ES2174444T3 - Procedimiento monoetapa para la obtencion de mono-eteres de glicol a partir de olefinas. - Google Patents
Procedimiento monoetapa para la obtencion de mono-eteres de glicol a partir de olefinas.Info
- Publication number
- ES2174444T3 ES2174444T3 ES98928204T ES98928204T ES2174444T3 ES 2174444 T3 ES2174444 T3 ES 2174444T3 ES 98928204 T ES98928204 T ES 98928204T ES 98928204 T ES98928204 T ES 98928204T ES 2174444 T3 ES2174444 T3 ES 2174444T3
- Authority
- ES
- Spain
- Prior art keywords
- olefins
- monoetapa
- eteres
- procedure
- glycol mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006735 epoxidation reaction Methods 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/13—Saturated ethers containing hydroxy or O-metal groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/86—Borosilicates; Aluminoborosilicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un procedimiento para producir monoéteres de glicol a partir de olefinas, haciendo reaccionar dichas olefinas con un reactivo de epoxidación in presencia de un compuesto orgánico que contiene grupos hidroxilo en una mezcla de catalizadores de epoxidación y catalizadores de alcoxilación.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19717320A DE19717320A1 (de) | 1997-04-24 | 1997-04-24 | Einstufiges Verfahren zur Herstellung von Glykolmonoethern aus Olefinen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2174444T3 true ES2174444T3 (es) | 2002-11-01 |
Family
ID=7827623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98928204T Expired - Lifetime ES2174444T3 (es) | 1997-04-24 | 1998-04-17 | Procedimiento monoetapa para la obtencion de mono-eteres de glicol a partir de olefinas. |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US6239315B1 (es) |
| EP (1) | EP0977721B1 (es) |
| JP (1) | JP4059927B2 (es) |
| KR (1) | KR100549674B1 (es) |
| CN (1) | CN1140489C (es) |
| AU (1) | AU8013998A (es) |
| CA (1) | CA2286340A1 (es) |
| DE (2) | DE19717320A1 (es) |
| ES (1) | ES2174444T3 (es) |
| ID (1) | ID22629A (es) |
| MX (1) | MX211744B (es) |
| WO (1) | WO1998047845A1 (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19717320A1 (de) * | 1997-04-24 | 1998-10-29 | Basf Ag | Einstufiges Verfahren zur Herstellung von Glykolmonoethern aus Olefinen |
| EP1085003A1 (en) * | 1999-03-31 | 2001-03-21 | DAICEL CHEMICAL INDUSTRIES, Ltd. | High-purity 1,3-propanediol derivative solvent, process for producing the same, and use thereof |
| US6749668B2 (en) | 2001-06-18 | 2004-06-15 | Degussa Ag | Process for the recovery of combustible components of a gas stream |
| CN1310836C (zh) * | 2002-02-08 | 2007-04-18 | 住友化学工业株式会社 | 金属化中孔硅酸盐及用其进行氧化的方法 |
| US6720436B2 (en) | 2002-03-18 | 2004-04-13 | Degussa Ag | Process for the epoxidation of olefins |
| US7141683B2 (en) | 2002-05-02 | 2006-11-28 | Degussa Ag | Process for the epoxidation of olefins |
| US6838572B2 (en) | 2002-09-30 | 2005-01-04 | Degussa Ag | Process for the epoxidation of olefins |
| US7722847B2 (en) | 2002-09-30 | 2010-05-25 | Evonik Degussa Gmbh | Aqueous hydrogen peroxide solutions and method of making same |
| US20050277542A1 (en) * | 2004-06-14 | 2005-12-15 | Kaminsky Mark P | Catalyst regeneration process |
| US20060094893A1 (en) * | 2004-10-29 | 2006-05-04 | Darbha Srinivas | Process for preparing cyclic carbonates |
| JP4790359B2 (ja) * | 2005-09-30 | 2011-10-12 | 日本乳化剤株式会社 | 水素イオン形態のメタロシリケート触媒を用いるグリコールエーテルの製造法 |
| US20120149862A1 (en) * | 2009-08-20 | 2012-06-14 | Basf Se | Process for preparing polyester alcohols |
| CN103012077B (zh) * | 2011-09-28 | 2015-02-25 | 中国石油化工股份有限公司 | 一种催化环氧丙烷醇解制备丙二醇单甲醚的方法 |
| CN103012078B (zh) * | 2011-09-28 | 2015-07-01 | 中国石油化工股份有限公司 | 一种催化氧化丙烯制备丙二醇单甲醚的方法 |
| US11203013B2 (en) | 2017-01-20 | 2021-12-21 | California Institute Of Technology | Enantiomerically enriched, polycrystalline molecular sieves |
| CN109704921B (zh) * | 2019-02-01 | 2022-01-04 | 淄博诺奥化工有限公司 | 邻二元醇的经济绿色制备方法 |
| CN115806488A (zh) * | 2022-12-28 | 2023-03-17 | 南京工业大学 | 一种对环烷醇进行开环烯丙基化的方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE671198A (es) * | 1964-11-09 | 1966-04-21 | ||
| FR1574021A (es) | 1968-04-03 | 1969-07-11 | ||
| NL6906922A (es) * | 1968-05-14 | 1969-11-18 | ||
