ES2186224T3 - Componentes y catalizadores para la polimerizacion de olefinas. - Google Patents

Componentes y catalizadores para la polimerizacion de olefinas.

Info

Publication number
ES2186224T3
ES2186224T3 ES98945242T ES98945242T ES2186224T3 ES 2186224 T3 ES2186224 T3 ES 2186224T3 ES 98945242 T ES98945242 T ES 98945242T ES 98945242 T ES98945242 T ES 98945242T ES 2186224 T3 ES2186224 T3 ES 2186224T3
Authority
ES
Spain
Prior art keywords
rent
olefins
polymerization
cyclealkyl
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98945242T
Other languages
English (en)
Inventor
Giampiero Morini
Yuri V Gulevich
Giulio Balbontin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
Original Assignee
Basell Poliolefine Italia SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Italia SRL filed Critical Basell Poliolefine Italia SRL
Application granted granted Critical
Publication of ES2186224T3 publication Critical patent/ES2186224T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

ESTA INVENCION SE REFIERE A UNOS CONSTITUYENTES SOLIDOS DE CATALIZADOR PARA LA POLIMERIZACION DE OLEFINAS CH 2 = CHR, DONDE R ES HIDROGENO O BIEN UN RADICAL HIDROCARBILO QUE TIENE DE 1 A 12 ATOMOS DE CARBONO, QUE COMPRENDEN TI, MG, UN HALOGENO Y UN COMPUESTO DONADOR DE ELECTRONES ESCOGIDO ENTRE CIANOESTERES DE FORMULA (I). EN DICHA FORMULA, R 1 ES UN G RUPO ALQUILO, ALQUENILO, CICLOALQUILO, CICLOALQUILALQUILO, ALQUILCICLOALQUILO, ARILO, ARILALQUILO, O ALQUILARILO C 1 - C 20 LINEAL O RAMIFICADO; N VALE 0, 1, 2 O 3. R 2 , R 3 , R 4 Y R 5 SE ESCOGEN INDEPENDIENTEMENTE ENTRE EL HIDROGENO O GRUPOS ALQUILO, ALQUENILO, CICLOALQUILO, CICLOALQUILALQUILO, ALQUILCICLOALQUILO, ARILO, ARILALQUILO O ALQUILARILO C 1 -C 20 LINEALES O RAMIFICA DOS; DOS O MAS DE DOS ELEMENTOS ENTRE R 2 Y R 3 , Y R 4 Y R 5 PUEDEN ESTAR UNIDOS PARA FORMAR UN CICLO. CUANDO SE USAN PARA LA POLIMERIZACION DE OLEFINAS, LOS CONSTITUYENTES DE CATALIZADOR CONSIDERADOS SE CARACTERIZAN POR UNA EXCELENTE RESPUESTA AL HIDROGENO Y POR LACAPACIDAD DE PRODUCIR POLIMEROS QUE TENGAN UN AMPLIO REPARTO DE LOS PESOS MOLECULARES.
ES98945242T 1997-09-03 1998-08-14 Componentes y catalizadores para la polimerizacion de olefinas. Expired - Lifetime ES2186224T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP97202707 1997-09-03

Publications (1)

Publication Number Publication Date
ES2186224T3 true ES2186224T3 (es) 2003-05-01

Family

ID=8228698

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98945242T Expired - Lifetime ES2186224T3 (es) 1997-09-03 1998-08-14 Componentes y catalizadores para la polimerizacion de olefinas.

Country Status (12)

