ES2182749T3 - Catalizadores de lecho fijo. - Google Patents

Catalizadores de lecho fijo.

Info

Publication number
ES2182749T3
ES2182749T3 ES00115182T ES00115182T ES2182749T3 ES 2182749 T3 ES2182749 T3 ES 2182749T3 ES 00115182 T ES00115182 T ES 00115182T ES 00115182 T ES00115182 T ES 00115182T ES 2182749 T3 ES2182749 T3 ES 2182749T3
Authority
ES
Spain
Prior art keywords
catalyst
catalysts
metal
raney
fixed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00115182T
Other languages
English (en)
Inventor
Daniel Dr Ostgard
Monika Berweiler
Barbara Bender
Gernot Stein
Konrad Dr Mobus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Application granted granted Critical
Publication of ES2182749T3 publication Critical patent/ES2182749T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Catalizador de lecho fijo de metal Raney, moldeado y activado, que se puede obtener por un procedimiento que comprende esencialmente las siguientes etapas: preparación de una mezcla de polvos que esencialmente constan de por lo menos una aleación para el catalizador y eventualmente por lo menos de un aglutinante, y de un humectante y, en caso necesario, de un aditivo, elegido del grupo constituido por un adyuvante para el moldeo, lubricante, plastificante, formador de poros y mezclas de los mismos, constando la citada aleación para el catalizador esencialmente por lo menos de un metal Raney industrial como metal catalíticamente activo para el catalizador, un componente de la aleación lixiviable y, en caso necesario, de un promotor, constando el citado aglutinante esencialmente de por lo menos un metal Raney industrial puro, homogeneización de la citada mezcla, moldeo de la citada mezcla, para obtener un precursor moldeado del catalizador, que todavía no está activado, calcinación del citadoprecursor moldeado del catalizador a una temperatura por debajo de 850°C, para producir un precursor sinterizado del catalizador y activación del citado precursor sinterizado del catalizador por lixiviación con un álcali del citado componente lixiviable de la aleación, hasta que la capa exterior lixiviada, y activada con ello, tenga un espesor regulable entre 0, 05 y 1 mm y, a continuación, lavado del catalizador definitivo; contaminación del catalizador citado con renio como promotor después de la activación citada, por introducción del citado catalizador en una solución de ácido perrénico o soluciones de otras sales de Re a lo largo de un periodo suficiente para fijar todo el renio sobre el catalizador o por adición del renio a la aleación sin activar o, eventualmente, por adición del renio al aglutinante.
ES00115182T 1999-07-31 2000-07-13 Catalizadores de lecho fijo. Expired - Lifetime ES2182749T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19936135A DE19936135A1 (de) 1999-07-31 1999-07-31 Festbettkatalysatoren

Publications (1)

Publication Number Publication Date
ES2182749T3 true ES2182749T3 (es) 2003-03-16

Family

ID=7916777

Family Applications (1)

Application Number Title Priority Date Filing Date
ES00115182T Expired - Lifetime ES2182749T3 (es) 1999-07-31 2000-07-13 Catalizadores de lecho fijo.

Country Status (8)

