ES2177038T3 - Composicion de caucho dienico reforzado con una carga blanca, que comprende como agente de acoplamiento (carga blanca/elastomero) un poliorganosiloxano multifuncionalizado. - Google Patents

Composicion de caucho dienico reforzado con una carga blanca, que comprende como agente de acoplamiento (carga blanca/elastomero) un poliorganosiloxano multifuncionalizado.

Info

Publication number
ES2177038T3
ES2177038T3 ES98939630T ES98939630T ES2177038T3 ES 2177038 T3 ES2177038 T3 ES 2177038T3 ES 98939630 T ES98939630 T ES 98939630T ES 98939630 T ES98939630 T ES 98939630T ES 2177038 T3 ES2177038 T3 ES 2177038T3
Authority
ES
Spain
Prior art keywords
white
multifunctionalized
white load
coupling agent
polyganosiloxane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98939630T
Other languages
English (en)
Inventor
Frederic Chiron
Claude Laforet
Jean-Luc Mangeret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
Compagnie Generale des Etablissements Michelin SCA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale des Etablissements Michelin SCA filed Critical Compagnie Generale des Etablissements Michelin SCA
Application granted granted Critical
Publication of ES2177038T3 publication Critical patent/ES2177038T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0008—Compositions of the inner liner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0025—Compositions of the sidewalls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/392—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/5403—Silicon-containing compounds containing no other elements than carbon or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La invención se refiere a una composición de caucho vulcanizable en azufre y diseñada para la fabricación de bandas de rodadura, que comprende al menos un elastómero de dieno, una carga blanca como agente reforzador y un agente de acoplamiento (carga blanca/elastómero) un poliorganosiloxano multifuncionalizado que comprende por molécula: alfa, al menos una primera unidad de siloxilo soportada en un átomo de silicio al menos un radical alcoxilo C1-C15 lineal o ramificado; y beta, al menos una segunda unidad de siloxilo soportándose en un átomo de silicio al menos un radical de fórmula general Z-SH, siendo Z un enlace divalente lineal o ramificado, que comprende preferiblemente de 2 a 30 átomos de carbono.
ES98939630T 1997-07-11 1998-07-10 Composicion de caucho dienico reforzado con una carga blanca, que comprende como agente de acoplamiento (carga blanca/elastomero) un poliorganosiloxano multifuncionalizado. Expired - Lifetime ES2177038T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9709047 1997-07-11
FR9801452 1998-02-04

Publications (1)

Publication Number Publication Date
ES2177038T3 true ES2177038T3 (es) 2002-12-01

Family

ID=26233680

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98939630T Expired - Lifetime ES2177038T3 (es) 1997-07-11 1998-07-10 Composicion de caucho dienico reforzado con una carga blanca, que comprende como agente de acoplamiento (carga blanca/elastomero) un poliorganosiloxano multifuncionalizado.

Country Status (12)

Country Link
US (1) US6313205B1 (es)
EP (1) EP0996676B1 (es)
JP (1) JP2001509530A (es)
KR (1) KR100511701B1 (es)
CN (1) CN1214069C (es)
AU (1) AU8807198A (es)
BR (1) BR9811001A (es)
CA (1) CA2296010A1 (es)
DE (1) DE69806008T2 (es)
ES (1) ES2177038T3 (es)
PL (1) PL338041A1 (es)
WO (1) WO1999002602A1 (es)

Families Citing this family (57)

