ES2192994A1 - Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion. - Google Patents

Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.

Info

Publication number
ES2192994A1
ES2192994A1 ES200200684A ES200200684A ES2192994A1 ES 2192994 A1 ES2192994 A1 ES 2192994A1 ES 200200684 A ES200200684 A ES 200200684A ES 200200684 A ES200200684 A ES 200200684A ES 2192994 A1 ES2192994 A1 ES 2192994A1
Authority
ES
Spain
Prior art keywords
sorbent
separation
carbonation
combustion gases
integrated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200200684A
Other languages
English (en)
Other versions
ES2192994B1 (es
Inventor
Garcia Juan Carlos Abanades
John Oakey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES200200684A priority Critical patent/ES2192994B1/es
Application filed by Consejo Superior de Investigaciones Cientificas CSIC filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to PCT/ES2003/000118 priority patent/WO2003080223A1/es
Priority to CA2479886A priority patent/CA2479886C/en
Priority to JP2003578042A priority patent/JP2005520678A/ja
Priority to EP03712141A priority patent/EP1495794A1/en
Priority to CN038066807A priority patent/CN1642620B/zh
Priority to AU2003216925A priority patent/AU2003216925B2/en
Publication of ES2192994A1 publication Critical patent/ES2192994A1/es
Priority to US10/946,319 priority patent/US20050060985A1/en
Application granted granted Critical
Publication of ES2192994B1 publication Critical patent/ES2192994B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/343—Heat recovery
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Gas Separation By Absorption (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

Procedimiento de combustión con separación integrada de CO{sub,2} mediante carbonatación. Se propone un proceso para la separación de CO{sub,2} de gases de combustión aplicable a puntos de gran emisión (centrales térmicas de cualquier combustible carbonoso). La corriente de CO{sub,2} separada es susceptible de utilización y/o confinamiento en formaciones geológicas. El proceso propuesto pretende reducir los altos costes de separación de CO{sub,2}, que impiden el uso a gran escala de estas opciones de confinamiento de CO{sub,2}, recogidas en los informes del IPCC de la ONU. La invención consiste en poner en contacto los gases de combustión con un sorbente calcáreo (caliza, dolomita calcinadas) a 650-750 C donde se produce la reacción de captura de CO{sub,2} por la rápida carbonatación del sorbente. La regeneración del sorbente se lleva a cabo en otro reactor (calcinador) que trabaja en atmósferas de CO{sub,2} o CO{sub,2}/H{sub,2}O y en a presión igual o inferior a la atmosférica.
ES200200684A 2002-03-22 2002-03-22 Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion. Expired - Fee Related ES2192994B1 (es)

Priority Applications (8)

Application Number Priority Date Filing Date Title
ES200200684A ES2192994B1 (es) 2002-03-22 2002-03-22 Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.
CA2479886A CA2479886C (en) 2002-03-22 2003-03-14 Combustion method with integrated carbon dioxide separation by means of carbonation
JP2003578042A JP2005520678A (ja) 2002-03-22 2003-03-14 炭酸塩化によるｃｏ２の集積的分離を伴う燃焼方法
EP03712141A EP1495794A1 (en) 2002-03-22 2003-03-14 Combustion method with integrated co sb 2 /sb separation by means of carbonation
PCT/ES2003/000118 WO2003080223A1 (es) 2002-03-22 2003-03-14 Procedimiento de combustión con separación integrada de co2 mediante carbonatación
CN038066807A CN1642620B (zh) 2002-03-22 2003-03-14 通过碳化作用进行综合co2分离的燃烧方法
AU2003216925A AU2003216925B2 (en) 2002-03-22 2003-03-14 Combustion method with integrated CO2 separation by means of carbonation
US10/946,319 US20050060985A1 (en) 2002-03-22 2004-09-21 Combustion method with integrated CO2 separation by means of carbonation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200200684A ES2192994B1 (es) 2002-03-22 2002-03-22 Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.

Publications (2)

Publication Number Publication Date
ES2192994A1 true ES2192994A1 (es) 2003-10-16
ES2192994B1 ES2192994B1 (es) 2005-02-16

Family

ID=28051967

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200200684A Expired - Fee Related ES2192994B1 (es) 2002-03-22 2002-03-22 Procedimiento de combustion con separacion integrada de co2 mediante carbonatacion.

