ES2179035T3 - Polimerizacion de monomeros que contienen insaturacion olefinica empleando iniciadores anionicos. - Google Patents

Polimerizacion de monomeros que contienen insaturacion olefinica empleando iniciadores anionicos.

Info

Publication number
ES2179035T3
ES2179035T3 ES91904601T ES91904601T ES2179035T3 ES 2179035 T3 ES2179035 T3 ES 2179035T3 ES 91904601 T ES91904601 T ES 91904601T ES 91904601 T ES91904601 T ES 91904601T ES 2179035 T3 ES2179035 T3 ES 2179035T3
Authority
ES
Spain
Prior art keywords
typically
polymer
polydiene
terminated
olefinica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91904601T
Other languages
English (en)
Inventor
Neil Shepherd
Malcolm John Stewart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinetiq Ltd
Original Assignee
Qinetiq Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinetiq Ltd filed Critical Qinetiq Ltd
Application granted granted Critical
Publication of ES2179035T3 publication Critical patent/ES2179035T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
  • Magnetic Heads (AREA)
  • Glass Compositions (AREA)
  • Control Of Motors That Do Not Use Commutators (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Polymerization Catalysts (AREA)

Abstract

PROCESO PARA POLIMERIZAR ANIONICAMENTE UN MONOMERO 1,3 DIENO CONJUGADO, CONSISTE EN CONTACTAR EL MONOMERO EN UN DISOLVENTE DE HIDROCARBONO INERTE CON UN INICIADOR DE ETER DE SILILO MONOFUNCIONAL DE FORMULA GENERAL R1R2R3SI R1 A R3 SON SELECCIONADOS INDEPENDIENTEMENTE DE GRUPOS SUSTITUYENTES ORGANICOS MONOVALENTES Y A ES UN GRUPO DE PUENTE DE HIDROCARBONO DE CADENA CORTA, PARA DAR UN POLIDIENO CON UN PESO MOLECULAR NORMAL DE 1.000-10.000, UN CONTENIDO ALTO NORMAL 1,4 DE 90% Y UNA POLIDISPENSIDAD NORMAL DE 1,15. LOS EXTREMOS REACTIVOS DE LAS CADENAS DEL POLIMERO VIVO PUEDEN TERMINARSE CON UN GRUPO REACTIVO COMO HIDROXILO TRATANDO EL POLIMERO CON OXIDO DE ETILENO. LA CONSIGUIENTE ELIMINACION DE LOS GRUPOS DE EXTREMO SILILO RELATIVAMENTE NO REACTIVOS DEL POLIMERO POR REACCION CON FLUORURO TETRA INADO EN HIDROXI EXTENSIBLE EN CADENA DIFUNCIONAL UTIL COMO UN PREPOLIMERO AGLOMERANTE DE CAUCHO.
ES91904601T 1990-02-08 1991-02-06 Polimerizacion de monomeros que contienen insaturacion olefinica empleando iniciadores anionicos. Expired - Lifetime ES2179035T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB909002804A GB9002804D0 (en) 1990-02-08 1990-02-08 Anionic polymerisation

Publications (1)

Publication Number Publication Date
ES2179035T3 true ES2179035T3 (es) 2003-01-16

Family

ID=10670616

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91904601T Expired - Lifetime ES2179035T3 (es) 1990-02-08 1991-02-06 Polimerizacion de monomeros que contienen insaturacion olefinica empleando iniciadores anionicos.

