ES2183761T3 - Proceso de alquilacion de naftalenos utilizando catalizador mixto de h/nh3. - Google Patents

Proceso de alquilacion de naftalenos utilizando catalizador mixto de h/nh3.

Info

Publication number
ES2183761T3
ES2183761T3 ES00107556T ES00107556T ES2183761T3 ES 2183761 T3 ES2183761 T3 ES 2183761T3 ES 00107556 T ES00107556 T ES 00107556T ES 00107556 T ES00107556 T ES 00107556T ES 2183761 T3 ES2183761 T3 ES 2183761T3
Authority
ES
Spain
Prior art keywords
alkylation
naftalen
ammonium
mixed catalyst
alkylating agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00107556T
Other languages
English (en)
Inventor
Susan Chmura Ardito
Henry Ashjian
Thomas F Degnan
Terry Eugene Helton
Quang Ngoc Le
Augusto Rudolfo Quinones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
ExxonMobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Oil Corp filed Critical ExxonMobil Oil Corp
Application granted granted Critical
Publication of ES2183761T3 publication Critical patent/ES2183761T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Procedimiento para la preparación de naftalenos substituidos por alquilos de cadena larga, que comprende la alquilación de un naftaleno con un agente alquilante que posee un grupo alifático alquilante que tiene, como mínimo, seis átomos de carbono, en condiciones de reacción de alquilación en presencia de un catalizador de alquilación que comprende ceolita Y que contiene lugares intercambiables y amonio y especies protónicas asociadas con los lugares de intercambio, y en el que la proporción de amonio:especies protónicas se encuentra dentro de una gama de 95:5 a 5:95, base molar, formando un naftaleno alquilado que posee como mínimo un grupo alquilo derivado del agente alquilante.
ES00107556T 1993-12-27 1994-12-19 Proceso de alquilacion de naftalenos utilizando catalizador mixto de h/nh3. Expired - Lifetime ES2183761T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/173,006 US5457254A (en) 1993-12-27 1993-12-27 Naphthalene alkylation process using mixed H/NH3 form catalyst

Publications (1)

Publication Number Publication Date
ES2183761T3 true ES2183761T3 (es) 2003-04-01

Family

ID=22630112

Family Applications (2)

Application Number Title Priority Date Filing Date
ES00107556T Expired - Lifetime ES2183761T3 (es) 1993-12-27 1994-12-19 Proceso de alquilacion de naftalenos utilizando catalizador mixto de h/nh3.
ES95906670T Expired - Lifetime ES2154724T3 (es) 1993-12-27 1994-12-19 Proceso de alquilacion de naftaleno utilizando un catalizador zedita usy en forma de mezcla de h/nh3.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES95906670T Expired - Lifetime ES2154724T3 (es) 1993-12-27 1994-12-19 Proceso de alquilacion de naftaleno utilizando un catalizador zedita usy en forma de mezcla de h/nh3.

Country Status (9)