Country Status (8)

Country Link
US (1) US20050060985A1 (es)
EP (1) EP1495794A1 (es)
JP (1) JP2005520678A (es)
CN (1) CN1642620B (es)
AU (1) AU2003216925B2 (es)
CA (1) CA2479886C (es)
ES (1) ES2192994B1 (es)
WO (1) WO2003080223A1 (es)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007113364A1 (es) * 2006-03-31 2007-10-11 Consejo Superior De Investigaciones Científicas Procedimiento de precalcinación con producción de co2 puro o fácilmente purificable proveniente de la descomposición de carbonatos
ES2345135A1 (es) * 2007-07-17 2010-09-15 Fundacion Circe- Centro De Investigacion De Recursos Y Consumos Energeticos Dispositivo ciclonico para calcinacion y procedimiento de separacion de co2 usando dicho dispositivo.
ES2370619A1 (es) * 2010-04-27 2011-12-20 Fundación Investigación E Innovación Para El Desarrollo Social Procedimiento para la obtención de hidrogeno, a partir de la biomasa y carbón vegetal.
ES2401294R1 (es) * 2011-06-24 2013-07-11 Consejo Superior Investigacion DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO

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US7618606B2 (en) 2003-02-06 2009-11-17 The Ohio State University Separation of carbon dioxide (CO2) from gas mixtures
AU2003304534A1 (en) 2003-11-14 2004-06-06 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Reactivation of lime-based sorbents by co2 shocking
WO2005046863A1 (en) * 2003-11-14 2005-05-26 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Pre-treatment of lime-based sorbents using hydration
CA2613698C (en) * 2005-06-28 2013-02-05 The Ohio State University Separation of carbon dioxide (co2) from gas mixtures by calcium based reaction separation (cars-co2) process
AU2006303828C1 (en) * 2005-10-21 2011-04-14 Calix Limited System and method for calcination/carbonation cycle processing
CN101378992A (zh) * 2005-10-21 2009-03-04 Calix私人有限公司 材料化合物及其制造方法
US8951493B2 (en) * 2005-10-21 2015-02-10 Calix Ltd. Material compound and a method of fabricating the same
AU2007233570B2 (en) 2006-03-31 2010-11-18 Calix Limited System and method for the calcination of minerals
FR2908327B1 (fr) * 2006-11-09 2009-01-30 Air Liquide Procede de fabrication de clinker a emission de co2 controlee
WO2008097666A1 (en) * 2007-02-10 2008-08-14 Vast Power Portfolio, Llc Hot fluid recovery of heavy oil with steam and carbon dioxide
FR2921059B1 (fr) * 2007-09-14 2011-06-24 Rech S Geol Et Minieres Brgm Bureau De Procede et installation de production de clinker
CN102112205B (zh) * 2008-05-15 2014-09-17 Calix有限公司 用于处理烟道气的系统和方法
EP2296786A4 (en) 2008-06-05 2012-09-19 Ind Res Ltd METHOD FOR SEPARATING GAS
DE102008050816B4 (de) 2008-10-08 2013-09-05 Alstom Technology Ltd. Verfahren und Anordnung zur Abscheidung von CO2 aus Verbrennungsabgas
ES2339733B1 (es) 2008-11-21 2011-03-15 Union Fenosa Generacion, S.A. Procedimiento y dispositivo para la combustion de biomasa sin emisionde dioxido de carbono.
FR2944217B1 (fr) * 2009-04-08 2011-04-01 Inst Francais Du Petrole Procede de captage du dioxyde de carbone avec integration thermique de la regeneration avec la chaine de compression
DE102009039055A1 (de) * 2009-08-28 2011-03-10 Technische Universität Darmstadt Verfahren und Einrichtung zur Abscheidung von CO2 aus Abgas
CN102575178B (zh) * 2009-09-18 2014-12-10 沃姆瑟能源解决方案公司 带有焦炭制备系统的整体煤气化联合循环装置
WO2011047409A1 (en) * 2009-10-24 2011-04-28 Calix Limited System and method for processing an input fuel gas and steam to produce carbon dioxide and an output fuel gas
US8647413B2 (en) * 2009-10-30 2014-02-11 General Electric Company Spray process for the recovery of CO2 from a gas stream and a related apparatus
WO2013037938A1 (en) 2011-09-15 2013-03-21 Energy Knowledge Group Bv Process for the preparation of biofuel using algae
KR101863967B1 (ko) * 2011-09-30 2018-06-04 한국전력공사 저에너지 소비형 이산화탄소의 회수방법
NO343140B1 (no) * 2013-06-14 2018-11-19 Zeg Power As Fremgangsmåte for bærekraftig energiproduksjon i et kraftverk som omfatter en fastoksid brenselcelle
US9586827B2 (en) 2013-09-06 2017-03-07 David LeRoy Hagen CO2 producing calciner
TWI516302B (zh) * 2013-12-11 2016-01-11 財團法人工業技術研究院 循環塔二氧化碳捕獲系統、碳酸化爐、煅燒爐及其使用方法
KR101529823B1 (ko) * 2014-05-21 2015-06-29 현대중공업 주식회사 석탄가스화 복합발전 시스템
EP2959966B1 (en) * 2014-06-24 2018-09-05 General Electric Technology GmbH A calciner and a method for calcination of a carbon dioxide rich sorbent
CN104841363A (zh) * 2015-04-22 2015-08-19 马鞍山市顺达环保设备有限公司 一种矿热炉用吸附剂及其制备方法
US9956517B2 (en) * 2016-05-23 2018-05-01 General Electric Company Gmbh System and method for reducing carbon dioxide emissions from a flue gas generated via combusting a fossil fuel
CN106595363B (zh) * 2016-12-09 2018-10-23 南京工业大学 高温钙循环热化学储能方法及系统
US11738307B2 (en) 2017-03-09 2023-08-29 Hot Lime Labs Limited Method and apparatus for carbon dioxide capture and release
CN108619896B (zh) * 2018-05-16 2023-11-21 安徽建筑大学 一种基于切换式填充床反应器的co2循环脱除装置及方法
NO345216B1 (en) 2019-08-28 2020-11-09 Zeg Power As Hydrogen-fuelled gas turbine power system and method for its operation
WO2021108395A1 (en) 2019-11-25 2021-06-03 Wormser Energy Solutions, Inc. Char preparation system and gasifier for all-steam gasification with carbon capture
CN115307149B (zh) * 2022-08-26 2025-08-08 中国科学院广州能源研究所 一种蓄热式可燃固废气化处置系统及co2富集方法
WO2025099734A1 (en) * 2023-11-09 2025-05-15 Pi Green Innovations Pvt. Ltd Process for capturing multi-gaseous components and system therefor

