ES2179066T3 - Copolimero de etileno, composicion de resina termoplastica que lo contiene y procedimiento de produccion de este copolimero. - Google Patents

Copolimero de etileno, composicion de resina termoplastica que lo contiene y procedimiento de produccion de este copolimero.

Info

Publication number
ES2179066T3
ES2179066T3 ES94907077T ES94907077T ES2179066T3 ES 2179066 T3 ES2179066 T3 ES 2179066T3 ES 94907077 T ES94907077 T ES 94907077T ES 94907077 T ES94907077 T ES 94907077T ES 2179066 T3 ES2179066 T3 ES 2179066T3
Authority
ES
Spain
Prior art keywords
sub
relationship
copolymer
formula
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94907077T
Other languages
English (en)
Inventor
Shuji Machida
Haruo Shikuma
Ayami Hoshino
Yutaka Takakura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP21131593A external-priority patent/JP3444431B2/ja
Priority claimed from JP33440293A external-priority patent/JP3483215B2/ja
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Application granted granted Critical
Publication of ES2179066T3 publication Critical patent/ES2179066T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

SE PRESENTAN COPOLIMEROS DE ETILENO DERIVADOS DE ETILENO Y DE OLEFINAS C{SUB, 3-20} QUE NO CONTIENEN CARBONO CUATERNARIO EN LA CADENA PRINCIPAL Y QUE TIENEN UNA ENERGIA DE ACTIVACION (EA) DE FLUJO FUNDIDO DE ENTRE 8 Y 20 KCAL/MOL, Y EN DONDE (1) LA CONSTANTE DE HUGGINS (K{SUB, 1}) Y LA CONSTANTE DE HUGGINS (K{SUB, 2}) DEL POLIMERO DE ETILENO LINEAL, TIENEN AMBAS LAS MISMAS VISCOSIDADES, SATISFACIENDO LA RELACION DE LA FORMULA: 1.12<K{SUB, 1}/K{SUB, 2} >= 5, O (2) LA RELACION MOLAR DE LOS GRUPOS DE METIL CON RESPECTO A LOS GRUPOS DE METILENO EN LA CADENA MOLECULAR, [CH{SUB, 3}/CH{SUB, 2}], ESTA ENTRE 0.005 Y 0.1 Y SATISFACE LA RELACION DE LA FORMULA: TM <= 131 - 1340 [CH{SUB, 3}/CH{SUB, 2}], O (3) EL MW Y LA PROPORCION DE ENGROSAMIENTO (DR) SATISFACE LA RELACION DE LA FORMULA: DR > 0.5 + 0.125 X LOG MW. ESTOS COPOLIMEROS DE ETILENO SON DIFERENTES DE LOS HDPE, LLDPE Y LDPE ORDINARIOS, Y SE CARACTERIZAN EN QUE POSEEN UNA EXCELENTE PROCESABILIDAD Y SON CAPACES DE CONTROLAR DIFERENTES PROPIEDADES, TALES COMO LA DENSIDAD, EL PUNTO DE FUSION Y LA CRISTALINIDAD.
ES94907077T 1993-02-22 1994-02-21 Copolimero de etileno, composicion de resina termoplastica que lo contiene y procedimiento de produccion de este copolimero. Expired - Lifetime ES2179066T3 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP3202193 1993-02-22
JP5369593 1993-03-15
JP21131593A JP3444431B2 (ja) 1993-08-26 1993-08-26 エチレン系共重合体及びそれを含有する熱可塑性樹脂組成物
JP33440293A JP3483215B2 (ja) 1993-12-28 1993-12-28 エチレン系共重合体及びそれを含有する熱可塑性樹脂組成物

Publications (1)

Publication Number Publication Date
ES2179066T3 true ES2179066T3 (es) 2003-01-16

Family

ID=27459541

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94907077T Expired - Lifetime ES2179066T3 (es) 1993-02-22 1994-02-21 Copolimero de etileno, composicion de resina termoplastica que lo contiene y procedimiento de produccion de este copolimero.

