ES2190657T3 - Inhibicion de la polimerizacion de monomeros de estireno utilizando dihidroxiarenos y nitroxidos sustituidos. - Google Patents
Inhibicion de la polimerizacion de monomeros de estireno utilizando dihidroxiarenos y nitroxidos sustituidos.Info
- Publication number
- ES2190657T3 ES2190657T3 ES99944100T ES99944100T ES2190657T3 ES 2190657 T3 ES2190657 T3 ES 2190657T3 ES 99944100 T ES99944100 T ES 99944100T ES 99944100 T ES99944100 T ES 99944100T ES 2190657 T3 ES2190657 T3 ES 2190657T3
- Authority
- ES
- Spain
- Prior art keywords
- dihidroxiarenos
- nitroxides
- replaced
- styrene monomers
- inhibiting polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title abstract 4
- -1 nitroxides Chemical class 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 230000002401 inhibitory effect Effects 0.000 title 1
- 239000000178 monomer Substances 0.000 title 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Una composición para la inhibición de la polimerización de compuestos aromáticos de vinilo que comprende: un dihidroxiareno; un agente de transferencia de hidrógeno; y un nitróxido estable.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15048898A | 1998-09-09 | 1998-09-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2190657T3 true ES2190657T3 (es) | 2003-08-01 |
Family
ID=22534761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99944100T Expired - Lifetime ES2190657T3 (es) | 1998-09-09 | 1999-09-08 | Inhibicion de la polimerizacion de monomeros de estireno utilizando dihidroxiarenos y nitroxidos sustituidos. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6284936B2 (es) |
| EP (1) | EP1119533B1 (es) |
| JP (1) | JP2002524430A (es) |
| KR (1) | KR20010079775A (es) |
| AT (1) | ATE230714T1 (es) |
| AU (1) | AU760809B2 (es) |
| BR (1) | BR9913523A (es) |
| CA (1) | CA2342945A1 (es) |
| DE (1) | DE69904848T2 (es) |
| ES (1) | ES2190657T3 (es) |
| NO (1) | NO20011017L (es) |
| TW (1) | TW544447B (es) |
| WO (1) | WO2000014039A1 (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE307789T1 (de) | 1999-12-02 | 2005-11-15 | Crompton Corp | Polymerisationsinhibierung von ungesättigten monomeren |
| ES2292487T3 (es) * | 1999-12-03 | 2008-03-16 | Chemtura Corporation | Composicion y metodo para inhibir la polimerizacion y el crecimiento polimerico. |
| US6761833B2 (en) * | 2001-03-20 | 2004-07-13 | Atofina Chemicals, Inc. | Stabilization of monomers by compositions based on alkylhydroxylamines |
| EP1383722B1 (en) * | 2001-04-30 | 2006-12-06 | Baker Hughes Incorporated | Inhibition of popcorn polymer growth |
| US6579442B2 (en) * | 2001-05-22 | 2003-06-17 | Ge Betz, Inc. | Methods and compositions for inhibiting polymerization of vinyl monomers |
| CA2565556A1 (en) * | 2004-05-03 | 2005-12-08 | Neosil, Inc. | Polycationic antimicrobial therapeutic |
| JP5675184B2 (ja) * | 2010-06-18 | 2015-02-25 | 伯東株式会社 | ビニル化合物の重合防止剤組成物ならびにこれを用いたビニル化合物の重合防止方法 |
| KR101532990B1 (ko) * | 2011-09-22 | 2015-07-01 | 도요 고무 고교 가부시키가이샤 | 연마 패드 |
| MY167438A (en) * | 2011-11-29 | 2018-08-28 | Dorf Ketal Chemicals India Private Ltd | Amine based additive composition for control and inhibition of polymerization of styrene, and method of use thereof |
| BR112014013283B1 (pt) * | 2011-12-02 | 2020-05-12 | Dorf Ketal Chemicals (I) Private Limited | Composto aditivo baseado em amina e nitróxido para o controle e inibição da polimerização do estireno, e método de utilização do mesmo |
| US9944577B2 (en) * | 2012-10-25 | 2018-04-17 | Baker Hughes, A Ge Company, Llc | Hydroquinone compounds for inhibiting monomer polymerization |
| US9611336B2 (en) | 2012-10-25 | 2017-04-04 | Baker Hughes Incorporated | Quinone compounds for inhibiting monomer polymerization |
| TWI686380B (zh) | 2014-10-14 | 2020-03-01 | 美商藝康美國公司 | 在丙烯酸酯/甲基丙烯酸酯方法中降低聚合物結垢及黏聚 |
| RU2715559C2 (ru) | 2015-03-18 | 2020-03-02 | ЭКОЛАБ ЮЭсЭй ИНК. | Применение стабильных липофильных соединений гидроксиламина для ингибирования полимеризации виниловых мономеров |
| US9957209B2 (en) | 2015-03-31 | 2018-05-01 | Ecolab Usa Inc. | Use of quinone methides as antipolymerants for vinylic monomers |
| RU2746125C2 (ru) | 2015-04-20 | 2021-04-07 | ЭКОЛАБ ЮЭсЭй ИНК. | Пространственно затрудненные гидрохиноны в качестве средств, предохраняющих от обрастания, в отношении ненасыщенных мономеров |
| US20170158621A1 (en) * | 2015-12-04 | 2017-06-08 | Baker Hughes Incorporated | Substituted phenol derivatives for mitigating fouling |