Country Status (10)

Country Link
US (2) US5331058B1 (es)
EP (1) EP0513217B1 (es)
JP (1) JP3031566B2 (es)
AT (1) ATE224919T1 (es)
CA (1) CA2074722C (es)
DE (1) DE69133119T2 (es)
DK (1) DK0513217T3 (es)
ES (1) ES2179035T3 (es)
GB (4) GB9002804D0 (es)
WO (1) WO1991012277A1 (es)

Families Citing this family (117)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5665829A (en) * 1990-02-08 1997-09-09 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Gt. Britain & Northern Ireland Process for the polymerization of olefinic-containing monomers employing anionic initiators
JP3019171B2 (ja) 1991-10-01 2000-03-13 東亞合成株式会社 珪素原子に結合した加水分解性基を有する化合物からなるアニオン重合開始剤
US5393843A (en) * 1992-08-31 1995-02-28 Shell Oil Company Butadiene polymers having terminal functional groups
US5336726A (en) * 1993-03-11 1994-08-09 Shell Oil Company Butadiene polymers having terminal silyl groups
JPH0753630A (ja) * 1993-06-30 1995-02-28 Shell Internatl Res Maatschappij Bv 末端に水酸基を有する液状スターポリマー
US5391663A (en) * 1993-11-22 1995-02-21 Shell Oil Company Protected functional initiators for making terminally functionalized polymers
US5391637A (en) * 1993-11-23 1995-02-21 Shell Oil Company Capping of anionic polymers with oxetanes
US5376745A (en) * 1993-12-01 1994-12-27 Shell Oil Company Low viscosity terminally functionalized isoprene polymers
US5321148A (en) * 1993-12-30 1994-06-14 Fmc Corporation Process for preparing functionalized alkyllithium compounds
US6160054A (en) 1995-05-08 2000-12-12 Fmc Corporation Hetero-telechelic polymers and processes for making same
US5565526A (en) * 1994-05-13 1996-10-15 Fmc Corporation Functionalized initiators for anionic polymerization
JPH09505351A (ja) * 1994-02-18 1997-05-27 エフ エム シー コーポレーション アニオン重合用の新規な官能化開始剤
US5792815A (en) * 1995-05-08 1998-08-11 Fmc Corporation Functionalized polymer produced with functionalized initiators by anionic polymerization
US5416168A (en) * 1994-03-31 1995-05-16 Shell Oil Company Protected functional initiators for making terminally functionalized polymers
US5654371A (en) * 1994-05-13 1997-08-05 Fmc Corporation Anionic polymerization process using functionalized initiators
US5821307A (en) * 1994-05-13 1998-10-13 Fmc Corporation Functionalized chain extended initiators for anionic polymerization
US6197891B1 (en) 1994-05-13 2001-03-06 Fmc Corporation Functionalized chain extended initiators for anionic polymerization
US5708092A (en) * 1994-05-13 1998-01-13 Fmc Corporation Functionalized chain extended initiators for anionic polymerization
US5403946A (en) * 1994-07-25 1995-04-04 Fmc Corporation Process of preparing trimethylsilyloxy functionalized alkyllithium compounds
US5912378A (en) * 1994-07-25 1999-06-15 Fmc Corporation Process for preparing trimethylsilyloxy functionalized alkyllithium compounds
US5478899A (en) * 1994-10-27 1995-12-26 Shell Oil Company Alkoxy silyl capping agents for making terminally functionalized polymers
US5827929A (en) * 1994-10-31 1998-10-27 Fmc Corporation Functionalized initiators for anionic polymerization
US5461116A (en) * 1994-11-10 1995-10-24 Shell Oil Company Core functionalized star block copolymers
US5527753A (en) * 1994-12-13 1996-06-18 Fmc Corporation Functionalized amine initiators for anionic polymerization
US5486568A (en) * 1994-12-20 1996-01-23 Shell Oil Company Protected functional initiated polymers capped with low surface energy fluorocarbons
ZA963049B (en) * 1995-04-19 1996-07-29 Shell Int Research Coupling of anionic polymers with trialkoxysilanes having silicon-hydrogen bonds