Country Status (5)

Country Link
US (1) US5747620A (es)
EP (1) EP0690079B1 (es)
DE (1) DE69430910T2 (es)
ES (1) ES2179066T3 (es)
WO (1) WO1994019381A1 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
WO1994018250A1 (fr) * 1993-02-05 1994-08-18 Idemitsu Kosan Co., Ltd. Polyethylene, composition de resine thermoplastique le contenant, et procede de production de polyethylene
JP3102890B2 (ja) * 1994-10-24 2000-10-23 旭化成工業株式会社 ポリオキシメチレン樹脂組成物
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
DE69836415T3 (de) 1997-02-07 2014-03-27 Exxonmobil Chemical Patents Inc. Herstellung von vinyl enthaltenden polymeren
EP0958314B1 (en) * 1997-02-07 2002-11-06 ExxonMobil Chemical Patents Inc. Propylene polymers incorporating polyethylene macromers
DE19711452A1 (de) 1997-03-19 1998-09-24 Sca Hygiene Paper Gmbh Feuchtigkeitsregulatoren enthaltende Zusammensetzung für Tissueprodukte, Verfahren zur Herstellung dieser Produkte, Verwendung der Zusammensetzung für die Behandlung von Tissueprodukten sowie Tissueprodukte in Form von wetlaid einschließlich TAD oder Airlaid (non-woven) auf Basis überwiegend Cellulosefasern enthaltender flächiger Trägermaterialien
DE60022326T3 (de) * 1999-06-17 2012-03-22 Mitsui Chemicals, Inc. Ethylen(co)polymere und deren verwendung
EP1209173A4 (en) 1999-07-26 2003-04-16 Idemitsu Petrochemical Co BRANCHED OLEFINIC MACROMONOMERS, OLEFINIC GRAFT POLYMER AND POLYOLEFIN MIXTURE
CN1222402C (zh) * 1999-09-29 2005-10-12 纳幕尔杜邦公司 经改善加工性能的聚乙烯
US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6455638B2 (en) 2000-05-11 2002-09-24 Dupont Dow Elastomers L.L.C. Ethylene/α-olefin polymer blends comprising components with differing ethylene contents
DE60113701T2 (de) 2000-07-24 2006-03-16 Idemitsu Kosan Co. Ltd. Propylen homo-und copolymer
DE60120930T2 (de) 2000-07-26 2007-06-21 Mitsui Chemicals, Inc. Neues ethylencopolymer und dessen verwendungen
FR2814464B1 (fr) * 2000-09-22 2004-04-09 Centre Nat Rech Scient Utilisation d'especes hydrures de chrome supportees pour realiser la polymerisation d'olefines
MXPA03004946A (es) * 2000-12-06 2005-02-14 Omlidon Technologies Llc Polietileno resistente al desgaste, procesable en estado fundido.
DE60224512T2 (de) 2001-03-12 2008-05-21 Idemitsu Kosan Co. Ltd. Verfahren zur herstellung einer polyolefinharzzusammensetzung und einer polypropylenzusammensetzung
EP1408080B1 (en) * 2001-07-12 2012-12-26 Idemitsu Kosan Co., Ltd. Polyolefin resin composition
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
JP4903357B2 (ja) * 2003-03-28 2012-03-28 住友化学株式会社 エチレン重合体
DE102007025220A1 (de) * 2006-06-08 2008-01-10 Sumitomo Chemical Co. Ltd. Thermoplastische Elastomerzusammensetzung und Laminat
EP2070957B1 (en) * 2006-08-31 2013-10-02 Mitsui Chemicals, Inc. Polyolefin polymer containing vinyl groups at both ends and composition thereof
US7754834B2 (en) 2007-04-12 2010-07-13 Univation Technologies, Llc Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density

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US3432518A (en) * 1966-06-27 1969-03-11 Phillips Petroleum Co Polymer hydrogenation
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
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US5444134A (en) * 1991-07-11 1995-08-22 Idemitsu Kosan Co., Ltd. Process for producing olefin based polymers and olefin polymerization catalyst
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US5459217A (en) * 1993-04-09 1995-10-17 Mitsui Petrochemical Industries, Ltd. Ethylene/alpha-olefin copolymer
JPH05339315A (ja) * 1992-06-11 1993-12-21 Mitsui Petrochem Ind Ltd オレフィンの重合方法
JP3355534B2 (ja) * 1992-09-10 2002-12-09 住友化学工業株式会社 エチレン−αオレフィン共重合体及び該共重合体を用いて成形されてなる成形体
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EP0610942B1 (en) * 1993-02-12 1998-06-10 Tosoh Corporation Ethylene.alpha-olefin copolymer and film thereof

Also Published As

Publication number Publication date
WO1994019381A1 (fr) 1994-09-01
EP0690079B1 (en) 2002-07-03
EP0690079A1 (en) 1996-01-03
DE69430910D1 (de) 2002-08-08
EP0690079A4 (en) 1997-08-20
DE69430910T2 (de) 2002-12-12
US5747620A (en) 1998-05-05

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