ES2182494T3 - Procedimiento integrado para la preparacion de complejos de dienos. - Google Patents
Procedimiento integrado para la preparacion de complejos de dienos.Info
- Publication number
- ES2182494T3 ES2182494T3 ES99909951T ES99909951T ES2182494T3 ES 2182494 T3 ES2182494 T3 ES 2182494T3 ES 99909951 T ES99909951 T ES 99909951T ES 99909951 T ES99909951 T ES 99909951T ES 2182494 T3 ES2182494 T3 ES 2182494T3
- Authority
- ES
- Spain
- Prior art keywords
- group
- groups
- hydrocarbyl
- hydrogen
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 5
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 3
- 125000000129 anionic group Chemical group 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002879 Lewis base Substances 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 150000007527 lewis bases Chemical class 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 230000007935 neutral effect Effects 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 229910052735 hafnium Chemical group 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Un procedimiento para preparar un complejo metálico correspondiente a la fórmula: (L-A-L)MD, o uno de sus aductos base de Lewis, que comprende poner en contacto, en cualquier orden, un complejo de un metal del Grupo 4 que corresponde a la fórmula MX2D, o uno de sus aductos base de Lewis, y un compuesto de la fórmula: (L-A-L)M"n, y recuperar el producto resultante, en el que: M es titanio, zirconio o hafnio en el estado de oxidación formal +2; M" es hidrógeno o un catión metálico del Grupo 1, un dicatión metálico del Grupo 2 o de cinc, un catión monohaluro de magnesio o cinc, un grupo tri(hidrocarbil C1- 20)sililo, un grupo mono(hidrocarbil C1-20)aluminio; un grupo di(hidrocarbil C1-20)-aluminio; o un grupo mono(hidrocarbil C1-20)cinc, con la condición de que M" sea lábil en las condiciones de reacción; L, independientemente de cada caso, es un grupo ligando aniónico unido a A, excepto en la fórmula (L-A-L- )M"n, cuando M"es hidrógeno o sililo, L es un grupo ligando neutro unido a A, conteniendo dicho grupo L hasta 50 átomos distintos de hidrógeno; A es un grupo puente divalente que une dos grupos L; D es un derivado de 1,3-butadieno neutro y sustituido, sustituido con uno o más grupos hidrocarbilo, grupos sililo, grupos hidrocarbilsililo, grupos sililhidrocarbilo o sus mezclas, estando situado al menos uno de dichos sustituyentes en la posición 1 ó 4, teniendo dicho D de 5 a 40 átomos distintos de hidrógeno; X, independientemente de cada caso, es un grupo lábil aniónico monovalente de hasta 50 átomos distintos de hidrógeno y, opcionalmente, dos grupos X están unidos entre sí, formando con ello un grupo lábil aniónico divalente; y
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7748998P | 1998-03-11 | 1998-03-11 | |
| US9120798P | 1998-06-30 | 1998-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2182494T3 true ES2182494T3 (es) | 2003-03-01 |
Family
ID=26759319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99909951T Expired - Lifetime ES2182494T3 (es) | 1998-03-11 | 1999-03-10 | Procedimiento integrado para la preparacion de complejos de dienos. |
Country Status (14)
| Country | Link |
|---|---|
| US (3) | US6084115A (es) |
| EP (1) | EP1062219B1 (es) |
| JP (1) | JP4577676B2 (es) |
| KR (1) | KR100624249B1 (es) |
| CN (1) | CN1210280C (es) |
| AR (1) | AR015731A1 (es) |
| AT (1) | ATE222913T1 (es) |
| AU (1) | AU2903299A (es) |
| BR (1) | BR9908807A (es) |
| CA (1) | CA2322324C (es) |
| DE (1) | DE69902638T2 (es) |
| ES (1) | ES2182494T3 (es) |
| PT (1) | PT1062219E (es) |
| WO (1) | WO1999046270A1 (es) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6479424B1 (en) | 1998-12-14 | 2002-11-12 | Bp Corporation North America Inc. | Fluxional catalysts and related ligands containing bulky substituents |
| GB9918668D0 (en) * | 1999-08-06 | 1999-10-13 | Bp Chem Int Ltd | Polymerisation catalysts |
| DE19962910A1 (de) * | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| KR101059401B1 (ko) * | 2002-12-04 | 2011-08-29 | 바젤 폴리올레핀 게엠베하 | 1-부텐 중합체 제조 방법 |
| US7534848B2 (en) | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE10358082A1 (de) * | 2003-12-10 | 2005-07-14 | Basell Polyolefine Gmbh | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| JP5188178B2 (ja) | 2004-06-16 | 2013-04-24 | ダウ グローバル テクノロジーズ エルエルシー | 重合調整剤を選択するための技術 |