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Publication number Priority date Publication date Assignee Title
DE19905820A1 (de) * 1998-10-27 2000-05-04 Degussa Schwefelfunktionelle Polyorganosilane
MXPA02012423A (es) * 2000-06-16 2003-06-06 Michelin Rech Tech Composicion de caucho para neumaticos que comprende un poliorganosiloxano multifuncional como agente de acoplamiento.
KR100820033B1 (ko) 2000-07-31 2008-04-08 소시에떼 드 테크놀로지 미쉐린 주행 트레드를 갖는 타이어
DE10044989A1 (de) * 2000-09-11 2002-03-21 Bayer Ag Flüssige schwefelhaltige Oligosiloxane und ihre Verwendung in Kautschukmischungen
DE60221184T2 (de) * 2001-05-15 2008-04-10 Sumitomo Rubber Industries Ltd., Kobe Kautschukzusammensetzung für Reifenlauffläche und Reifen mit derselben
JP4536375B2 (ja) 2001-06-28 2010-09-01 ソシエテ ド テクノロジー ミシュラン 極めて低い比表面積のシリカで強化されたタイヤトレッド
ATE465208T1 (de) 2001-06-28 2010-05-15 Michelin Soc Tech Reifenlauffläche verstärkt durch kieselsäure mit niedriger spezifischer oberfläche
JP3826081B2 (ja) * 2001-09-04 2006-09-27 横浜ゴム株式会社 空気入りタイヤ及びその製造方法
FR2849045B1 (fr) * 2002-12-19 2005-01-21 Rhodia Chimie Sa Oligomeres polyorganosiloxane portant des fonctions thiols ou episulfures et leurs procedes de preparation
WO2004056918A1 (fr) * 2002-12-19 2004-07-08 Societe De Technologie Michelin Composition de caoutchouc pour pneumatique comportant un oligomere polyorganosiloxane a titre d’agent de couplage
JP4243962B2 (ja) * 2003-02-27 2009-03-25 横浜ゴム株式会社 空気入りタイヤ及びその製造方法
CA2446474C (en) * 2003-10-24 2011-11-29 Rui Resendes Silica-filled elastomeric compounds
MY164448A (en) * 2003-12-15 2017-12-15 Ciba Holding Inc Coupling agents between filler and elastomer
EP2277939B1 (en) * 2005-03-24 2017-02-22 Bridgestone Corporation Compounding silica-reinforced rubber with low volatile organic compound (VOC) emission
FR2886303B1 (fr) * 2005-05-26 2007-07-20 Rhodia Chimie Sa Utilisation d'une combinaison particuliere d'un agent de couplage et d'un agent de recouvrement, comme systeme de couplage(charge blanche-elastomere) dans les compositions de caoutchouc comprenant une charge inorganique
EP1928888A1 (en) * 2005-09-21 2008-06-11 Ciba Holding Inc. Filled rubber compounds with improved processability
US8501895B2 (en) 2007-05-23 2013-08-06 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes
US7915368B2 (en) 2007-05-23 2011-03-29 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes
US8962746B2 (en) 2007-12-27 2015-02-24 Bridgestone Corporation Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds
US8794282B2 (en) 2007-12-31 2014-08-05 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
US8097674B2 (en) 2007-12-31 2012-01-17 Bridgestone Corporation Amino alkoxy-modified silsesquioxanes in silica-filled rubber with low volatile organic chemical evolution
DE102008001007A1 (de) * 2008-04-04 2009-10-08 Robert Bosch Gmbh Silikon-Polymer modifizierte Gummi-Zusammensetzungen, Verfahren zu ihrer Herstellung sowie dieses Material umfassende Scheibenwischer
CN101260190B (zh) * 2008-04-28 2011-04-27 华南理工大学 多官能度聚硅氧烷偶联剂及其制备方法
FR2940290B1 (fr) 2008-12-22 2010-12-31 Michelin Soc Tech Agent de couplage mercaptosilane bloque
FR2947552B1 (fr) 2009-05-20 2011-08-26 Michelin Soc Tech Agent de couplage organosilane
FR2945815B1 (fr) 2009-05-20 2011-07-01 Michelin Soc Tech Composition de caoutchouc comportant un agent de couplage organosilane
FR2954774B1 (fr) 2009-10-30 2012-01-06 Michelin Soc Tech Methode de preparation d'un melange maitre de caoutchouc naturel et de silice
FR2954775B1 (fr) 2009-10-30 2012-03-30 Michelin Soc Tech Methode de preparation d'un melange maitre d'elastomere dienique synthetique et de silice
FR2952064B1 (fr) 2009-10-30 2012-08-31 Michelin Soc Tech Methode de preparation d'un melange maitre d'elastomere dienique et de silice
US8642691B2 (en) 2009-12-28 2014-02-04 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
FR2962440B1 (fr) * 2010-07-12 2012-08-03 Total Raffinage Marketing Procede de preparation de polymeres greffes sans amorceur et sans solvant et compositions bitume/polymere comprenant lesdits polymeres greffes