US5523447A (en) * 1995-06-07 1996-06-04 Fmc Corporation Organolithium process
US5900464A (en) * 1995-07-25 1999-05-04 Fmc Corporation Processes for making methacrylate and acrylate polymers
US5798418A (en) * 1995-07-31 1998-08-25 Fmc Corporation Star polymers from mixed initiators
US5922810A (en) 1995-07-31 1999-07-13 Fmc Corporation Deprotection of protected functional polymers
US5919870A (en) * 1995-07-31 1999-07-06 Fmc Corporation Functional telechelic star polymers
AU6643096A (en) * 1995-08-03 1997-03-05 Fmc Corporation Functionalized polystyrene/polydiene copolymers and processes for making same
AU6643196A (en) * 1995-08-04 1997-03-05 Fmc Corporation Telechelic polystyrene/polyethylene copolymers and processes for making same
CN1048989C (zh) * 1995-10-17 2000-02-02 中国石油化工总公司 多官能团有机碱金属引发剂及其合成方法
US5780551A (en) * 1995-11-02 1998-07-14 Fmc Corporation Telechelic polymers from mixed initiator
AU7445996A (en) * 1995-12-22 1997-07-17 Fmc Corporation Functionalized chain extended initiators for anionic polymerization
US5663250A (en) * 1996-05-16 1997-09-02 Shell Oil Company Deprotection with molten salt
US5663398A (en) * 1996-05-17 1997-09-02 Fmc Corporation Processes for preparing functionalized alkyllithium compounds
US5965681A (en) * 1996-06-18 1999-10-12 Fmc Corporation Protected functionalized telechelic polymers and processes for making the same
AU3641897A (en) * 1996-07-17 1998-02-09 Conrad W Kamienski Protected functionalized heterotelechelic polymers and processes for preparing the same
FR2761995B1 (fr) * 1997-04-10 1999-05-28 Atochem Elf Sa Systeme d'amorcage comprenant un amorceur sylile pour la (co)polymerisation anionique de monomeres (meth)acryliques et procede l'utilisant
US6075097A (en) * 1997-06-06 2000-06-13 Shell Oil Company Process for producing conjugated diene diols using carbon dioxide
US6153706A (en) * 1997-07-30 2000-11-28 Fmc Corporation Protected multi-functionalized star polymers and processes for making the same
US6605564B1 (en) * 1997-11-14 2003-08-12 Fmc Corporation Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions
US6545103B2 (en) 1997-11-14 2003-04-08 Fmc Corporation Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions
TW442498B (en) * 1998-05-18 2001-06-23 Shell Internattonale Res Mij B Process for making anionic polymeric di-and polyfunctional polymers using protected functional initiators, and functionalised polymer producted thereby
US6090902A (en) * 1998-12-21 2000-07-18 Dow Corning Corporation Organopolysiloxane-modified graft copolymers
US6610859B1 (en) 1999-02-24 2003-08-26 Fmc Corporation Protected aminofunctionalized polymerization initiators and methods of making and using same
US6121474A (en) * 1999-02-24 2000-09-19 Fmc Corporation Amine anionic polymerization initiators and functionalized polymers derived therefrom
WO2000050478A1 (en) * 1999-02-25 2000-08-31 Fmc Corporation Novel formulations of alkyllithiums with improved thermal stability, processes to produce these formulations and processes for using the same to improve stability of living polymer chain ends
US6228947B1 (en) 1999-02-26 2001-05-08 Shell Oil Company Deprotection of polymers prepared with silyloxy protected functional initiators by reaction with aqueous fluoroboric acid
US6391981B1 (en) 1999-04-23 2002-05-21 Kraton Polymers Us Llc Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls
US6455651B1 (en) 1999-04-23 2002-09-24 Kraton Polymers U.S. Llc Uniform initiation of anionic polymerization using organo-substituted alkali metal initiators
