ES2195452T3 - Proceso de fabricacion de polimeros elastomericos acoplados con estaño. - Google Patents
Proceso de fabricacion de polimeros elastomericos acoplados con estaño.Info
- Publication number
- ES2195452T3 ES2195452T3 ES99100652T ES99100652T ES2195452T3 ES 2195452 T3 ES2195452 T3 ES 2195452T3 ES 99100652 T ES99100652 T ES 99100652T ES 99100652 T ES99100652 T ES 99100652T ES 2195452 T3 ES2195452 T3 ES 2195452T3
- Authority
- ES
- Spain
- Prior art keywords
- tin
- cement
- polymer
- reactor
- approx
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title abstract 2
- 239000004568 cement Substances 0.000 abstract 4
- 150000004820 halides Chemical class 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000011414 polymer cement Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A CAUCHOS DE NEUMATICOS PREPARADOS MEDIANTE POLIMERIZACION ANIONICA Y QUE ESTAN ACOPLADOS FRECUENTEMENTE CON UN AGENTE ACOPLANTE ADECUADO, TAL COMO UN HALURO DE ESTAÑO, PARA MEJORAR DETERMINADAS PROPIEDADES. SE HAN OBTENIDO, DE FORMA INESPERADA, PROPIEDADES MUY MEJORADAS EN LOS NEUMATICOS DE CAUCHO, TAL COMO UNA MENOR HISTERESIS, MEDIANTE EL ACOPLAMIENTO ASIMETRICO DEL CAUCHO. LA PRESENTE INVENCION DESCRIBE UN PROCESO PARA PREPARAR UN POLIMERO CAUCHOTOSO ASIMETRICAMENTE ACOPLADO AL ESTAÑO QUE COMPRENDE: (1) POLIMERIZACION CONTINUA DE UN MONOMERO DIENICO, EN UN PRIMER REACTOR, PARA LOGRAR UNA CONVERSION DE AL MENOS UN 90 %, UTILIZANDO UN INICIADOR ANIONICO, Y PRODUCCION DE UN CEMENTO POLIMERICO QUE CONTIENE CADENAS DE CAUCHO DE POLIDIENO LATENTES; (2) ALIMENTACION CONTINUA DE DICHO CEMENTO PRODUCIDO A UN SEGUNDO REACTOR; (3) ADICION DE UN HALURO DE ESTAÑO A DICHO CEMENTO EN DICHO SEGUNDO REACTOR BAJO CIERTAS CONDICIONES DE AGITACION, PARA PRODUCIR UN CEMENTOPOLIMERICO CON DICHO HALURO DE ESTAÑO HOMOGENEAMENTE DISPERSO EN SU INTERIOR, SIENDO EL TIEMPO DE RESIDENCIA EN DICHO SEGUNDO REACTOR DE APROX. 15 MINUTOS A APROX. 4 HORAS; (4) ALIMENTACION CONTINUA DE DICHO CEMENTO POLIMERICO CON HALURO DE ESTAÑO DISPERSO EN SU INTERIOR A UN REACTOR DE FLUJO DE TIPO PISTON, CON UN TIEMPO DE RESIDENCIA DE APROX. 15 MINUTOS A APROX. 1 HORA, PARA PRODUCIR UN CEMENTO POLIMERICO COMPUESTO POR DICHO POLIMERO CAUCHOTOSO ASIMETRICAMENTE ACOPLADO CON EL ESTAÑO; (5) EXTRACCION CONTINUA DEL PRODUCTO OBTENIDO EN (4) PROCEDENTE DE DICHO REACTOR DE FLUJO TIPO PISTON. DICHO POLIMERO ASI OBTENIDO PRESENTA ESTABILIDAD MEJORADA CON EL ENVEJECIMIENTO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7202198P | 1998-01-21 | 1998-01-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2195452T3 true ES2195452T3 (es) | 2003-12-01 |
Family
ID=22105077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99100652T Expired - Lifetime ES2195452T3 (es) | 1998-01-21 | 1999-01-14 | Proceso de fabricacion de polimeros elastomericos acoplados con estaño. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0930318B1 (es) |
| JP (1) | JP4308956B2 (es) |
| KR (1) | KR19990067956A (es) |
| AR (1) | AR014449A1 (es) |
| BR (1) | BR9900331A (es) |