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ES2003265A6 (es) * 1987-04-21 1988-10-16 Espan Carburos Metal Procedimiento para la obtencion de co2 y n2 a partir de los gases generados en un motor o turbina de combustion interna
EP0487102A1 (en) * 1990-11-22 1992-05-27 Hitachi, Ltd. Recycling system for the recovery and utilization of CO2 gas
GB2291051A (en) * 1994-07-12 1996-01-17 Agency Ind Science Techn Separating carbon dioxide from gases containing it

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ES2003265A6 (es) * 1987-04-21 1988-10-16 Espan Carburos Metal Procedimiento para la obtencion de co2 y n2 a partir de los gases generados en un motor o turbina de combustion interna
EP0487102A1 (en) * 1990-11-22 1992-05-27 Hitachi, Ltd. Recycling system for the recovery and utilization of CO2 gas
GB2291051A (en) * 1994-07-12 1996-01-17 Agency Ind Science Techn Separating carbon dioxide from gases containing it

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007113364A1 (es) * 2006-03-31 2007-10-11 Consejo Superior De Investigaciones Científicas Procedimiento de precalcinación con producción de co2 puro o fácilmente purificable proveniente de la descomposición de carbonatos
ES2302610A1 (es) * 2006-03-31 2008-07-16 Consejo Superior Investig. Cientificas Procedimiento de calcinacion con produccion de co2 puro o facilmente purificable proveniente de la descomposicion de carbonatos.
ES2302610B1 (es) * 2006-03-31 2009-06-12 Consejo Superior Investig. Cientificas Procedimiento de calcinacion con produccion de co2 puro o facilmente purificable proveniente de la descomposicion de carbonatos.
ES2345135A1 (es) * 2007-07-17 2010-09-15 Fundacion Circe- Centro De Investigacion De Recursos Y Consumos Energeticos Dispositivo ciclonico para calcinacion y procedimiento de separacion de co2 usando dicho dispositivo.
ES2345135B1 (es) * 2007-07-17 2011-07-18 Fundacion Circe- Centro De Investigacion De Recursos Y Consumos Energeticos Dispositivo ciclonico para calcinacion y procedimiento de separacion de co2 usando dicho dispositivo.
ES2370619A1 (es) * 2010-04-27 2011-12-20 Fundación Investigación E Innovación Para El Desarrollo Social Procedimiento para la obtención de hidrogeno, a partir de la biomasa y carbón vegetal.
ES2401294R1 (es) * 2011-06-24 2013-07-11 Consejo Superior Investigacion DISPOSITIVO Y PROCEDIMIENTO PARA LA CAPTURA DE CO2 POR CARBONATACION DE CaO

Also Published As

Publication number Publication date
AU2003216925B2 (en) 2008-09-11
CN1642620A (zh) 2005-07-20
ES2192994B1 (es) 2005-02-16
WO2003080223A1 (es) 2003-10-02
AU2003216925A1 (en) 2003-10-08
CA2479886C (en) 2011-05-17
CA2479886A1 (en) 2003-10-02
US20050060985A1 (en) 2005-03-24
JP2005520678A (ja) 2005-07-14
CN1642620B (zh) 2011-08-10
EP1495794A1 (en) 2005-01-12

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