ES2182336T3 - Nuevos sistemas de catalizadores para reacciones de (co-)polimerizacion, halogenuros-amidas de metalocenos y su utilizacion. - Google Patents

Nuevos sistemas de catalizadores para reacciones de (co-)polimerizacion, halogenuros-amidas de metalocenos y su utilizacion.

Info

Publication number
ES2182336T3
ES2182336T3 ES98932131T ES98932131T ES2182336T3 ES 2182336 T3 ES2182336 T3 ES 2182336T3 ES 98932131 T ES98932131 T ES 98932131T ES 98932131 T ES98932131 T ES 98932131T ES 2182336 T3 ES2182336 T3 ES 2182336T3
Authority
ES
Spain
Prior art keywords
reactions
metalocenos
halogenuros
amidas
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98932131T
Other languages
English (en)
Inventor
Florian Munck
Werner Zeiss
Christoph Hartmann
Alexander Vogel
Andreas Detig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
United Initiators GmbH and Co KG
Original Assignee
United Initiators GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United Initiators GmbH and Co KG filed Critical United Initiators GmbH and Co KG
Application granted granted Critical
Publication of ES2182336T3 publication Critical patent/ES2182336T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La invención se refiere a nuevos metalocenos sustituidos de manera mezclada con actividad mejorada, un procedimiento de producción de compuestos de metalocenos, así como la utilización de halogenuros de metalocenamidas para la generación de un sistema catalítico activo para reacciones de (co)polimerización.
ES98932131T 1997-06-10 1998-06-08 Nuevos sistemas de catalizadores para reacciones de (co-)polimerizacion, halogenuros-amidas de metalocenos y su utilizacion. Expired - Lifetime ES2182336T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19724465 1997-06-10

Publications (1)

Publication Number Publication Date
ES2182336T3 true ES2182336T3 (es) 2003-03-01

Family

ID=7832059

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98932131T Expired - Lifetime ES2182336T3 (es) 1997-06-10 1998-06-08 Nuevos sistemas de catalizadores para reacciones de (co-)polimerizacion, halogenuros-amidas de metalocenos y su utilizacion.

Country Status (12)

Country Link
US (1) US6316562B1 (es)
EP (2) EP1028123A3 (es)
JP (1) JP2002504940A (es)
AT (1) ATE223441T1 (es)
BR (1) BR9810432A (es)
CA (1) CA2293490A1 (es)
DE (1) DE59805425D1 (es)
DK (1) DK0990003T3 (es)
ES (1) ES2182336T3 (es)
NO (1) NO996038L (es)
PT (1) PT990003E (es)
WO (1) WO1998056831A1 (es)

