ES2191282T3 - Procedimiento para purificar trihidrocarbilfosfinas usando metanol. - Google Patents

Procedimiento para purificar trihidrocarbilfosfinas usando metanol.

Info

Publication number
ES2191282T3
ES2191282T3 ES98908508T ES98908508T ES2191282T3 ES 2191282 T3 ES2191282 T3 ES 2191282T3 ES 98908508 T ES98908508 T ES 98908508T ES 98908508 T ES98908508 T ES 98908508T ES 2191282 T3 ES2191282 T3 ES 2191282T3
Authority
ES
Spain
Prior art keywords
methanol
mol
trihydrocarbylphosphine
trihydrocarbylphosphins
purify
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98908508T
Other languages
English (en)
Inventor
Tse-Chong Wu
K Pushpananda A Senaratne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albemarle Corp
Original Assignee
Albemarle Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Corp filed Critical Albemarle Corp
Application granted granted Critical
Publication of ES2191282T3 publication Critical patent/ES2191282T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5095—Separation; Purification; Stabilisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)

Abstract

Un procedimiento para la purificación de trihidrocarbilfosfina con al menos un grupo arilo y al menos un grupo alquilo o cicloalquilo en la molécula, a partir de una masa de reacción que comprende la trihidrocarbilfosfina, comprendiendo el procedimiento cristalizar la masa de reacción utilizando un disolvente constituido esencialmente por metanol. El procedimiento proporciona una producción inesperadamente eficaz de compuestos de trihidrocarbilfosfina con purezas de al menos el 97% en moles, y más preferiblemente de al menos aproximadamente el 99% en moles. Es otra realización de la invención una neomentildifenilfosfina con una pureza de al menos el 97% en moles producida mediante cristalización de neomentildifenilfosfina con una pureza inferior al 97% en moles, utilizando un disolvente constituido esencialmente por metanol.
ES98908508T 1997-02-10 1998-02-09 Procedimiento para purificar trihidrocarbilfosfinas usando metanol. Expired - Lifetime ES2191282T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US79706797A 1997-02-10 1997-02-10

Publications (1)

Publication Number Publication Date
ES2191282T3 true ES2191282T3 (es) 2003-09-01

Family

ID=25169806

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98908508T Expired - Lifetime ES2191282T3 (es) 1997-02-10 1998-02-09 Procedimiento para purificar trihidrocarbilfosfinas usando metanol.

Country Status (5)

Country Link
EP (1) EP0970094B1 (es)
CA (1) CA2278767A1 (es)
DE (1) DE69810758T2 (es)
ES (1) ES2191282T3 (es)
WO (1) WO1998034941A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5994587A (en) * 1997-02-10 1999-11-30 Albemarle Corporation Process for purifying neomenthyldiphenylphosphine using methanol
JP2004527484A (ja) * 2001-01-31 2004-09-09 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エチレン性不飽和化合物のカルボニル化方法、その方法において使用される二座ジホスフィン組成物、およびその二座ジホスフィン組成物の調製方法
CN110885343A (zh) * 2019-12-11 2020-03-17 聊城大学 一种薄荷基双碳、磷手性叔膦衍生物、其制备方法及应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1066261A (en) * 1964-01-14 1967-04-26 Ilford Ltd Photographic materials
US3644536A (en) * 1969-09-18 1972-02-22 Pennwalt Corp Process for 1 3 5-tris(alpha-hydroxy-isopropyl)benzene
GB2097795B (en) * 1981-05-01 1984-08-01 Johnson Matthey Plc Recovering triaryl phosphine from poisoned thodium catalyst systems
US5710340A (en) * 1996-04-29 1998-01-20 Albemarle Corporation Synthesis of cycloalkyldiarylphosophines

Also Published As

Publication number Publication date
DE69810758D1 (de) 2003-02-20
EP0970094B1 (en) 2003-01-15
WO1998034941A1 (en) 1998-08-13
EP0970094A1 (en) 2000-01-12
CA2278767A1 (en) 1998-08-13
DE69810758T2 (de) 2003-10-23

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