US6225415B1 (en) 1999-09-20 2001-05-01 University Of North Carolina At Charlotte Process to selectively place functional groups within polymer chain
US20020198343A1 (en) * 2000-03-14 2002-12-26 Willis Carl Lesley Uniform initiation of anionic polymerization using organo-substituted alkali metal initiators
WO2002034800A1 (en) 2000-10-25 2002-05-02 Asahi Kasei Kabushiki Kaisha Hydrogenated polymer
US6943250B2 (en) 2001-03-06 2005-09-13 Fmc Corporation Protected aminofunctionalized polymerization initiators and methods of making and using same
ATE309276T1 (de) 2001-04-11 2005-11-15 Asahi Chemical Ind Hydriertes polymer und verfahren zu dessen herstellung
US7074855B2 (en) * 2001-05-01 2006-07-11 Kuraray Co., Ltd. Thermoplastic elastomer composition
US20030069366A1 (en) * 2001-09-17 2003-04-10 Letchford Robert J. Urethane oligomers of heterotelechelic amine functional polyolefins
WO2003035705A1 (en) * 2001-10-23 2003-05-01 Asahi Kasei Kabushiki Kaisha Hydrogenated copolymer
WO2003091339A1 (en) 2002-04-24 2003-11-06 Asahi Kasei Chemicals Corporation Asphalt composition
DE60321467D1 (de) * 2002-07-11 2008-07-17 Kraton Polymers Res Bv Gekoppelte styrolblockcopolymere und herstellungsverfahren dafür
WO2006088187A1 (ja) 2005-02-21 2006-08-24 Asahi Kasei Chemicals Corporation 水添ブロック共重合体及びその組成物
EP1856205A1 (en) 2005-03-01 2007-11-21 Firestone Polymers, LLC Oxygen scavenging polyesters with reduced recycle color
KR101097071B1 (ko) 2005-04-07 2011-12-22 아사히 가세이 케미칼즈 가부시키가이샤 블록 공중합체 수소첨가물, 또는 그 시트, 필름
EP1908795B1 (en) 2005-05-19 2011-08-10 Mitsui Chemicals, Inc. Resin composition for foam and use thereof
CN103642167B (zh) 2005-09-14 2018-04-13 旭化成株式会社 热收缩膜的制造方法
CN101268107B (zh) 2005-09-22 2012-10-10 旭化成化学株式会社 共轭二烯系聚合物及其制造方法
EP2045272B1 (en) 2006-07-24 2010-12-29 Asahi Kasei Chemicals Corporation Modified conjugated diene polymer and method for producing the same
EP2050773A4 (en) 2006-08-08 2009-07-22 Asahi Kasei Chemicals Corp HYDROGENIC BLOCK COPOLYMERS AND CROSSLINKING COMPOSITIONS CONTAINING SAME
CN100443514C (zh) * 2006-08-17 2008-12-17 山东大学 端双羟基聚合物及其制备方法
WO2008084512A1 (ja) 2006-12-26 2008-07-17 Asahi Kasei E-Materials Corporation 放熱材料及び放熱材料で成形した放熱シート
ATE534674T1 (de) 2007-03-28 2011-12-15 Asahi Kasei Chemicals Corp Verfahren zur herstellung eines modifizierten konjugierten dienpolymers, zusammensetzungen mit dem polymer und reifen mit diesen zusammensetzungen
KR20160110557A (ko) * 2007-12-28 2016-09-21 가부시키가이샤 브리지스톤 히드록시아릴 관능화 중합체
WO2009133930A1 (ja) 2008-04-30 2009-11-05 旭化成イーマテリアルズ株式会社 樹脂組成物及びそれを用いたシート
CN102119190B (zh) 2008-08-12 2012-11-07 旭化成化学株式会社 氢化嵌段共聚物组合物和使用该组合物的成型体
JP5705120B2 (ja) 2009-10-02 2015-04-22 旭化成ケミカルズ株式会社 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及び変性共役ジエン系重合体組成物
ES2797387T3 (es) 2009-12-31 2020-12-02 Bridgestone Corp Iniciadores de aminosilano y polímeros funcionalizados preparados a partir de los mismos
JP5584288B2 (ja) 2010-04-16 2014-09-03 旭化成ケミカルズ株式会社 変性共役ジエン系重合体の製造方法、及び変性共役ジエン系重合体組成物
EP2452981A1 (de) * 2010-11-16 2012-05-16 LANXESS Deutschland GmbH Trialkylsilyloxy-terminierte Polymere
CN107236061B (zh) 2010-12-30 2020-08-07 株式会社普利司通 氨基硅烷引发剂及由其制备的官能化聚合物
EA201490496A1 (ru) 2011-08-26 2014-08-29 Асахи Касеи Кемикалз Корпорейшн Способ получения модифицированных полимеров сопряженных диенов, модифицированные полимеры сопряженных диенов, композиции модифицированных полимеров сопряженных диенов, композиции каучука и автомобильные шины
EA201491052A1 (ru) 2011-11-28 2014-09-30 Асахи Касеи Кемикалз Корпорейшн Способ очистки 1,3-бутадиена
