ES2191129T3 - Composicion catalitica y su utilizacion en la polimerizacion de olefinas. - Google Patents

Composicion catalitica y su utilizacion en la polimerizacion de olefinas.

Info

Publication number
ES2191129T3
ES2191129T3 ES97103834T ES97103834T ES2191129T3 ES 2191129 T3 ES2191129 T3 ES 2191129T3 ES 97103834 T ES97103834 T ES 97103834T ES 97103834 T ES97103834 T ES 97103834T ES 2191129 T3 ES2191129 T3 ES 2191129T3
Authority
ES
Spain
Prior art keywords
solid
prepolymer
olefin polymerization
catalyst
catalytic composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97103834T
Other languages
English (en)
Inventor
Jean Malinge
Claude Brun
Jean-Loup Lacombe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atofina SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina SA filed Critical Atofina SA
Application granted granted Critical
Publication of ES2191129T3 publication Critical patent/ES2191129T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCEDIMIENTO DE FABRICACION DE UN COMPONENTE CATALITICO SOLIDO PARA LA POLIMERIZACION O COPOLIMERIZACION DE LAS OLEFINAS, QUE LLEVAN A UN POLIMERO O COPOLIMERO A LA DISTRIBUCION DE LAS MASAS MOLECULARES ENSANCHADAS. EL PROCEDIMIENTO COMPRENDE UNA PRIMERA ETAPA QUE COMPRENDE UNA PUESTA EN CONTACTO ENTRE A) UN SOPORTE SOLIDO QUE COMPRENDE EN SU SUPERFICIE AL MENOS 5 GRUPOS HIDROXILOS POR NANOMETRO CUADRADO (OH/NM{SUP,2}) Y B) UN DERIVADO ORGANICO DEL MAGNESIO, Y EVENTUALMENTE, PREFERENTEMENTE, C) UN ALUMINOXANO, PARA OBTENER UN PRIMER SOLIDO, Y A CONTINUACION UNA SEGUNDA ETAPA QUE COMPRENDE UNA PUESTA EN CONTACTO ENTRE EL PRIMER SOLIDO Y UN AGENTE CLORANTE PARA OBTENER UN SEGUNDO SOLIDO, Y EN UNA ETAPA POSTERIOR, UNA IMPREGNACION DEL SEGUNDO SOLIDO POR UN DERIVADO DE UN METAL DE TRANSICION.
ES97103834T 1996-04-02 1997-03-07 Composicion catalitica y su utilizacion en la polimerizacion de olefinas. Expired - Lifetime ES2191129T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9604109A FR2746672B1 (fr) 1996-04-02 1996-04-02 Composante catalytique et son utilisation en polymerisation des olefines

Publications (1)

Publication Number Publication Date
ES2191129T3 true ES2191129T3 (es) 2003-09-01

Family

ID=9490811

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97103834T Expired - Lifetime ES2191129T3 (es) 1996-04-02 1997-03-07 Composicion catalitica y su utilizacion en la polimerizacion de olefinas.

Country Status (11)

Country Link
US (2) US6433108B1 (es)
EP (1) EP0799840B1 (es)
JP (2) JP3034219B2 (es)
KR (1) KR100228556B1 (es)
CN (2) CN1117772C (es)
AT (1) ATE231888T1 (es)
CA (1) CA2201390C (es)
DE (1) DE69718696T2 (es)
ES (1) ES2191129T3 (es)
FR (1) FR2746672B1 (es)
NO (1) NO315518B1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0112706B1 (pt) * 2000-07-24 2016-01-19 Sasol Tech Pty Ltd métodos para formar um precursor de catalisador de fischer-tropsch, e, método para formar um catalisador de fischer-tropsch
KR20020050892A (ko) * 2000-12-22 2002-06-28 유현식 폴리올레핀 나노복합체
KR100426123B1 (ko) 2001-07-04 2004-04-08 주식회사 엘지화학 내후성 열가소성 수지의 제조방법
EP1403292B1 (en) * 2002-09-30 2016-04-13 Borealis Polymers Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
JP4398826B2 (ja) * 2003-09-25 2010-01-13 テクノポリマー株式会社 帯電防止性熱可塑性樹脂組成物及びそれを用いた成形品
KR100466502B1 (ko) * 2003-10-17 2005-01-15 (주) 디엔에프솔루션 넓은 분자량 분포 특성을 갖는 폴리에틸렌 제조용 실리카담지 중합 촉매 및 그의 제조방법
US6962889B2 (en) * 2004-01-28 2005-11-08 Engelhard Corporation Spherical catalyst for olefin polymerization
WO2008124127A1 (en) * 2007-04-09 2008-10-16 The Regents Of The University Of California Soft and strong elastomeric compositions from semicrystalline-amorphous polyolefin block copolymers
KR101691690B1 (ko) 2013-08-26 2017-01-02 유세환 벽돌 조적용 연결구
CN104084184B (zh) * 2014-06-12 2016-05-04 陕西师范大学 半导体光催化剂钛酸镁钠的制备方法及应用
HUE049864T2 (hu) * 2014-07-31 2020-10-28 Versalis Spa Alfa-olefinek (ko)polimerizálására szolgáló szilárd katalizátor és annak elõállítási folyamata
CN105881313A (zh) * 2015-04-03 2016-08-24 牟少奇 防二次污染且带有夹持杆和固持装置的医疗器械夹具
KR102219802B1 (ko) 2019-07-09 2021-02-24 이승구 조적벽돌 결합구조
KR102342247B1 (ko) 2019-08-08 2021-12-22 이승구 조적벽돌 결합구조

