ES2178237T3 - Fotonitrosacion de ciclododecano en el cloroformo en medio quasi-anhidrido. - Google Patents
Fotonitrosacion de ciclododecano en el cloroformo en medio quasi-anhidrido.Info
- Publication number
- ES2178237T3 ES2178237T3 ES98935082T ES98935082T ES2178237T3 ES 2178237 T3 ES2178237 T3 ES 2178237T3 ES 98935082 T ES98935082 T ES 98935082T ES 98935082 T ES98935082 T ES 98935082T ES 2178237 T3 ES2178237 T3 ES 2178237T3
- Authority
- ES
- Spain
- Prior art keywords
- chloroform
- photonitrosation
- cyclododecan
- anhydride
- middle quasi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 title abstract 4
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- UWJLMHZSTOSAJG-UHFFFAOYSA-N cyclododecylidene(oxido)oxidanium Chemical compound [O-][O+]=C1CCCCCCCCCCC1 UWJLMHZSTOSAJG-UHFFFAOYSA-N 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/06—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by nitrosation of hydrocarbons or substituted hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Steroid Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
La invención se refiere a un procedimiento para la preparación de oximo de ciclododecanona que consta en la reacción fotoquímica de la ciclododecanona solubilizada en cloroformo, un agente de nitrosación y cloruro de hidrógeno en un medio cuasi-anhídrido, por ejemplo en condiciones tales que el contenido de agua del medio de reacción no exceda de 1000 ppm.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9708357 | 1997-07-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2178237T3 true ES2178237T3 (es) | 2002-12-16 |
Family
ID=9508753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98935082T Expired - Lifetime ES2178237T3 (es) | 1997-07-02 | 1998-07-02 | Fotonitrosacion de ciclododecano en el cloroformo en medio quasi-anhidrido. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6197999B1 (es) |
| EP (1) | EP0993438B1 (es) |
| JP (1) | JP4391013B2 (es) |
| KR (1) | KR100530730B1 (es) |
| CN (1) | CN1109671C (es) |
| AT (1) | ATE219049T1 (es) |
| CA (1) | CA2295956C (es) |
| DE (1) | DE69806005T2 (es) |
| ES (1) | ES2178237T3 (es) |
| WO (1) | WO1999001424A1 (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2784103B1 (fr) * | 1998-09-21 | 2000-12-08 | Atochem Elf Sa | Procede de preparation de lauryllactame par photonitrosation de cyclododecane et transposition de beckmann en presence d'acide methanesulfonique |
| JP5042434B2 (ja) * | 2002-03-07 | 2012-10-03 | 株式会社ダイセル | 亜硝酸エステル等を用いたオキシム化合物の製造法 |
| FR2931478B1 (fr) * | 2008-05-26 | 2012-08-03 | Arkema France | Prodece de preparation de lactames comprenant une etape de photonitrosation suivie d'une etape de transposition de beckmann |
| US9181177B2 (en) * | 2012-06-26 | 2015-11-10 | Toray Industries, Inc. | Method of producing cycloalkanone oxime |
| US9932296B2 (en) | 2012-06-27 | 2018-04-03 | Toray Industries, Inc. | Method of producing cycloalkanone oxime |
| EP3498759A1 (de) | 2017-12-13 | 2019-06-19 | Evonik Degussa GmbH | Verfahren zur herstellung von polymeren aus monomeren umfassend laurinlactam |
| EP3498758A1 (de) | 2017-12-13 | 2019-06-19 | Evonik Degussa GmbH | Verfahren zur herstellung von polymeren aus monomeren umfassend laurinlactam |
| CN108409646B (zh) * | 2018-01-19 | 2020-05-19 | 南京红太阳生物化学有限责任公司 | 一种烟酰胺的合成方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1026034A (en) * | 1963-07-03 | 1966-04-14 | Toyo Rayon Co Ltd | Photonitrosation of cycloalkanes |
| DE1251720B (de) * | 1964-04-20 | 1967-10-12 | Badische Anilin &. Soda-Fabrik Aktiengesellschaft, Ludwigshafen/Rhein | Veifahren und Vorrichtung zur kontinuierlichen Durchfuhrung photochemischer Reaktionen |
| FR1440775A (fr) * | 1965-04-21 | 1966-06-03 | Basf Ag | Procédé de photo-oximation continue des cyclanes |
| US3853729A (en) * | 1972-02-29 | 1974-12-10 | Aquitaine Petrole | New photochemical cycloalkane oximation process |
| FR2746390B1 (fr) * | 1996-03-25 | 1998-04-24 | Atochem Elf Sa | PROCEDE DE PREPARATION DE l'OXIME DE LA CYCLODODECANONE PAR PHOTONITROSATION DE CYCLODODECANE EN PRESENCE DE TRICHLORONITROSOMETHANE |
-
1998
- 1998-07-02 ES ES98935082T patent/ES2178237T3/es not_active Expired - Lifetime
- 1998-07-02 CA CA002295956A patent/CA2295956C/fr not_active Expired - Fee Related
- 1998-07-02 EP EP98935082A patent/EP0993438B1/fr not_active Expired - Lifetime
- 1998-07-02 DE DE69806005T patent/DE69806005T2/de not_active Expired - Lifetime
- 1998-07-02 KR KR10-1999-7012491A patent/KR100530730B1/ko not_active Expired - Fee Related
- 1998-07-02 US US09/446,975 patent/US6197999B1/en not_active Expired - Fee Related
- 1998-07-02 CN CN98808500A patent/CN1109671C/zh not_active Expired - Fee Related
- 1998-07-02 JP JP2000501138A patent/JP4391013B2/ja not_active Expired - Fee Related
- 1998-07-02 WO PCT/FR1998/001415 patent/WO1999001424A1/fr not_active Ceased
- 1998-07-02 AT AT98935082T patent/ATE219049T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US6197999B1 (en) | 2001-03-06 |
| KR100530730B1 (ko) | 2005-11-23 |
| EP0993438A1 (fr) | 2000-04-19 |
| CA2295956A1 (fr) | 1999-01-14 |
| CA2295956C (fr) | 2007-09-18 |
| CN1268113A (zh) | 2000-09-27 |
| DE69806005D1 (de) | 2002-07-18 |
| JP2001509472A (ja) | 2001-07-24 |
| KR20010014340A (ko) | 2001-02-26 |
| JP4391013B2 (ja) | 2009-12-24 |
| WO1999001424A1 (fr) | 1999-01-14 |
| DE69806005T2 (de) | 2003-02-13 |
| CN1109671C (zh) | 2003-05-28 |
| EP0993438B1 (fr) | 2002-06-12 |
| ATE219049T1 (de) | 2002-06-15 |
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