Country Link
US (1) US5457254A (es)
EP (2) EP1020417B1 (es)
JP (1) JP3832849B2 (es)
AU (1) AU675612B2 (es)
CA (1) CA2174513A1 (es)
DE (2) DE69431539T2 (es)
ES (2) ES2183761T3 (es)
TW (1) TW300880B (es)
WO (1) WO1995018083A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5545788A (en) * 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
US5629463A (en) * 1993-12-23 1997-05-13 Mobil Oil Corporation Naphthalene alkylation with RE and mixed H/NH3 form catalyst
EP0796908A1 (en) 1996-02-20 1997-09-24 Unilever N.V. Oxidation resistant lubricant
AU6165399A (en) * 1998-10-01 2000-04-17 Solutia Inc. Alkylation of aromatic compounds with alpha-olefins using zeolite catalysts
US6747182B2 (en) 2000-03-24 2004-06-08 Exxonmobil Chemical Patents Inc. Production of alkylated aromatic compounds using dealuminated catalysts
US6596662B2 (en) 2000-03-24 2003-07-22 Exxonmobil Chemical Patents Inc. Production of alkylated aromatic compounds using dealuminated catalysts
US6436882B1 (en) 2001-06-29 2002-08-20 King Industries, Inc. Functional fluids
US20050192184A1 (en) * 2001-11-29 2005-09-01 Wu Margaret M. Alkylated naphthalenes as synthetic lubricant base stocks
US7312185B2 (en) * 2002-10-31 2007-12-25 Tomlin Scientific Inc. Rock bit grease composition
TWM254134U (en) * 2004-01-30 2005-01-01 Jr-Yi Yang Hair care device
US8735427B2 (en) 2010-04-09 2014-05-27 Pacific Tech Industries, Inc. Grease-like gel for repelling rodents
US8697752B2 (en) 2010-04-09 2014-04-15 Pacific Tech Industries, Inc. Grease-like gel for repelling insects and preventing undesirable behavior in hoofed animals
US9238599B2 (en) * 2011-12-07 2016-01-19 Exxonmobil Chemical Patents Inc. Alkylaromatic process
US9187384B2 (en) 2011-12-13 2015-11-17 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
CN103508834A (zh) * 2013-10-09 2014-01-15 江苏中能化学有限公司 一种高选择性合成1,1-苯基四氢萘基乙烷异构体作为导热流体的方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3716596A (en) * 1968-04-18 1973-02-13 Mobil Oil Corp Alkylation and dealkylation of aromatics in the presence of crystalline aluminosilicates
US4570027A (en) * 1984-04-27 1986-02-11 Exxon Research And Engineering Co. Alkylation of aromatic molecules using a silica-alumina catalyst derived from zeolite
US5243115A (en) * 1986-03-31 1993-09-07 Chemical Research & Licensing Company Alkylation of organic aromatic compounds
US4962256A (en) * 1988-10-06 1990-10-09 Mobil Oil Corp. Process for preparing long chain alkyl aromatic compounds
DE68903419T2 (de) * 1988-03-28 1993-06-03 Tosoh Corp Ein verfahren zur herstellung von diisopropylauphthalenen.
US5001295A (en) * 1988-10-06 1991-03-19 Mobil Oil Corp. Process for preparing dialkylnaphthalene
US5043508A (en) * 1989-05-30 1991-08-27 Mobil Oil Corporation Process for preparing long chain alkyl aromatic compounds
US5034563A (en) * 1990-04-06 1991-07-23 Mobil Oil Corporation Naphthalene alkylation process
US5191135A (en) * 1991-03-25 1993-03-02 Mobil Oil Corporation Aromatics alkylation process
US5177284A (en) * 1991-05-28 1993-01-05 Mobil Oil Corporation Catalysts/process to synthesize alkylated naphthalene synthetic fluids with increased alpha/beta isomers for improving product qualities
US5191134A (en) * 1991-07-18 1993-03-02 Mobil Oil Corporation Aromatics alkylation process

Also Published As

Publication number Publication date
JPH09507847A (ja) 1997-08-12
DE69431539D1 (de) 2002-11-14
TW300880B (es) 1997-03-21
AU675612B2 (en) 1997-02-06
DE69426891T2 (de) 2001-06-21
US5457254A (en) 1995-10-10
WO1995018083A1 (en) 1995-07-06
EP0737175B1 (en) 2001-03-14
DE69426891D1 (de) 2001-04-19
EP1020417B1 (en) 2002-10-09
EP1020417A1 (en) 2000-07-19
CA2174513A1 (en) 1995-07-06
JP3832849B2 (ja) 2006-10-11
AU1515995A (en) 1995-07-17
EP0737175A1 (en) 1996-10-16
DE69431539T2 (de) 2003-02-13
ES2154724T3 (es) 2001-04-16
EP0737175A4 (en) 1997-05-07

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