ES2192883T3 - Procedimiento para la realizacion de reacciones gas-liquido y reactor de circulacion para el mismo. - Google Patents

Procedimiento para la realizacion de reacciones gas-liquido y reactor de circulacion para el mismo.

Info

Publication number
ES2192883T3
ES2192883T3 ES99969074T ES99969074T ES2192883T3 ES 2192883 T3 ES2192883 T3 ES 2192883T3 ES 99969074 T ES99969074 T ES 99969074T ES 99969074 T ES99969074 T ES 99969074T ES 2192883 T3 ES2192883 T3 ES 2192883T3
Authority
ES
Spain
Prior art keywords
reactor
circulation
chambers
gas
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99969074T
Other languages
English (en)
Inventor
Rudiger Schutte
Hubertus Eickhoff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1998141843 external-priority patent/DE19841843A1/de
Application filed by Degussa GmbH filed Critical Degussa GmbH
Application granted granted Critical
Publication of ES2192883T3 publication Critical patent/ES2192883T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/022—Preparation from organic compounds
    • C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32—Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/34—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2453—Plates arranged in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2458—Flat plates, i.e. plates which are not corrugated or otherwise structured, e.g. plates with cylindrical shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2459—Corrugated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2481—Catalysts in granular from between plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2497—Size aspects, i.e. concrete sizes are being mentioned in the classified document
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2498—Additional structures inserted in the channels, e.g. plates, catalyst holding meshes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32206—Flat sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/3221—Corrugated sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32213—Plurality of essentially parallel sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32255—Other details of the sheets
    • B01J2219/32262—Dimensions or size aspects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B01J2219/32475—Composition or microstructure of the elements comprising catalytically active material involving heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/33—Details relating to the packing elements in general
    • B01J2219/3306—Dimensions or size aspects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/332—Details relating to the flow of the phases
    • B01J2219/3322—Co-current flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/332—Details relating to the flow of the phases
    • B01J2219/3325—Counter-current flow

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

Procedimiento para la realización de reacciones gas-líquido, en el que una fase líquida, que representa un componente de reacción o que contiene uno de tales en forma disuelta, emulsionada o suspendida, y una fase gaseosa que contiene un gas que va a transformar en presencia o ausencia de un catalizador, son conducidas en la misma dirección de flujo a través de un reactor de circulación que presenta al menos tres cámaras de reactor dispuestas paralelas una junto a otra y en la dirección longitudinal de reactor, concebidas para la misma dirección de circulación y abiertas en la dirección de circulación, cuya relación entre el ancho b y el ancho s de resquicio en el centro es mayor de 3, caracterizado porque se emplea un reactor de circulación, cuyas cámaras de reactor presentan un ancho s de resquicio en el rango de 5 a 100 mm, estando realizada al menos una parte de las paredes que se encuentran entre las cámaras del reactor como placas de intercambiador de calor atravesadas por un medio deintercambio de calor o presentando el reactor al menos una pila de placas formada por placas sencillas que constituyen cámaras paralelas en la dirección de circulación y al menos una pila de placas formada por placas de intercambiador de calor que constituyen cámaras paralelas en la dirección de circulación, y porque la temperatura en las cámaras del reactor es regulada por este medio.
ES99969074T 1998-09-12 1999-08-28 Procedimiento para la realizacion de reacciones gas-liquido y reactor de circulacion para el mismo. Expired - Lifetime ES2192883T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE1998141843 DE19841843A1 (de) 1998-09-12 1998-09-12 Verfahren zur Durchführung von Gas-Flüssig-Reaktionen und Durchflußreaktor hierfür
DE19843574 1998-09-23

Publications (1)

Publication Number Publication Date
ES2192883T3 true ES2192883T3 (es) 2003-10-16

Family

ID=26048824

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99969074T Expired - Lifetime ES2192883T3 (es) 1998-09-12 1999-08-28 Procedimiento para la realizacion de reacciones gas-liquido y reactor de circulacion para el mismo.

Country Status (19)

Country Link
US (1) US6419892B1 (es)
EP (1) EP1123256B1 (es)
JP (1) JP4653310B2 (es)
KR (1) KR100569622B1 (es)
AR (1) AR020429A1 (es)
AT (1) ATE238967T1 (es)
AU (1) AU767574B2 (es)
BR (1) BR9913593B1 (es)
CA (1) CA2340232C (es)
DE (1) DE59905358D1 (es)
ES (1) ES2192883T3 (es)
ID (1) ID29144A (es)
IL (1) IL141170A (es)
MY (1) MY126459A (es)
NZ (1) NZ509764A (es)
PL (1) PL194706B1 (es)
PT (1) PT1123256E (es)
TR (1) TR200100595T2 (es)
WO (1) WO2000015550A1 (es)

Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
DE10042746A1 (de) * 2000-08-31 2002-03-28 Degussa Verfahren und Vorrichtung zum Durchführen von Reaktionen in einem Reaktor mit spaltförmigen Reaktionsräumen
FR2832937B1 (fr) * 2001-12-04 2004-01-16 Technip France Procede et dispositif de reaction chimique entre un gaz et au moins un compose en solution, mis en oeuvre en presence d'un catalyseur solide
CA2532646C (en) * 2003-07-24 2012-09-11 Basf Aktiengesellschaft Reactor for partial oxidation with heat-transfer sheet modules
TWI338590B (en) * 2003-07-24 2011-03-11 Basf Ag Preparation of (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed partial oxidation of c3 and/or c4 precursor compounds in a reactor having thermoplate modules
EP1514594A1 (en) * 2003-09-10 2005-03-16 Methanol Casale S.A. Pseudo-isothermal catalytic reactor
US7357378B2 (en) * 2004-10-18 2008-04-15 Air Prodcuts And Chemicals, Inc. Divided wall exchange column
GB0512120D0 (en) * 2005-06-15 2005-07-20 Johnson Matthey Plc Multi-phase reactions
JP5823384B2 (ja) * 2009-06-05 2015-11-25 ソルヴェイ（ソシエテ アノニム） 多相混合物から液体を分離するための方法
EP2663539B1 (de) * 2011-01-13 2016-07-27 Bayer Intellectual Property GmbH Verfahren zur herstellung von 2,2-difluorethylamin aus 2,2-difluor-1-chlorethan und ammoniak
JP6532193B2 (ja) * 2014-05-20 2019-06-19 国立大学法人 東京大学 表面流下式濃縮装置並びに表面流下式濃縮方法
CN112430188B (zh) * 2020-12-04 2023-07-28 西安联众安科化工有限公司 一种新型加氢技术制备异丙基苯胺的方法

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GB620129A (en) 1945-11-13 1949-03-21 Olaf George Dixon Improvements in and relating to treating gases or vapours with liquids
DE1542089B2 (de) 1951-01-28 1973-08-23 Verfahren zur durchfuehrung kontinuierlicher hydrierungen
DE1055501B (de) 1955-01-11 1959-04-23 Leuna Werke Veb Kolonne fuer Destillations- oder andere Stoffaustauschzwecke
DE1067783B (de) * 1956-09-05 1959-10-29 Joseph Graner Kontakt- und Trennkolonne
US4337231A (en) * 1979-08-07 1982-06-29 Kureha Kagaku Kogyo Kabushiki Kaisha Removal of sulfur dioxide from exhaust gas
SE431532B (sv) 1982-09-08 1984-02-13 Eka Ab Forfarande vid framstellning av veteperoxid
US4428923A (en) 1982-11-09 1984-01-31 Degussa Aktiengesellschaft Continuous process for the production of hydrogen peroxide according to the anthraquinone process
DK156701C (da) * 1987-08-27 1990-01-29 Haldor Topsoe As Fremgangsmaade til gennemfoerelse af heterogene katalytiske kemiske reaktioner
FR2634396B1 (fr) * 1988-07-22 1990-09-14 Inst Francais Du Petrole Procede et appareillage de reformage basse pression des essences avec chauffage par des gaz de fumees
FI82670C (fi) 1989-01-27 1991-04-10 Kemira Oy Foerfarande foer framstaellning av vaeteperoxid.
JPH03181338A (ja) * 1989-12-11 1991-08-07 Gebr Sulzer Ag 触媒エレメントおよび触媒反応用反応器
ATA166091A (de) * 1991-08-23 1996-02-15 Faigle Heinz Kg Füllkörper
FI95457C (fi) * 1994-03-15 1996-02-12 Kemira Chemicals Oy Menetelmä vetyperoksidin valmistamiseksi ja siinä käytettävä reaktori
FI97465C (fi) * 1995-02-10 1996-12-27 Kemira Chemicals Oy Menetelmä vetyperoksidin valmistamiseksi
DE19536971A1 (de) 1995-10-04 1997-04-10 Elwatec Elektrolyse Und Wasser Strömungsreaktor mit kapillaren Strömungskanälen sowie Anlage zur katalytischen Reduzierung von Nitrat und/oder Nitrit in mit Wasserstoff beladenem Wasser sowie Verfahren zum Betreiben der Anlage
DE19611976A1 (de) * 1996-03-26 1997-10-02 Basf Ag Verfahren und Reaktor zur Durchführung von Stoffumwandlungen mit in Flüssigkeiten suspendierten Katalysatoren
DE19808385A1 (de) * 1998-02-27 1999-09-02 Basf Ag Verfahren zur Suspensionshydrierung einer Anthrachinon-Verbindung in einem speziellen Reaktor zur Herstellung von Wasserstoffperoxid

Also Published As

Publication number Publication date
CA2340232C (en) 2009-08-18
AR020429A1 (es) 2002-05-15
PL346531A1 (en) 2002-02-11
KR100569622B1 (ko) 2006-04-11
NZ509764A (en) 2003-04-29
WO2000015550A1 (de) 2000-03-23
PT1123256E (pt) 2003-09-30
TR200100595T2 (tr) 2001-07-23
IL141170A (en) 2004-07-25
PL194706B1 (pl) 2007-06-29
CA2340232A1 (en) 2000-03-23
JP4653310B2 (ja) 2011-03-16
JP2002524255A (ja) 2002-08-06
KR20010079793A (ko) 2001-08-22
DE59905358D1 (de) 2003-06-05
EP1123256A1 (de) 2001-08-16
AU767574B2 (en) 2003-11-20
IL141170A0 (en) 2002-02-10
MY126459A (en) 2006-10-31
US6419892B1 (en) 2002-07-16
ID29144A (id) 2001-08-02
BR9913593B1 (pt) 2011-08-23
EP1123256B1 (de) 2003-05-02
AU5971799A (en) 2000-04-03
BR9913593A (pt) 2001-06-12
ATE238967T1 (de) 2003-05-15

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