Country Link
US (1) US6284703B1 (es)
EP (1) EP1086745B1 (es)
AT (1) ATE223754T1 (es)
DE (2) DE19936135A1 (es)
DK (1) DK1086745T3 (es)
ES (1) ES2182749T3 (es)
PT (1) PT1086745E (es)
ZA (1) ZA200003791B (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6309758B1 (en) * 1999-05-06 2001-10-30 W. R. Grace & Co.-Conn. Promoted porous catalyst
EP1125633B1 (de) * 2000-02-18 2007-01-03 Degussa AG Verfahren zur Herstellung von Carbonsäuren durch Dehydrierung von Alkoholen
US20020038051A1 (en) 2000-02-18 2002-03-28 Degussa-Huls Ag Raney copper
ATE350158T1 (de) * 2000-02-18 2007-01-15 Degussa Verfahren zur herstellung von carbonsäuren durch dehydrierung von alkoholen
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
DE10219224A1 (de) * 2002-04-30 2003-11-13 Basf Ag Verfahren zur Herstellung von gamma-Butyrolacton
US7682724B2 (en) * 2002-10-18 2010-03-23 Monsanto Technology Llc Use of metal supported copper catalysts for reforming alcohols
US7375053B2 (en) * 2003-04-07 2008-05-20 W. R. Grace & Co.- Conn. Nickel and cobalt plated sponge catalysts
US6995115B2 (en) * 2003-09-23 2006-02-07 Catalytic Materials, Llc Catalyst for the generation of CO-free hydrogen from methane
US7001586B2 (en) * 2003-09-23 2006-02-21 Catalytic Materials, Llc CO-free hydrogen from decomposition of methane
US20050100494A1 (en) 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US6919489B1 (en) 2004-03-03 2005-07-19 Eastman Chemical Company Process for a cyclohexanedimethanol using raney metal catalysts
US7304011B2 (en) 2004-04-15 2007-12-04 W.R. Grace & Co. -Conn. Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en) 2004-04-15 2005-10-20 George Yaluris Compositions and processes for reducing NOx emissions during fluid catalytic cracking
WO2006050742A1 (en) * 2004-11-10 2006-05-18 Degussa Gmbh The fixed bed hydrogenation of fatty nitriles to fatty amines
US20080214387A1 (en) * 2004-11-12 2008-09-04 Daniel Ostgard Process For Modifying Catalysts and the Use of the Catalysts
US20090264679A1 (en) * 2004-12-14 2009-10-22 Daniel Ostgard Control of metal catalyst settling rates, settling densities and improved performance via use of flocculants
KR101382014B1 (ko) 2005-04-27 2014-04-04 더블유.알. 그레이스 앤드 캄파니-콘. 유동상 접촉 분해 중의 ＮＯｘ 방출 감소를 위한 조성물 및공정
DE102005040286A1 (de) * 2005-08-25 2007-03-01 Basf Ag Mechanisch stabiler Katalysator auf Basis von alpha-Aluminiumoxid
CA2654795C (en) * 2006-06-13 2014-08-26 Monsanto Technology Llc Reformed alcohol power systems
US8735635B2 (en) 2009-02-25 2014-05-27 W. R. Grace & Co.-Conn. Process for making 1, 2-propane diol from hydrogenation of glycerol
US20110011772A1 (en) * 2009-07-15 2011-01-20 Stephen Raymond Schmidt Nickel and Cobalt Plated Sponge Catalysts
US8766017B2 (en) 2011-07-29 2014-07-01 Eastman Chemical Company Integrated process for the preparation of 1,4-cyclohexanedimethanol from terephthalic acid
US8410318B2 (en) 2011-07-29 2013-04-02 Eastman Chemical Company Process for the preparation of 1,4-cyclohexanedimethanol from terephthalic acid
US8410317B2 (en) 2011-07-29 2013-04-02 Eastman Chemical Company Process for the preparation of 1,4-cyclohexanedimethanol
US8877984B2 (en) 2011-07-29 2014-11-04 Eastman Chemical Company Process for the preparation of 1,3-cyclohexanedimethanol from isophthalic acid
ES3010651T3 (en) 2015-01-30 2025-04-04 Evonik Operations Gmbh Method for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT257556B (de) * 1962-11-16 1967-10-10 Celanese Corp Verfahren zur Herstellung von Alkoholen
BE643400A (es) * 1963-06-07 1964-05-29
US4089812A (en) * 1976-07-30 1978-05-16 The United States Of America As Represented By The Secretary Of The Interior Massive catalyst
US4043946A (en) 1976-07-30 1977-08-23 The United States Of America As Represented By The Secretary Of The Interior Production of supported Raney nickel catalysts by reactive diffusion
DE3537247A1 (de) * 1985-10-19 1987-04-23 Bayer Ag Verwendung von modifizierten raney-katalysatoren zur herstellung von aromatischen diaminoverbindungen
US4895994A (en) * 1988-04-14 1990-01-23 W. R. Grace & Co.-Conn. Shaped catalysts and processes
US4826799A (en) * 1988-04-14 1989-05-02 W. R. Grace & Co.-Conn. Shaped catalyst and process for making it
DE4335360A1 (de) * 1993-10-16 1995-04-20 Degussa Aktivierter Metall-Festbettkatalysator nach Raney und Verfahren zu seiner Herstellung
DE4424069A1 (de) * 1994-07-08 1996-01-11 Bayer Ag Verfahren zur Herstellung von Bernsteinsäureanhydrid
DE4446907A1 (de) * 1994-12-27 1996-07-04 Basf Ag Verfahren zur Herstellung eines Hydrierkatalysators
TW340806B (en) * 1995-03-28 1998-09-21 Mitsui Toatsu Chemicals Modified Raney catalyst and process for preparation thereof
DE19640554A1 (de) * 1996-10-01 1998-04-02 Basf Ag Verfahren zur Herstellung von Phthaliden
DE19721897A1 (de) * 1997-05-26 1998-12-03 Degussa Geformter Metall-Festbettkatalysator, Verfahren zu seiner Herstellung und seine Verwendung

Also Published As

Publication number Publication date
US6284703B1 (en) 2001-09-04
PT1086745E (pt) 2003-01-31
DK1086745T3 (da) 2002-11-25
DE19936135A1 (de) 2001-02-15
EP1086745A1 (de) 2001-03-28
DE50000478D1 (de) 2002-10-17
EP1086745B1 (de) 2002-09-11
ATE223754T1 (de) 2002-09-15
ZA200003791B (en) 2001-02-07

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