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ192572A (en) 1979-01-10 1981-11-19 Ici Ltd Catalyst component and olefine polymerisation catalyst containing this component
EP0032308A3 (en) 1980-01-10 1981-08-05 Imperial Chemical Industries Plc Ethylene polymerisation process
US4481301A (en) * 1981-12-04 1984-11-06 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
FR2546522B1 (fr) * 1983-05-25 1985-07-26 Ato Chimie Procede de preparation d'une composante de metal de transition pour un systeme catalytique de polymerisation d'olefines
US4554265A (en) * 1984-06-29 1985-11-19 Exxon Research & Engineering Co. Polymerization catalyst
JPH0655780B2 (ja) 1984-07-09 1994-07-27 東燃株式会社 オレフイン重合用触媒成分
FR2596396B1 (fr) * 1986-03-27 1988-11-18 Atochem Support spherique de catalyseur pour la polymerisation des alpha-olefines catalyseurs obtenus a partir de ces supports
DE3766342D1 (de) * 1986-06-16 1991-01-03 Tonen Corp Verfahren zur herstellung eines aethylen-propylen-copolymerkautschuks.
FR2616789B1 (fr) 1987-06-16 1991-07-26 Atochem Procede de traitement de composante catalytique sur support d'oxyde metallique poreux pour la polymerisation des olefines en phase gazeuse. application du catalyseur obtenu a la polymerisation des olefines
IT1227240B (it) * 1988-09-29 1991-03-27 Enichem Anic Spa Procedimento per la polimerizzazione dell'etilene e perla copolimerizzazione dell'etilene con alfa-olefine e catalizzatore relativo
IT1245250B (it) 1991-03-27 1994-09-13 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
FR2680792B1 (fr) * 1991-08-30 1994-09-09 Bp Chemicals Snc Procede de fabrication d'un polymere de l'ethylene.
FR2680793B1 (fr) * 1991-08-30 1994-09-09 Bp Chemicals Snc Procede de fabrication d'un polymere de l'ethylene.
US5210167A (en) * 1991-11-25 1993-05-11 Mobil Oil Corporation LLDPE films with improved optical properties
ES2163404T3 (es) * 1993-04-07 2002-02-01 Atofina Res Procedimiento para la produccion de poliolefinas y catalizador poliolefinico.
JP3549614B2 (ja) * 1995-05-09 2004-08-04 三井化学株式会社 エチレン系重合体組成物
FR2734570B1 (fr) 1995-05-22 1997-07-04 Bp Chemicals Snc Procede de preparation d'un catalyseur de type ziegler-natta

Also Published As

Publication number Publication date
JP3034219B2 (ja) 2000-04-17
DE69718696T2 (de) 2003-10-16
JPH11236414A (ja) 1999-08-31
EP0799840A1 (fr) 1997-10-08
ATE231888T1 (de) 2003-02-15
KR100228556B1 (ko) 1999-11-01
NO971377L (no) 1997-10-03
US20020147284A1 (en) 2002-10-10
NO315518B1 (no) 2003-09-15
CA2201390A1 (fr) 1997-10-02
JPH1036425A (ja) 1998-02-10
CN1400225A (zh) 2003-03-05
CA2201390C (fr) 2002-05-14
US6433108B1 (en) 2002-08-13
CN1166497A (zh) 1997-12-03
KR970069127A (ko) 1997-11-07
NO971377D0 (no) 1997-03-24
FR2746672B1 (fr) 1998-04-24
DE69718696D1 (de) 2003-03-06
FR2746672A1 (fr) 1997-10-03
CN1117772C (zh) 2003-08-13
US6555642B2 (en) 2003-04-29
EP0799840B1 (fr) 2003-01-29

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