FR2974093B1 (fr) 2011-04-15 2015-05-08 Michelin Soc Tech Procede de preparation d'un melange maitre d'elastomere et d'une charge inorganique renforcante
FR2981076B1 (fr) 2011-10-11 2013-11-01 Michelin Soc Tech Methode pour preparer un melange maitre d'elastomere dienique et de silice
FR2981079B1 (fr) 2011-10-11 2013-11-01 Michelin Soc Tech Methode pour preparer un melange maitre d'elastomere dienique et de silice
FR2981081B1 (fr) 2011-10-11 2013-11-01 Michelin Soc Tech Methode de preparation d'un melange maitre de caoutchouc naturel et de silice
FR2981077B1 (fr) 2011-10-11 2013-11-01 Michelin Soc Tech Methode pour preparer un melange maitre d'elastomere dienique et de silice
FR2981080B1 (fr) 2011-10-11 2013-11-01 Michelin Soc Tech Methode de preparation d'un melange maitre de caoutchouc naturel et de silice dopee magnesium
FR2981078B1 (fr) 2011-10-11 2013-11-01 Michelin Soc Tech Methode pour preparer un melange maitre d'elastomere dienique et de silice
FR2984326B1 (fr) 2011-12-16 2014-01-10 Michelin Soc Tech Agent de couplage mercaptosilane bloque
KR101625032B1 (ko) * 2013-02-25 2016-05-27 요코하마 고무 가부시키가이샤 타이어용 고무 조성물 및 이것을 이용하는 공기입 타이어
JP5907308B2 (ja) * 2013-02-25 2016-04-26 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びこれを用いる空気入りタイヤ
US9550850B2 (en) * 2013-02-25 2017-01-24 The Yokohama Rubber Co., Ltd. Rubber composition for tire tread, and pneumatic tire using same
US10150845B2 (en) 2013-12-27 2018-12-11 Bridgestone Corporation Vulcanizates and tire components prepared from compositions including mercapto-functional siloxanes
JP6247591B2 (ja) * 2014-05-08 2017-12-13 株式会社ブリヂストン ゴム組成物、インナーライナー、シーラントおよび空気入りタイヤ
CN107406689A (zh) 2014-12-31 2017-11-28 株式会社普利司通 用于将钢合金粘附到橡胶的氨基烷氧基改性倍半硅氧烷粘合剂
FR3038320A1 (fr) 2015-07-02 2017-01-06 Michelin & Cie Composition de caoutchouc comprenant une silice de tres haute surface specifique et une resine hydrocarbonee de faible temperature de transition vitreuse
EP3263359A1 (en) * 2016-06-28 2018-01-03 Sumitomo Rubber Industries, Ltd. Rubber composition for sealants
FR3053337B1 (fr) 2016-06-30 2018-07-06 Compagnie Generale Des Etablissements Michelin Polysulfure de monohydroxysilane
FR3053345B1 (fr) 2016-06-30 2018-07-06 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc comprenant un agent de couplage polysulfure de monohydroxysilane
JP6869333B2 (ja) 2016-09-02 2021-05-12 株式会社ブリヂストン ポリマーセメントのその場ヒドロシリル化により調製される複数のシラン官能基を有するシス−１，４−ポリジエンの製造
FR3060565A1 (fr) 2016-12-16 2018-06-22 Michelin & Cie Polysulfure d'alcoxysilane
FR3065960B1 (fr) 2017-05-05 2019-06-28 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc comprenant au moins une silice en tant que charge renforcante inorganique
FR3079841B1 (fr) 2018-04-06 2020-10-09 Michelin & Cie Pneumatique comportant une composition de caoutchouc comprenant un nouvel agent de couplage polysulfure porteur de groupes associatifs azotes
FR3079842B1 (fr) 2018-04-06 2020-10-09 Michelin & Cie Pneumatique comportant une composition de caoutchouc comprenant un nouvel agent de couplage polysulfure porteur de groupes associatifs azotes
FR3113906B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
FR3113905B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
CN116082641B (zh) * 2021-11-08 2024-07-09 中蓝晨光化工有限公司 一种t型对称结构的大分子烷氧基硅烷处理剂及其制备方法与应用

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Also Published As

Publication number Publication date
DE69806008D1 (de) 2002-07-18
JP2001509530A (ja) 2001-07-24
KR100511701B1 (ko) 2005-09-02
AU8807198A (en) 1999-02-08
CN1265126A (zh) 2000-08-30
PL338041A1 (en) 2000-09-25
KR20010021698A (ko) 2001-03-15
DE69806008T2 (de) 2002-11-28
EP0996676A1 (fr) 2000-05-03
WO1999002602A1 (fr) 1999-01-21
EP0996676B1 (fr) 2002-06-12
BR9811001A (pt) 2000-11-07
US6313205B1 (en) 2001-11-06
CN1214069C (zh) 2005-08-10
CA2296010A1 (fr) 1999-01-21

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