Families Citing this family (104)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59914158D1 (de) 1998-11-25 2007-03-08 Basell Polyolefine Gmbh Metallocenmonohalogenide
GB9826874D0 (en) * 1998-12-07 1999-01-27 Borealis As Process
ATE422508T1 (de) 2001-12-19 2009-02-15 Borealis Tech Oy Herstellung von geträgerten katalysatoren für die olefinpolymerisation
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
ES2377948T3 (es) * 2003-06-20 2012-04-03 Borealis Polymers Oy Procedimiento para la preparación de una composición de un catalizador para la polimerización de olefinas
DE102004022861A1 (de) * 2004-05-06 2005-12-01 Basell Polyolefine Gmbh Verfahren zur racemo-selectiven Herstellung von ansa-Metallocenen
GB0423555D0 (en) 2004-10-22 2004-11-24 Borealis Tech Oy Process
ATE478921T1 (de) 2005-10-21 2010-09-15 Borealis Tech Oy Zusammensetzung
EP1795542A1 (en) 2005-12-07 2007-06-13 Borealis Technology Oy Polymer
EP1803743B1 (en) 2005-12-30 2016-08-10 Borealis Technology Oy Catalyst particles
DE602006016776D1 (de) 2006-07-14 2010-10-21 Borealis Tech Oy Polyethylen hoher Dichte
ATE461973T1 (de) 2007-01-22 2010-04-15 Borealis Tech Oy Polypropylenzusammensetzung mit niedriger oberflächenenergie
US20100280206A1 (en) 2007-11-09 2010-11-04 Borealis Technology Oy Polyethylene copolymer
EP2130860A1 (en) 2008-06-06 2009-12-09 Borealis Technology Oy Polymer
EP2133389A1 (en) 2008-06-12 2009-12-16 Borealis AG Polypropylene composition
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
EP2186831B1 (en) 2008-11-10 2013-01-02 Borealis AG Process for the preparation of an unsupported, solid olefin polymerisation catalyst and use in polymerisation of olefins
ES2392698T3 (es) 2008-11-10 2012-12-13 Borealis Ag Proceso para la preparación de un sistema catalizador metalocénico sólido, sin soporte, y su uso en la polimerización de olefinas
EP2204410A1 (en) 2008-12-31 2010-07-07 Borealis AG Article coated with a composition comprising polyethylene prepared with a single site catalyst
EP2275476A1 (en) 2009-06-09 2011-01-19 Borealis AG Automotive material with excellent flow, high stiffness, excellent ductility and low CLTE
PL2308923T3 (pl) 2009-10-09 2012-11-30 Borealis Ag Kompozyt włókna szklanego o ulepszonej przetwarzalności
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
EP2338921B8 (en) 2009-12-22 2015-05-06 Borealis AG Preparation of single-site catalysts
EP2338920A1 (en) 2009-12-22 2011-06-29 Borealis AG Preparation of single-site catalysts
US8829128B2 (en) 2009-12-22 2014-09-09 Borealis Ag Preparation of polypropylene in the presence of a single-site catalyst
EP2386583A1 (en) 2010-05-07 2011-11-16 Borealis AG Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
EP2385073A1 (en) 2010-05-07 2011-11-09 Borealis AG Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
ES2564189T3 (es) 2010-05-07 2016-03-18 Borealis Ag Preparación de un sistema de catalizador sólido
EP2738183A1 (en) 2010-05-07 2014-06-04 Borealis AG Preparation of a solid catalyst system
EP2415598B1 (en) 2010-08-06 2014-02-26 Borealis AG Multilayer film
CA2816187C (en) 2010-10-28 2019-02-05 Borealis Ag Single site polymer
EP2495264B1 (en) 2011-03-04 2013-05-08 Borealis AG Exterior automotive article with reduced paintability failure
EP2554375B1 (en) 2011-08-03 2014-04-09 Borealis AG Film
EP2570195B1 (en) 2011-09-15 2014-12-03 Borealis AG Protective polymer layer
WO2013149915A1 (en) 2012-04-04 2013-10-10 Borealis Ag High-flow fiber reinforced polypropylene composition
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
ES2622627T3 (es) 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
EP2722345B1 (en) 2012-10-18 2018-12-05 Borealis AG Catalyst for the polymerisation of olefins
EP2829556B1 (en) 2013-07-24 2016-11-16 Borealis AG Process
EP2829558B1 (en) 2013-07-24 2016-12-14 Borealis AG Process
JP6216887B2 (ja) 2013-08-14 2017-10-18 ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓ Ａｇ 低温における耐衝撃性が改善されたプロピレン組成物
BR112016003128B1 (pt) 2013-08-21 2021-08-24 Borealis Ag Composição de poliolefina de alto fluxo com alta rigidez e resistência e artigos automotivos
EP3036283B1 (en) 2013-08-21 2019-02-27 Borealis AG High flow polyolefin composition with high stiffness and toughness
EP2853563B1 (en) 2013-09-27 2016-06-15 Borealis AG Films suitable for BOPP processing from polymers with high XS and high Tm
EP2860031B1 (en) 2013-10-11 2016-03-30 Borealis AG Machine direction oriented film for labels
PL2865713T3 (pl) 2013-10-24 2016-10-31 Wyrób formowany z rozdmuchiwaniem na bazie dwumodalnego bezładnego kopolimeru
US10519259B2 (en) 2013-10-24 2019-12-31 Borealis Ag Low melting PP homopolymer with high content of regioerrors and high molecular weight
WO2015062936A1 (en) 2013-10-29 2015-05-07 Borealis Ag Solid single site catalysts with high polymerisation activity
BR112016009549B1 (pt) 2013-11-22 2021-07-27 Borealis Ag Homopolímero de propileno de baixa emissão com alto índice de fluidez