| US12319650B2 (en) | 2022-02-23 | 2025-06-03 | Totalenergies Onetech | Cleaning process of a vinyl aromatic compounds distillation unit and processes including such cleaning process |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3800002A (en) * | 1970-03-20 | 1974-03-26 | Japan Synthetic Rubber Co Ltd | Process for preventing the polymerization of conjugated dienes |
| US4670131A (en) * | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
| US4654450A (en) * | 1986-02-24 | 1987-03-31 | Atlantic Richfield Company | Inhibiting polymerization of vinyl aromatic monomers |
| US4774374A (en) * | 1987-06-12 | 1988-09-27 | Uniroyal Chemical Company, Inc. | Stabilized vinyl aromatic composition |
| US5189086A (en) * | 1989-03-21 | 1993-02-23 | Ciba-Geigy Corporation | Polysubstituted N-hydrocarbyloxy hindered amine light stabilizers |
| US5359069A (en) * | 1989-03-21 | 1994-10-25 | Ciba-Geigy Corporation | Non-migrating 1-hydrocarbyloxy hindered amine derivatives as polymer stabilizers |
| US5157175A (en) * | 1991-09-09 | 1992-10-20 | Nalco Chemical Company | Composition and method for inhibition of styrene polymerization |
| JPH05156068A (ja) * | 1991-12-06 | 1993-06-22 | Mitsui Toatsu Chem Inc | 多孔性重合体粒子の製造方法 |
| US5254760A (en) * | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
| US5728872A (en) * | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
| US5888356A (en) * | 1994-08-19 | 1999-03-30 | Huels Aktiengesellschaft | Inhibition of polymerization of vinylaromatic or vinylaliphatic |
| US5545786C1 (en) * | 1994-11-28 | 2001-10-16 | Ciba Geigy Corp | Method for inhibiting premature polymerization of vinyl aromatic monomers |
| US5616774A (en) * | 1995-04-14 | 1997-04-01 | Ciba-Geigy Corporation | Inhibition of unsaturated monomers with 7-aryl quinone methides |
| US5583247A (en) * | 1995-04-14 | 1996-12-10 | Ciba-Geigy Corporation | 7-substituted quinone methides as inhibitors for unsaturated monomers |
| US6025515A (en) * | 1995-06-07 | 2000-02-15 | Baker Hughes Incorporated | Use of substituted phenols to inhibit polymer formation during the manufacture of acrylonitrile |
| EP0791573A1 (en) * | 1996-02-21 | 1997-08-27 | Nalco/Exxon Chemicals Company L.P. | Nitroxides as antipolymerants for vinyl acetate units |
| US5659095A (en) * | 1996-03-13 | 1997-08-19 | Uniroyal Chemical Company, Inc. | Composition for inhibiting the polymerization of aromatic vinyl monomers |
| DE19638868A1 (de) * | 1996-09-23 | 1998-03-26 | Basf Ag | Stabilisierte Monomerenzusammensetzung |
| US5844025A (en) * | 1996-12-02 | 1998-12-01 | Ciba Specialty Chemicals Corporation | 1,2-Bis-adducts of stable nitroxides with substituted ethylenes and stabilized compositions |
| DE19723890A1 (de) * | 1997-06-06 | 1998-12-10 | Consortium Elektrochem Ind | Verfahren zur Herstellung von aromatischen und heteroaromatischen Aldehyden und Ketonen |
| US5910232A (en) * | 1998-06-10 | 1999-06-08 | Nalco/Exxon Energy Chemicals, L.P. | Method for inhibiting polymer formation in styrene processing |
-
1999
- 1999-09-08 ES ES99944100T patent/ES2190657T3/es not_active Expired - Lifetime
- 1999-09-08 EP EP99944100A patent/EP1119533B1/en not_active Expired - Lifetime
- 1999-09-08 AT AT99944100T patent/ATE230714T1/de not_active IP Right Cessation
- 1999-09-08 WO PCT/US1999/020529 patent/WO2000014039A1/en not_active Ceased
- 1999-09-08 DE DE69904848T patent/DE69904848T2/de not_active Expired - Fee Related
- 1999-09-08 AU AU57059/99A patent/AU760809B2/en not_active Ceased
- 1999-09-08 CA CA002342945A patent/CA2342945A1/en not_active Abandoned
- 1999-09-08 KR KR1020017003033A patent/KR20010079775A/ko not_active Ceased
- 1999-09-08 BR BR9913523-0A patent/BR9913523A/pt not_active IP Right Cessation
- 1999-09-08 JP JP2000568799A patent/JP2002524430A/ja not_active Withdrawn
- 1999-09-29 TW TW088115575A patent/TW544447B/zh not_active IP Right Cessation
-
2000
- 2000-12-21 US US09/746,975 patent/US6284936B2/en not_active Expired - Lifetime
-
2001
- 2001-02-27 NO NO20011017A patent/NO20011017L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1119533B1 (en) | 2003-01-08 |
| EP1119533A1 (en) | 2001-08-01 |
| JP2002524430A (ja) | 2002-08-06 |
| AU5705999A (en) | 2000-03-27 |
| US20010003360A1 (en) | 2001-06-14 |
| NO20011017L (no) | 2001-04-23 |
| KR20010079775A (ko) | 2001-08-22 |
| DE69904848T2 (de) | 2003-11-06 |
| ATE230714T1 (de) | 2003-01-15 |
| CA2342945A1 (en) | 2000-03-16 |
| US6284936B2 (en) | 2001-09-04 |
| AU760809B2 (en) | 2003-05-22 |
| WO2000014039A1 (en) | 2000-03-16 |
| TW544447B (en) | 2003-08-01 |
| DE69904848D1 (de) | 2003-02-13 |
| BR9913523A (pt) | 2001-06-05 |
| NO20011017D0 (no) | 2001-02-27 |
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