ES2185445A1 - Flexible method for producing base oil and middle distillate by hydroisomerization reformation accompanying catalytic deparaffinization treatment - Google Patents

Flexible method for producing base oil and middle distillate by hydroisomerization reformation accompanying catalytic deparaffinization treatment

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Publication number
ES2185445A1
ES2185445A1 ES200001084A ES200001084A ES2185445A1 ES 2185445 A1 ES2185445 A1 ES 2185445A1 ES 200001084 A ES200001084 A ES 200001084A ES 200001084 A ES200001084 A ES 200001084A ES 2185445 A1 ES2185445 A1 ES 2185445A1
Authority
ES
Spain
Prior art keywords
hydroisomerization
reformation
base oil
middle distillate
catalytic dewaxing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200001084A
Other languages
Spanish (es)
Other versions
ES2185445B1 (en
Inventor
Eric Benazzi
Nathalie Marchal-George
Tivadar Cseri
Pierre Marion
Christophe Gueret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
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Filing date
Publication date
Priority claimed from FR9905494A external-priority patent/FR2792945B1/en
Priority claimed from FR0002364A external-priority patent/FR2805543B1/en
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of ES2185445A1 publication Critical patent/ES2185445A1/en
Application granted granted Critical
Publication of ES2185445B1 publication Critical patent/ES2185445B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
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    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Procedimiento flexible de producción de bases de aceites y destilados medios con una conversión-hidroisomerización seguida de un desparafinado catalítico. La invención se refiere a un procedimiento, mejorado, de fabricación de aceites de base de muy alta calidad y de producción simultánea de destilados medios de alta calidad, que comprende las etapas sucesivas de hidroisomerización y de desparafinado catalítico. La hidroisomerización se desarrolla en presencia de un catalizador que contiene al menos un metal noble depositado sobre un soporte ácido amorfo, siendo la dispersión en metal de 20-100%. Preferentemente, el soporte es un sílice-alúmina amorfa. El desparafinado catalítico se desarrolla en presencia de un catalizador que contiene al menos un elemento hidro- deshidrogenante (grupo VII) y al menos un tamiz molecular (zeolita preferida). Preferentemente, el tamiz es elegido entre la zeolita NU-10, EU-1, EU-13 y ferrierita.Flexible process for the production of oil bases and medium distillates with a conversion-hydroisomerization followed by catalytic dewaxing. The invention relates to an improved process for the manufacture of very high-quality base oils and for the simultaneous production of high-quality middle distillates, comprising the successive steps of hydroisomerization and catalytic dewaxing. Hydroisomerization is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acid support, the dispersion in metal being 20-100%. Preferably, the support is an amorphous silica-alumina. The catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VII) and at least one molecular sieve (preferred zeolite). Preferably, the screen is chosen from zeolite NU-10, EU-1, EU-13 and ferrierite.

ES200001084A 1999-04-29 2000-04-27 FLEXIBLE PROCEDURE FOR PRODUCTION OF OIL BASES AND MEDIUM DISTILLATES WITH A CONVERSION-HYDROISOMERIZATION FOLLOWED BY A CATALYTIC DEPARAFINING. Expired - Fee Related ES2185445B1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR9905494A FR2792945B1 (en) 1999-04-29 1999-04-29 PROCESS FOR PRODUCING OIL BASES AND MEDIUM DISTILLATES WITH CONVERSION-HYDROISOMERIZATION FOLLOWED BY CATALYTIC DEPARAFFINING
FR99/05494 1999-04-29
FR0002364A FR2805543B1 (en) 2000-02-24 2000-02-24 FLEXIBLE PROCESS FOR PRODUCING MEDIUM OIL BASES AND DISTILLATES WITH A HYDROISOMERIZATION CONVERSION FOLLOWED BY CATALYTIC DEPAINTING
FR00/02364 2000-02-24

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KR20000071874A (en) 2000-11-25
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NL1015036A1 (en) 2000-10-31
NL1015036C2 (en) 2001-02-12

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