCOHOL DE 1 A 20 ATOMOS DE CARBONO, UN ALQUIL O CICLOALQUIL MONOETER, AMONIACO, AGUA, UNA ALQUIL O ARILAMINA, Y MEZCLAS DE LOS MISMOS.
ES97911857T 1996-11-01 1997-10-21 Terminacion de polimerizaciones en fase gaseosa de dienos conjugagos, compuestos aromaticos sustituidos con vinilo y sus mezclas. Expired - Lifetime ES2170375T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/742,030 US5731381A (en) 1996-11-01 1996-11-01 Termination of gas phase polymerizations of conjugated dienes, vinyl-substituted aromatic compounds and mixtures thereof

Publications (1)

Publication Number Publication Date
ES2170375T3 true ES2170375T3 (es) 2002-08-01

Family

ID=24983218

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97911857T Expired - Lifetime ES2170375T3 (es) 1996-11-01 1997-10-21 Terminacion de polimerizaciones en fase gaseosa de dienos conjugagos, compuestos aromaticos sustituidos con vinilo y sus mezclas.

Country Status (9)

Country Link
US (1) US5731381A (es)
EP (1) EP0935615B1 (es)
JP (1) JP3238157B2 (es)
KR (1) KR100354201B1 (es)
BR (1) BR9712623A (es)
CA (1) CA2267567A1 (es)
DE (1) DE69711066T2 (es)
ES (1) ES2170375T3 (es)
WO (1) WO1998020049A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4067592B2 (ja) * 1996-12-04 2008-03-26 Ｊｓｒ株式会社 共役ジエン系重合体の製造方法
US6054563A (en) * 1997-03-05 2000-04-25 Rhodia Chimie Preparation of solid, powdery rare earth carboxylates by evaporation method
US6111082A (en) * 1998-04-17 2000-08-29 Rhodia Rare Earths Inc. Stable concentrated rare earth carboxylate liquids
US6090926A (en) * 1998-06-05 2000-07-18 Rhodia Rare Earths Inc. Powdery, solid rare earth carboxylates with improved solubility in aliphatic solvents which are highly active catalysts in Ziegler-Natta systems
US7005485B2 (en) * 1998-12-18 2006-02-28 Chevron Phillips Chemical Company Lp Process for producing polyolefins
US6967230B2 (en) * 1998-12-18 2005-11-22 Chevron Phillips Chemical Company Lp Process for producing polyolefins
EP1153934A1 (en) * 2000-05-09 2001-11-14 BP Chemicals S.N.C. Method for deactivating a polymerisation reaction
DE10022497A1 (de) * 2000-05-09 2001-11-15 Bayer Ag Copolymerisation konjugierter Diene mit nichtkonjugierten Olefinen mittels Katalysatoren der Seltenen Erden
FR2822469B1 (fr) * 2001-03-26 2004-07-30 Rhodia Elect & Catalysis Procede de preparation d'une solution stable de carboxylate de terre rare
DE10163154A1 (de) * 2001-12-20 2003-07-03 Basell Polyolefine Gmbh Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation
US6727330B1 (en) * 2003-02-07 2004-04-27 Firestone Polymers, Llc Termination and reduced gel in high cis polybutadiene
US6987152B1 (en) 2005-01-11 2006-01-17 Univation Technologies, Llc Feed purification at ambient temperature
CA2617436A1 (en) * 2005-08-02 2007-02-08 Ineos Europe Limited Diene polymerisation catalysts comprising two or more transition metals
US7446167B2 (en) * 2006-04-13 2008-11-04 Fina Technology, Inc. Catalyst deactivation agents and methods for use of same
TW200936564A (en) * 2007-11-15 2009-09-01 Univation Tech Llc Methods for the removal of impurities from polymerization feed streams
BRPI0921633B1 (pt) * 2008-10-31 2019-05-14 Chevron Phillips Chemical Company Lp Método para desativação e têmpera de um catalisador de oligomerização
CN102906128B (zh) * 2010-02-19 2014-11-26 宇部兴产株式会社 聚丁二烯及改质聚丁二烯、其等的制造方法、及使用其等的橡胶强化苯乙烯系树脂组成物
US11878952B1 (en) 2022-11-14 2024-01-23 Chevron Phillips Chemical Company Lp Oligomerization catalyst system deactivation and related ethylene oligomerization processes

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1235543A (en) * 1984-09-12 1988-04-19 Norio Kashiwa Process for producing propylene block copolymer
FR2646426B2 (fr) * 1988-09-13 1991-08-16 Bp Chemicals Sa Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite
FR2665704B1 (fr) * 1990-08-07 1994-04-08 Bp Chemicals Snc Procede pour arreter une reaction de (co-)polymerisation effectuee a l'aide d'un catalyseur a base d'oxyde de chrome.
US5336738A (en) * 1990-08-07 1994-08-09 Bp Chemicals Limited Kill-gas introduction to a fluidized bed reactor containing chromium oxide catalyst
GB9103527D0 (en) * 1991-02-20 1991-04-10 Exxon Chemical Patents Inc Hp catalyst killer
DE4130352A1 (de) * 1991-09-12 1993-03-18 Basf Ag Des- und reaktivierte metallocenkatalysatorsysteme
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process

Also Published As

Publication number Publication date
US5731381A (en) 1998-03-24
DE69711066T2 (de) 2002-08-14
KR100354201B1 (ko) 2002-09-28
KR20000052976A (ko) 2000-08-25
EP0935615B1 (en) 2002-03-13
DE69711066D1 (de) 2002-04-18
CA2267567A1 (en) 1998-05-14
JP2000509750A (ja) 2000-08-02
JP3238157B2 (ja) 2001-12-10
BR9712623A (pt) 1999-10-26
WO1998020049A1 (en) 1998-05-14
EP0935615A1 (en) 1999-08-18

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