| DE (1) | DE69906398T2 (es) |
| ES (1) | ES2195452T3 (es) |
| FR (1) | FR2773806B1 (es) |
| GB (1) | GB2333528B (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2272375A1 (en) * | 1998-06-03 | 1999-12-03 | Paul Harry Sandstrom | Tire tread containing isoprene-butadiene rubber |
| US6350807B1 (en) * | 1999-08-18 | 2002-02-26 | The Goodyear Tire & Rubber Company | Silica-reinforced tire tread rubber |
| US6525140B1 (en) | 2000-03-23 | 2003-02-25 | Firestone Polymers, Llc | Method of preparation of coupled branched and linear polymer compositions |
| DE102007038441A1 (de) | 2007-08-16 | 2009-02-19 | Lanxess Deutschland Gmbh | Gekoppelte und Heteroatome enthaltende modifizierte Polymere auf Basis von konjugierten Dienen |
| DE102007038442A1 (de) | 2007-08-16 | 2009-02-19 | Lanxess Deutschland Gmbh | Modifizierte Polymere auf Basis von konjugierten Dienen oder von konjugierten Dienen und vinylaromatischen Verbindungen, ein Verfahren zu deren Herstellung sowie deren Verwendung |
| DE102007038439A1 (de) | 2007-08-16 | 2009-02-19 | Lanxess Deutschland Gmbh | Nanostrukturierte Polymere auf Basis von konjugierten Dienen |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4311803A (en) * | 1979-05-01 | 1982-01-19 | Phillips Petroleum Company | Continuous solution polymerization process |
| JPH0662727B2 (ja) * | 1984-08-27 | 1994-08-17 | 日本合成ゴム株式会社 | ゴム組成物 |
| CA1335614C (en) * | 1987-10-30 | 1995-05-16 | Ronald James Hoxmeier | Method for preparing asymmetric radial copolymers |
| US5422403A (en) * | 1994-08-11 | 1995-06-06 | The Goodyear Tire & Rubber Company | Coupled styrene-isoprene-butadiene rubber |
| GB2322133A (en) * | 1997-02-14 | 1998-08-19 | Goodyear Tire & Rubber | Asymmetrical tin-coupled rubbery polymers |
-
1999
- 1999-01-14 ES ES99100652T patent/ES2195452T3/es not_active Expired - Lifetime
- 1999-01-14 DE DE69906398T patent/DE69906398T2/de not_active Expired - Lifetime
- 1999-01-14 EP EP99100652A patent/EP0930318B1/en not_active Expired - Lifetime
- 1999-01-18 KR KR1019990001231A patent/KR19990067956A/ko not_active Withdrawn
- 1999-01-19 BR BR9900331-7A patent/BR9900331A/pt not_active IP Right Cessation
- 1999-01-20 GB GB9901255A patent/GB2333528B/en not_active Expired - Fee Related
- 1999-01-21 AR ARP990100229A patent/AR014449A1/es unknown
- 1999-01-21 JP JP01301099A patent/JP4308956B2/ja not_active Expired - Fee Related
- 1999-01-21 FR FR9900647A patent/FR2773806B1/fr not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB9901255D0 (en) | 1999-03-10 |
| BR9900331A (pt) | 2000-04-11 |
| JPH11255821A (ja) | 1999-09-21 |
| DE69906398D1 (de) | 2003-05-08 |
| GB2333528A (en) | 1999-07-28 |
| KR19990067956A (ko) | 1999-08-25 |
| EP0930318B1 (en) | 2003-04-02 |
| JP4308956B2 (ja) | 2009-08-05 |
| EP0930318A1 (en) | 1999-07-21 |
| FR2773806A1 (fr) | 1999-07-23 |
| AR014449A1 (es) | 2001-02-28 |
| DE69906398T2 (de) | 2003-12-11 |
| FR2773806B1 (fr) | 2002-06-07 |
| GB2333528B (en) | 2002-01-09 |
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