BR112016011829B1 (pt) 2013-12-04 2022-01-18 Borealis Ag Composição de polipropileno, fibra e trama soprada em fusão, artigo e uso da composição de polipropileno
KR101873134B1 (ko) 2013-12-18 2018-06-29 보레알리스 아게 향상된 강성/인성 균형을 가진 bopp 필름
US10227427B2 (en) 2014-01-17 2019-03-12 Borealis Ag Process for preparing propylene/1-butene copolymers
JP6474417B2 (ja) 2014-02-06 2019-02-27 ボレアリス エージー 軟質及び透明衝撃コポリマー
WO2015117958A1 (en) 2014-02-06 2015-08-13 Borealis Ag Soft copolymers with high impact strength
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
EP2947118B1 (en) 2014-05-20 2017-11-29 Borealis AG Polypropylene composition for automotive interior applications
EP2995631A1 (en) 2014-09-12 2016-03-16 Borealis AG Process for producing graft copolymers on polyolefin backbone
EP3053976A1 (en) 2015-02-09 2016-08-10 Borealis AG Adhesive composition
CN107428138B (zh) 2015-02-27 2019-07-12 博里利斯股份公司 仅基于聚乙烯的层压膜结构
ES2819978T5 (en) 2015-12-15 2026-02-24 Borealis Gmbh Polyethylene based laminated film structure with barrier properties
EP3241611B1 (en) 2016-05-02 2020-03-04 Borealis AG A process for feeding a polymerisation catalyst
FI3463859T4 (fi) 2016-06-03 2025-07-16 Borealis Ag Monikerroksinen rakenne
EP3261096A1 (en) 2016-06-21 2017-12-27 Borealis AG Cable and composition
EP3261095B1 (en) 2016-06-21 2026-02-11 Borealis GmbH Cable with improved electrical properties
US11613633B2 (en) 2016-06-21 2023-03-28 Borealis Ag Polymer composition for wire and cable applications with advantageous thermomechanical behaviour and electrical properties
EP3261093B1 (en) 2016-06-21 2023-08-02 Borealis AG Cable with advantageous electrical properties
WO2017220724A1 (en) 2016-06-23 2017-12-28 Borealis Ag Process for catalyst deactivation
WO2018091653A1 (en) 2016-11-18 2018-05-24 Borealis Ag Catalyst
EP3728342A1 (en) 2017-12-21 2020-10-28 Borealis AG Process for the preparation of solid catalyst
US11447580B2 (en) 2017-12-27 2022-09-20 Borealis Ag Ziegler-Natta catalyst and preparation thereof
CN111566131B (zh) 2017-12-28 2024-04-26 博里利斯股份公司 催化剂及其制备方法
JP7329256B2 (ja) * 2018-02-07 2023-08-18 ユーピー ケミカル カンパニー リミテッド 第４族金属元素含有化合物、その製造方法、それを含む膜形成用前駆体組成物、及びそれを利用する膜の形成方法
WO2020064314A1 (en) 2018-09-26 2020-04-02 Borealis Ag Propylene copolymer with excellent optical properties
EP3856798A1 (en) 2018-09-26 2021-08-04 Borealis AG Propylene random copolymer for use in film applications
CN119931216A (zh) 2018-09-26 2025-05-06 博里利斯股份公司 具有优异的光学和机械性能的丙烯共聚物组合物
EP3883989B1 (en) 2018-11-23 2024-02-28 Borealis AG Polypropylene composition with improved optical properties and whitening resistance
ES2986685T3 (es) 2018-11-30 2024-11-12 Borealis Ag Proceso de lavado
ES2945963T3 (es) 2018-12-14 2023-07-11 Borealis Ag Composición de polipropileno con combinación favorable de óptica, suavidad y bajo sellado
US12202964B2 (en) 2019-01-28 2025-01-21 Borealis Ag Polymer composition
WO2020156993A1 (en) 2019-01-28 2020-08-06 Borealis Ag Process for producing a polymer composition
EP3825357B1 (en) 2019-11-25 2025-04-09 Borealis AG Propylene composition for foaming with improved mechanical properties
US20230250319A1 (en) 2020-07-13 2023-08-10 Borealis Ag Adhesive polyethylene composition
EP4179035B1 (en) 2020-07-13 2026-03-04 Borealis GmbH Adhesive polyethylene composition
WO2022129409A1 (en) 2020-12-18 2022-06-23 Borealis Ag Modification of polyethylene terpolymer
EP4019582B1 (en) 2020-12-23 2025-07-30 Borealis GmbH Polyethylene film
KR20230130052A (ko) 2021-01-08 2023-09-11 보레알리스 아게 조성물
EP4036130B1 (en) 2021-01-29 2023-03-22 Borealis AG Modification of polyethylene copolymer
EP4053194B1 (en) 2021-03-03 2023-08-02 Borealis AG Monolayer blown film
EP4056599B1 (en) 2021-03-09 2023-07-26 Borealis AG Polyethylene composition for a film layer
ES2956482T3 (es) 2021-03-09 2023-12-21 Borealis Ag Composición de polietileno para una capa de película
EP4305075A1 (en) 2021-03-09 2024-01-17 Borealis AG Polyethylene composition for a film layer
ES3071095T3 (en) 2021-10-10 2026-06-19 Borealis Gmbh Polyethylene composition for a film layer
EP4166581A1 (en) 2021-10-12 2023-04-19 Borealis AG Propylene composition for foaming with high melt flow rate
WO2023198579A1 (en) 2022-04-11 2023-10-19 Borealis Ag Multilayer film
EP4389783A1 (en) 2022-12-20 2024-06-26 Borealis AG Catalyst transition process
EP4389776A1 (en) 2022-12-20 2024-06-26 Borealis AG Process
TW202438539A (zh) 2022-12-23 2024-10-01 奧地利商柏列利斯股份公司 高流動性聚丙烯均聚物的製造方法
KR20250126808A (ko) 2022-12-23 2025-08-25 보레알리스 아게 폴리프로필렌 단독중합체 또는 공중합체의 제조방법
CN120380039A (zh) 2022-12-23 2025-07-25 北欧化工股份公司 聚丙烯共聚物的生产方法
EP4417629A1 (en) 2023-02-14 2024-08-21 Borealis AG Polyethylene blend for a film layer
EP4735486A1 (en) 2023-06-30 2026-05-06 Borealis GmbH Process
EP4538321A1 (en) 2023-10-11 2025-04-16 Borealis AG A way to increase the nucleation efficiency of ssc materials
WO2025219533A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for the preparation of a propylene homopolymer
WO2025219537A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for propylene polymerization with optimized prepolymerization conditions