EP2662392A1 (de) 2012-05-09 2013-11-13 LANXESS Deutschland GmbH Allylaminhaltige, carbinolterminierte Polymere
EP2662406A1 (de) 2012-05-09 2013-11-13 LANXESS Deutschland GmbH Aminhaltige, carbinolterminierte Polymere
EP2796471A1 (de) 2013-04-24 2014-10-29 LANXESS Deutschland GmbH Silanhaltige carboxyterminierte Polymere
EP2796485A1 (de) 2013-04-24 2014-10-29 LANXESS Deutschland GmbH Cold Flow reduzierte Polymere mit gutem Verarbeitungsverhalten
EP3023439B1 (en) 2013-07-17 2018-02-07 Asahi Kasei Kabushiki Kaisha Method for producing polymer
SG11201600094YA (en) 2013-07-17 2016-02-26 Asahi Kasei Chemicals Corp Method for producing polymer
EP2865540A1 (de) 2013-10-24 2015-04-29 LANXESS Deutschland GmbH Kautschukzusammensetzung
EP3053934A1 (en) 2015-02-06 2016-08-10 LANXESS Deutschland GmbH Heteroatom containing modified diene polymers
WO2017036721A1 (en) 2015-08-28 2017-03-09 Arlanxeo Deutschland Gmbh Increased efficiency desulfurization reagents
EP3135712A1 (en) 2015-08-28 2017-03-01 ARLANXEO Deutschland GmbH Increased efficiency of desulfurization reagents
KR20190031505A (ko) 2016-07-20 2019-03-26 쓰리엠 이노베이티브 프로퍼티즈 컴파니 양자점을 위한 안정화 스티렌계 중합체
US11345849B2 (en) 2016-07-20 2022-05-31 3M Innovative Properties Company Stabilizing styrenic polymer for quantum dots
DK3575361T3 (da) 2017-01-24 2022-01-03 Asahi Chemical Ind Termoplastisk elastomersammensætning, prop og beholder
EP3366709A1 (en) 2017-02-24 2018-08-29 ARLANXEO Deutschland GmbH In-chain phosphine- and phosphonium- containing diene-polymers
JP2019043883A (ja) * 2017-09-01 2019-03-22 国立大学法人京都大学 アルキルリチウム、化合物の製造方法、ポリマー、及びポリマーの製造方法
US11566094B2 (en) 2017-10-13 2023-01-31 Zeon Corporation Modified conjugated diene rubber
JP7301745B2 (ja) 2017-10-13 2023-07-03 日本ゼオン株式会社 共役ジエン系ゴム
DE102019119630B4 (de) 2018-07-20 2024-02-29 Asahi Kasei Kabushiki Kaisha Thermoplastische Elastomerzusammensetzung, deren Verwendung, Stopfen und Behälter
SG11202107567QA (en) 2019-01-24 2021-08-30 Asahi Chemical Ind Block copolymer composition, molded product, method for producing molded product, and method for adjusting hazevalue of molded product
WO2020189559A1 (ja) 2019-03-20 2020-09-24 旭化成株式会社 水添ブロック共重合体
EP3974459B1 (en) 2019-05-23 2024-01-17 Asahi Kasei Kabushiki Kaisha Hydrogenated copolymer composition, adhesive film, resin composition, and molded article
CN112239511B (zh) 2019-07-16 2023-07-18 旭化成株式会社 氢化嵌段共聚物、氢化嵌段共聚物组合物以及成型体
US12371514B2 (en) 2019-07-16 2025-07-29 Arlanxeo Deutschland Gmbh 1-amino-3-(oxyalkylalkoxysilyl)-2-propanol-terminated diene rubbers
US20220251246A1 (en) 2019-07-16 2022-08-11 Arlanxeo Deutschland Gmbh Carboxyterminated diene rubbers
EP4134244A4 (en) 2020-04-07 2024-04-24 ZS Elastomers Co., Ltd. CONJUGATED DIENE-BASED POLYMER, CONJUGATED DIENE-BASED POLYMER COMPOSITION, CROSS-LINKED RUBBER ITEM AND TIRE
WO2021241291A1 (ja) 2020-05-27 2021-12-02 旭化成株式会社 樹脂組成物、変性水添ブロック共重合体の製造方法、及び成形体
CN115667397B (zh) 2020-05-29 2025-08-08 横滨橡胶株式会社 轮胎用橡胶组合物及轮胎
JP7004025B2 (ja) 2020-05-29 2022-01-21 横浜ゴム株式会社 タイヤ用ゴム組成物及びタイヤ
KR102769479B1 (ko) 2020-06-22 2025-02-19 아사히 가세이 가부시키가이샤 수소 첨가 공중합체, 수지 조성물, 성형체 및 점착성 필름
CN118475629A (zh) 2022-01-25 2024-08-09 旭化成株式会社 氢化嵌段共聚物、氢化嵌段共聚物组合物以及成型体
JP7836391B2 (ja) 2022-05-18 2026-03-26 旭化成株式会社 複層成形用の熱可塑エラストマー組成物、複層成形体、及び複層成形体の製造方法
KR20250124109A (ko) 2022-12-16 2025-08-19 니폰 제온 가부시키가이샤 공액 디엔계 중합체, 공액 디엔계 중합체 조성물, 고무 가교물 및 타이어
US20250034389A1 (en) 2023-07-25 2025-01-30 Asahi Kasei Kabushiki Kaisha Foam Body, Method for Producing Foam Body, and Laminate