Country Link
US (2) US6143684A (es)
EP (1) EP0938509B1 (es)
JP (1) JP2001505249A (es)
KR (1) KR20000068886A (es)
CN (1) CN1242780A (es)
AR (1) AR017037A1 (es)
AU (1) AU9262498A (es)
BR (1) BR9806141A (es)
CA (1) CA2270239A1 (es)
DE (1) DE69809531T2 (es)
ES (1) ES2186224T3 (es)
WO (1) WO1999011677A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000068886A (ko) * 1997-09-03 2000-11-25 간디 지오프레이 에이치. 올레핀 중합용 성분 및 촉매
US6436864B1 (en) * 1999-10-06 2002-08-20 Sri International Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts
WO2002038628A2 (en) * 2000-11-07 2002-05-16 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith
US7091292B2 (en) 2002-04-24 2006-08-15 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US7060848B2 (en) * 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US6897276B2 (en) * 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
CN1310967C (zh) * 2004-07-01 2007-04-18 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
CN1318457C (zh) * 2004-09-02 2007-05-30 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分和催化剂
EP1794196A2 (en) * 2004-09-22 2007-06-13 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same
US7256296B2 (en) * 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
WO2006066126A2 (en) * 2004-12-16 2006-06-22 Symyx Technologies, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US8281332B2 (en) * 2007-05-02 2012-10-02 Google Inc. Animated video overlays
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
CN101735346B (zh) 2008-11-07 2012-05-30 中国石油天然气股份有限公司 一种丙烯均聚和共聚的催化剂及其制备方法和应用
CN102146145B (zh) * 2010-02-10 2012-11-21 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及催化剂
US8541333B2 (en) 2009-08-13 2013-09-24 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and a catalyst comprising the same
CN101993507B (zh) * 2009-08-13 2012-10-24 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及其催化剂
CN104558292B (zh) * 2013-10-28 2017-05-31 中国石油化工股份有限公司 一种用于烯烃聚合催化剂制备方法
CN107915796B (zh) * 2016-10-09 2021-03-16 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其应用和用于烯烃聚合的催化剂及其应用以及烯烃聚合方法
WO2018161854A1 (zh) 2017-03-10 2018-09-13 北京利和知信科技有限公司 用于烯烃聚合的固体催化剂组分、催化剂及其应用
US10300460B1 (en) 2017-11-17 2019-05-28 Chevron Phillips Chemical Company L.P. Aqueous methods for titanating a chromium/silica catalyst
CN116041577B (zh) 2021-10-28 2024-12-06 中国石油化工股份有限公司 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法
US11912809B2 (en) 2022-06-02 2024-02-27 Chevron Phillips Chemical Company Lp High porosity fluorided silica-coated alumina activator-supports and uses thereof in metallocene-based catalyst systems for olefin polymerization

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK133012C (da) * 1968-11-21 1976-08-09 Montedison Spa Katalysator til polymerisation af alkener
YU35844B (en) * 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
US4507450A (en) * 1976-08-18 1985-03-26 Mitsubishi Chemical Industries Limited Process for preparing polyolefin
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS55116710A (en) * 1979-03-02 1980-09-08 Mitsui Petrochem Ind Ltd Preparation of polymer or copolymer
JPS5630407A (en) * 1979-08-22 1981-03-27 Sumitomo Chem Co Ltd Preparation of highly stereoregular alpha-olefin polymer
US4297465A (en) * 1980-10-29 1981-10-27 Eastman Kodak Company Catalysts for polymerizing propylene in a high temperature solution process
JPS59129210A (ja) * 1983-01-14 1984-07-25 Mitsui Toatsu Chem Inc エチレン−α−オレフイン共重合体の製造方法
IT1230134B (it) * 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
IT1241093B (it) * 1990-03-30 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1262934B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262935B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
US6015867A (en) * 1994-09-28 2000-01-18 Showa Denko K.K. 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin
KR20000068886A (ko) * 1997-09-03 2000-11-25 간디 지오프레이 에이치. 올레핀 중합용 성분 및 촉매

Also Published As

Publication number Publication date
AU9262498A (en) 1999-03-22
KR20000068886A (ko) 2000-11-25
US6143684A (en) 2000-11-07
JP2001505249A (ja) 2001-04-17
EP0938509B1 (en) 2002-11-20
CN1242780A (zh) 2000-01-26
EP0938509A1 (en) 1999-09-01
DE69809531D1 (de) 2003-01-02
AR017037A1 (es) 2001-08-22
US6239236B1 (en) 2001-05-29
WO1999011677A1 (en) 1999-03-11
CA2270239A1 (en) 1999-03-11
DE69809531T2 (de) 2003-07-10
BR9806141A (pt) 1999-10-26

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