| IT1152299B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'espossidazione di composti olefinici |
| IT1152296B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per la sintesi di monometileteri dei glicoli |
| US4975401A (en) * | 1983-05-02 | 1990-12-04 | Mobil Oil Corporation | ZSM-5/ZSM-12 catalyst mixture for cracking alkylbenzenes |
| IT1207519B (it) * | 1985-12-19 | 1989-05-25 | Eniricerche Spa | Materiale sintetico cristallino poroso contenetne ossidi di silicio titanio e alluminio. |
| IT1213363B (it) * | 1986-10-22 | 1989-12-20 | Eniricerche Spa | Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e gallio. |
| US4752375A (en) * | 1986-09-03 | 1988-06-21 | Mobil Oil Corporation | Single riser fluidized catalytic cracking process utilizing a C3-4 paraffin-rich co-feed and mixed catalyst system |
| GB8820358D0 (en) * | 1988-08-26 | 1988-09-28 | Shell Int Research | Process for catalytic cracking of hydrocarbon feedstock |
| GB2252556A (en) * | 1991-02-08 | 1992-08-12 | Bp Chem Int Ltd | Alkoxy-alcohols from olefins |
| US5256828A (en) * | 1992-06-12 | 1993-10-26 | Texaco Chemical Company | Heterogeneous catalyst for alkoxylation of alcohols |
| DE4408772B4 (de) * | 1993-03-16 | 2006-09-07 | Mitsubishi Chemical Corp. | Verfahren zur Herstellung eines Polyoxyalkylenglykols und neues Metallaluminosilikat |
| JP3833250B2 (ja) * | 1994-11-22 | 2006-10-11 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 一体型混合粉末ペレット触媒およびそれを用いた蝋質供給原料の改質方法 |
| GB2309655A (en) * | 1996-02-03 | 1997-08-06 | Univ Delft Tech | Heterogeneous Catalysts |
| ES2167626T3 (es) * | 1996-02-22 | 2002-05-16 | Enichem Spa | Materiales compuestos a base de silice y zeolita en forma esferica y procedimiento para su preparacion. |
| DE19717320A1 (de) * | 1997-04-24 | 1998-10-29 | Basf Ag | Einstufiges Verfahren zur Herstellung von Glykolmonoethern aus Olefinen |
| US6008388A (en) * | 1998-04-16 | 1999-12-28 | Arco Chemical Technology, L.P. | Epoxidation process |
| KR100277203B1 (ko) * | 1998-06-15 | 2001-02-01 | 김충섭 | 수소와 산소에 의한 직접적 수산화 방향족 화합물의 제조방법 |
| US6307073B1 (en) * | 2000-07-25 | 2001-10-23 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
| US6441204B1 (en) * | 2001-10-19 | 2002-08-27 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
| US6403815B1 (en) * | 2001-11-29 | 2002-06-11 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
-
1997
- 1997-04-24 DE DE19717320A patent/DE19717320A1/de not_active Withdrawn
-
1998
- 1998-04-17 KR KR1019997009728A patent/KR100549674B1/ko not_active Expired - Fee Related
- 1998-04-17 ES ES98928204T patent/ES2174444T3/es not_active Expired - Lifetime
- 1998-04-17 EP EP98928204A patent/EP0977721B1/de not_active Expired - Lifetime
- 1998-04-17 CN CNB988043653A patent/CN1140489C/zh not_active Expired - Fee Related
- 1998-04-17 ID IDW991075A patent/ID22629A/id unknown
- 1998-04-17 CA CA002286340A patent/CA2286340A1/en not_active Abandoned
- 1998-04-17 JP JP54499598A patent/JP4059927B2/ja not_active Expired - Fee Related
- 1998-04-17 DE DE59803517T patent/DE59803517D1/de not_active Expired - Lifetime
- 1998-04-17 WO PCT/EP1998/002281 patent/WO1998047845A1/de not_active Ceased
- 1998-04-17 US US09/403,590 patent/US6239315B1/en not_active Expired - Fee Related
- 1998-04-17 AU AU80139/98A patent/AU8013998A/en not_active Abandoned
-
1999
- 1999-09-27 MX MX9908835A patent/MX211744B/es not_active IP Right Cessation
-
2001
- 2001-03-07 US US09/799,593 patent/US6740616B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0977721A1 (de) | 2000-02-09 |
| EP0977721B1 (de) | 2002-03-27 |
| MX211744B (en) | 2002-12-02 |
| JP4059927B2 (ja) | 2008-03-12 |
| AU8013998A (en) | 1998-11-13 |
| CN1140489C (zh) | 2004-03-03 |
| US6740616B2 (en) | 2004-05-25 |
| JP2002508746A (ja) | 2002-03-19 |
| CA2286340A1 (en) | 1998-10-29 |
| KR20010020164A (ko) | 2001-03-15 |
| MX9908835A (en) | 2000-01-31 |
| DE59803517D1 (de) | 2002-05-02 |
| ID22629A (id) | 1999-12-02 |
| WO1998047845A1 (de) | 1998-10-29 |
| US20010011148A1 (en) | 2001-08-02 |
| DE19717320A1 (de) | 1998-10-29 |
| KR100549674B1 (ko) | 2006-02-08 |
| CN1252784A (zh) | 2000-05-10 |
| US6239315B1 (en) | 2001-05-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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