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3324089A (en) * 1963-03-25 1967-06-06 Phillips Petroleum Co Silicon-containing compounds and a process of producing same
US3555066A (en) * 1968-12-13 1971-01-12 Dow Corning Organo-lithium derivatives of alpha-silylmethyl sulfides
DE2039017A1 (de) * 1969-08-13 1971-04-01 Inst Neftechimicheskogo Sintez Dilithiumorganische Katalysatoren zur Polymerisation von Dien- und Vinylmonomeren und Polymerisationsverfahren
US3929850A (en) * 1971-11-19 1975-12-30 Huels Chemische Werke Ag Process for the production of polymeric hydrocarbons having reactive silyl end groups
DE2615039A1 (de) * 1976-04-07 1977-10-20 Bayer Ag Silylaether und ein verfahren zur initiierung radikalisch auszuloesender polymerisationsreaktionen
DE2632294C2 (de) * 1976-07-17 1984-05-03 Bayer Ag, 5090 Leverkusen Silylether und ihre Verwendung als Polymerisationsinitiatoren
NL168232C (nl) * 1976-07-17 1982-03-16 Bayer Ag Werkwijze voor het bereiden van hardbare harsmengsels, werkwijze voor het bereiden van daarvoor als initiator geschikte silylethers, alsmede uit deze harsmengsels vervaardigde gevormde voortbrengselen.
ZA794221B (en) * 1978-09-05 1981-03-25 British Petroleum Co Process for the preparation of a functionalised solid product
US4351924A (en) * 1981-03-16 1982-09-28 E. I. Du Pont De Nemours And Company ω-, and α,ω-Hydroxyhydrocarbyl-(alkyl methacrylate) polymers and process
EP0189174B1 (en) * 1985-01-23 1990-04-25 Nissan Chemical Industries Ltd. Polymers of substituted 1,3-butadiene compounds and process for their preparation
JPS63218704A (ja) * 1987-03-06 1988-09-12 Nippon Paint Co Ltd テレキリツフポリマ−の製造方法
US4866145A (en) * 1988-04-01 1989-09-12 E. I. Du Pont De Nemours And Company Catalyst for group transfer polymerization
US5153291A (en) * 1988-06-28 1992-10-06 Bayer Aktiengesellschaft Trialkylsilyloxy-1,1-diphenyl ethylenes and polymers produced therewith
US5081191A (en) * 1989-01-18 1992-01-14 The Dow Chemical Company Functionalized polymers prepared by anionic polymerization