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4728706A (en) 1986-08-29 1988-03-01 E. I. Du Pont De Nemours And Company Titanium, zirconium- and hafnium containing initiators in the polymerization of acrylic monomers to "living" polymers
BR9104067A (pt) * 1990-09-20 1992-05-26 Dow Chemical Co Composto,processo para preparacao de compostos cataliticos e processo para polimerizacao de um ou mais monomeros
EP0519746A1 (en) * 1991-06-20 1992-12-23 Mitsui Petrochemical Industries, Ltd. Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst

Also Published As

Publication number Publication date
BR9810432A (pt) 2000-09-19
NO996038D0 (no) 1999-12-08
EP0990003B1 (de) 2002-09-04
DE59805425D1 (de) 2002-10-10
ATE223441T1 (de) 2002-09-15
US6316562B1 (en) 2001-11-13
NO996038L (no) 2000-02-03
DK0990003T3 (da) 2003-01-06
EP1028123A3 (de) 2004-12-01
WO1998056831A1 (de) 1998-12-17
JP2002504940A (ja) 2002-02-12
EP0990003A1 (de) 2000-04-05
EP1028123A2 (de) 2000-08-16
CA2293490A1 (en) 1998-12-17
PT990003E (pt) 2003-01-31

Similar Documents

Publication Publication Date Title
PT990003E (pt) Novos sistemas de catalisador para reaccoes de (co-)polimerizacao halogenetos de metalocenamida e sua utilizacao
BR9814410A (pt) Sistema catalisador suportado, uso do mesmo, e, processos para preparar um polìmero de olefina e, um sistema catalisador suportado.
NO951267D0 (no) Homogene katalysatorkomplekser på bærer, for olefinpolymerisasjon
FR2769245B1 (fr) Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
DE69839627D1 (de) Katalysator auf polymerträger zur polymerisation von olefinen
PT1204476E (pt) Melhoramentos relativos a processos cataliticos com um composto metalico
AR009034A1 (es) Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los
ES2041053T3 (es) Catalizadores para la polimerizacion de olefinas.
FI945486A0 (fi) Metalloseeneja, menetelmä niiden valmistamiseksi sekä niiden käyttö katalyytteinä
BR9809735A (pt) Catalisador e processo para a polimerização de olefinas
ATE239748T1 (de) Phosphol und diphosphol liganden für katalyse
DE69524879D1 (de) Nichtaromatische anionische dienylgruppe enthaltende metall (iii) komplexe und diese enthaltende additionspolymerizationskatalysatoren
CS9100655A2 (en) Catalyst applied on carrier material for ethylene polymerization and for ethylene copolymerization with alpha-olefins, process of this catalyst preparation and application
ES2101765T3 (es) Catalizadores para la polimerizacion de alfa-olefinas de ciclopentadienil-metal del grupo 6b y proceso para polimerizar alfa-olefinas.
DE69519049D1 (de) Polymerisationskatalysatoren
MX9702453A (es) Proceso de polimerizacion de olefina proquiral sindiotactica.
BR9000285A (pt) Composicoes de catalisador,processos para a preparacao de um composto de paladio complexo e de polimeros
DE69303660D1 (de) Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators
EA199700048A1 (ru) Циклопентадиеновые соединения, замещенные группой, содержащей гетероатом
ES2033514T3 (es) Procedimiento para la polimerizacion estereoespecifica de alfa-olefinas y sistema catalitico utilizable para dicha polimerizacion.
MX164614B (es) Proceso para preparar un polimero que contiene almidon
RU94001575A (ru) Каталитические композиции и способ изготовления полиолефинов
MY132452A (en) Process for preparing aldehydes
ES2135239T3 (es) Composiciones cataliticas que comprenden compuestos organometalicos.
ZA9610688B (en) Supported catalyst system a process for its preparation and its use for the polymerization of olefins