| BRPI0513057A (pt) * | 2004-07-08 | 2008-04-22 | Exxonmobil Chem Patents Inc | produção de polìmero em condições supercrìticas |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| JP2010529253A (ja) | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US8283419B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
| US8399725B2 (en) | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
| US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
| US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
| US8940839B2 (en) | 2011-03-25 | 2015-01-27 | Exxonmobil Chemical Patents Inc. | Diblock copolymers prepared by cross metathesis |
| EP2688916A4 (en) * | 2011-03-25 | 2014-10-22 | Exxonmobil Chem Patents Inc | NOVEL CATALYSTS AND METHOD OF USE THEREOF FOR PRODUCING VINYL-DERMED POLYMERS |
| US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| US8835563B2 (en) | 2011-03-25 | 2014-09-16 | Exxonmobil Chemical Patents Inc. | Block copolymers from silylated vinyl terminated macromers |
| US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
| JP6984128B2 (ja) * | 2016-12-29 | 2021-12-17 | 日本ポリエチレン株式会社 | ポリエチレン樹脂の製造方法並びに当該方法により製造されたポリエチレン樹脂を用いた太陽電池封止材および太陽電池モジュール |
| CN111408409B (zh) * | 2019-01-04 | 2023-03-14 | 中国石油化工股份有限公司 | 一种催化剂组合物、其制备方法及其在乙烯选择性二聚化合成1-丁烯的反应中的应用 |
| CA3216518A1 (en) | 2021-04-25 | 2022-11-03 | China Petroleum & Chemical Corporation | Propylene-based copolymer, preparation method therefor and use thereof, and polypropylene composition containing same |
| KR20230069618A (ko) * | 2021-11-12 | 2023-05-19 | 주식회사 에스피씨아이 | 초고분자량 폴리올레핀 중합용 메탈로센 화합물 및 이를 이용한 초고분자량 폴리올레핀 중합체의 제조방법 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| US5616664A (en) * | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
| US5512693A (en) * | 1994-12-07 | 1996-04-30 | The Dow Chemical Company | Preparation of titanium (II) or zirconium (II) complexes |
| US5491246A (en) * | 1995-04-24 | 1996-02-13 | The Dow Chemical Company | Synthesis of group 4 metal diene complexes |
| US5679816A (en) * | 1996-01-03 | 1997-10-21 | The Dow Chemical Company | Preparation of biscyclopentadienyl diene complexes |
| EP1056752B1 (en) * | 1998-02-20 | 2003-06-25 | Dow Global Technologies Inc. | Catalyst activators comprising expanded anions |
-
1999
- 1999-03-10 KR KR1020007010060A patent/KR100624249B1/ko not_active Expired - Fee Related
- 1999-03-10 JP JP2000535647A patent/JP4577676B2/ja not_active Expired - Lifetime
- 1999-03-10 DE DE69902638T patent/DE69902638T2/de not_active Expired - Lifetime
- 1999-03-10 PT PT99909951T patent/PT1062219E/pt unknown
- 1999-03-10 AT AT99909951T patent/ATE222913T1/de not_active IP Right Cessation
- 1999-03-10 AU AU29032/99A patent/AU2903299A/en not_active Abandoned
- 1999-03-10 ES ES99909951T patent/ES2182494T3/es not_active Expired - Lifetime
- 1999-03-10 BR BR9908807-0A patent/BR9908807A/pt not_active Application Discontinuation
- 1999-03-10 CA CA002322324A patent/CA2322324C/en not_active Expired - Fee Related
- 1999-03-10 US US09/265,641 patent/US6084115A/en not_active Expired - Lifetime
- 1999-03-10 AR ARP990101028A patent/AR015731A1/es not_active Application Discontinuation
- 1999-03-10 CN CNB99803892XA patent/CN1210280C/zh not_active Expired - Lifetime
- 1999-03-10 EP EP99909951A patent/EP1062219B1/en not_active Expired - Lifetime
- 1999-03-10 WO PCT/US1999/005230 patent/WO1999046270A1/en not_active Ceased
- 1999-10-20 US US09/420,625 patent/US6136993A/en not_active Expired - Lifetime
- 1999-10-20 US US09/420,626 patent/US6127563A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69902638T2 (de) | 2003-04-24 |
| EP1062219A1 (en) | 2000-12-27 |
| DE69902638D1 (de) | 2002-10-02 |
| WO1999046270A1 (en) | 1999-09-16 |
| KR20010041790A (ko) | 2001-05-25 |
| US6136993A (en) | 2000-10-24 |
| JP2002506074A (ja) | 2002-02-26 |
| CN1210280C (zh) | 2005-07-13 |
| US6127563A (en) | 2000-10-03 |
| US6084115A (en) | 2000-07-04 |
| AU2903299A (en) | 1999-09-27 |
| CA2322324C (en) | 2007-05-08 |
| EP1062219B1 (en) | 2002-08-28 |
| BR9908807A (pt) | 2000-10-31 |
| CN1292793A (zh) | 2001-04-25 |
| CA2322324A1 (en) | 1999-09-16 |
| AR015731A1 (es) | 2001-05-16 |
| PT1062219E (pt) | 2003-01-31 |
| ATE222913T1 (de) | 2002-09-15 |
| JP4577676B2 (ja) | 2010-11-10 |
| KR100624249B1 (ko) | 2006-09-13 |
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