Also Published As

Publication number Publication date
EP0513217B1 (en) 2002-09-25
CA2074722A1 (en) 1991-08-09
GB2241239A (en) 1991-08-28
ATE224919T1 (de) 2002-10-15
GB2272221B (en) 1994-08-10
GB9002804D0 (en) 1990-04-04
EP0513217A1 (en) 1992-11-19
GB2255567B (en) 1994-08-03
DE69133119T2 (de) 2003-07-31
GB9215291D0 (en) 1992-09-16
DE69133119D1 (de) 2002-10-31
GB2255567A (en) 1992-11-11
DK0513217T3 (da) 2003-01-06
US5331058A (en) 1994-07-19
CA2074722C (en) 2001-04-17
JPH05504164A (ja) 1993-07-01
JP3031566B2 (ja) 2000-04-10
GB2272221A (en) 1994-05-11
GB9322691D0 (en) 1993-12-22
GB9102587D0 (en) 1991-03-27
WO1991012277A1 (en) 1991-08-22
US5362699A (en) 1994-11-08
US5331058B1 (en) 1999-12-14

Similar Documents

Publication Publication Date Title
US5331058B1 (en) Polymerization of olefinic-containing monomers employing anionic initiators
KR860700257A (ko) 아크릴 별모양 중합체
GB1597500A (en) Polymers
KR960706513A (ko) 저 점도의 말단 작용화된 이소프렌 중합체(low viscosity terminally functionalized isoprene polymers)
KR20000048291A (ko) 오가노폴리실록산-개질된 그라프트 공중합체
KR930006063A (ko) 연속 테이퍼 중합체 및 공중합체, 및 이들의 제조방법
US4169115A (en) Preparation of block copolymers and products therefrom
EP0563902A1 (en) Fluorosilicone block copolymers and method for the preparation thereof
KR910006339A (ko) 폴리실옥산 코어를 가진 혼성 아크릴스타 중합체의 제조 방법
GB1432783A (en) Macromolecular monomers
KR910020056A (ko) 성상 블록 중합체 및 이의 제조 방법
KR950032339A (ko) 비대칭 방사상 중합체 생성 방법
Okay et al. Conditions of microgel formation in homogeneous anionic polymerization of 1, 4‐divinylbenzene
GB2020670A (en) Liquid polymer and liquid copolymers of Butadiene and the preparation thereof.
CN102108114A (zh) 抗冲击透明的乙烯基芳烃和共轭二烯烃线性非对称嵌段共聚物及其制备方法
Long et al. Synthesis and characterization of well-defined star polymers via a controlled sol-gel process
JPS6466241A (en) Production of organopolysiloxane having alkenyl group in side chain at center of molecular chain
JPS54149788A (en) Preparation of solvent-resistant acrylic resin
ES443215A1 (es) Un procedimiento para la preparacion de un copolimero elas- tomero.
KR910020057A (ko) 투명 내충격성 스티렌 수지의 제조방법
Ananthalakshmi et al. Thermal behaviour of glycidyl methacrylate homopolymers and copolymers
CA1098637A (en) Preparation of block copolymers and products therefrom
Samal et al. Photoinduced graft copolymerization: X—Graft copolymerization of methyl methacrylate onto wool using isoquinoline-sulphur dioxide charge-transfer complex as the initiator
EP0262077A3 (en) Reactive end group polymers
Rempp Recent advances in macromolecular engineering via ionic methods