ES2196770T3 - Fibra optica de plastico, cable de fibra optica, cable de fibra optica con un conector, procedimiento para la fabricacion de un polimero de metacrilato de metilo y procedimiento para la fabricacion de una fibra optica de plastico. - Google Patents
Fibra optica de plastico, cable de fibra optica, cable de fibra optica con un conector, procedimiento para la fabricacion de un polimero de metacrilato de metilo y procedimiento para la fabricacion de una fibra optica de plastico.Info
- Publication number
- ES2196770T3 ES2196770T3 ES99905290T ES99905290T ES2196770T3 ES 2196770 T3 ES2196770 T3 ES 2196770T3 ES 99905290 T ES99905290 T ES 99905290T ES 99905290 T ES99905290 T ES 99905290T ES 2196770 T3 ES2196770 T3 ES 2196770T3
- Authority
- ES
- Spain
- Prior art keywords
- optical fiber
- manufacture
- procedure
- plastic
- optical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000013307 optical fiber Substances 0.000 title 2
- 239000000835 fiber Substances 0.000 title 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 title 1
- 230000003287 optical effect Effects 0.000 title 1
- 239000013308 plastic optical fiber Substances 0.000 title 1
- 239000003999 initiator Substances 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003709 fluoroalkyl group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/04—Azo-compounds
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/045—Light guides
- G02B1/046—Light guides characterised by the core material
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/045—Light guides
- G02B1/048—Light guides characterised by the cladding material
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02033—Core or cladding made from organic material, e.g. polymeric material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Procedimiento para la fabricación de un (co)polímero de metacrilato que comprende la realización de la polimerización mientras se suministra un monómero (mezcla) que contiene al menos el 90% en peso en total de al menos un monómero de metacrilato y un iniciador de la polimerización por radicales representado por la fórmula (II) a un reactor, en el que la concentración del iniciador y la temperatura de polimerización satisfacen una relación representada por las ecuaciones (1) a (4) y la temperatura de polimerización es no inferior a 110ºC y no superior a 160ºC; ln (A) 105, 4 ¿ 45126/B (1) ln (A) 2545, 2/B ¿ 15, 82 (2) ln (A) 225, 9 ¿ 102168, 8/B (3) ln (A) 1300, 0/B ¿ 15, 74 (4) en las que A es una concentración de iniciador (una razón molar del iniciador / el monómero); B es una temperatura de polimerización (ºK); y ln es un símbolo para un logaritmo natural; en la que R es alquilo o fluoroalquilo.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4252698 | 1998-02-24 | ||
| JP22191198 | 1998-08-05 | ||
| JP22305698 | 1998-08-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2196770T3 true ES2196770T3 (es) | 2003-12-16 |
Family
ID=27291246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99905290T Expired - Lifetime ES2196770T3 (es) | 1998-02-24 | 1999-02-24 | Fibra optica de plastico, cable de fibra optica, cable de fibra optica con un conector, procedimiento para la fabricacion de un polimero de metacrilato de metilo y procedimiento para la fabricacion de una fibra optica de plastico. |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6777083B1 (es) |
| EP (1) | EP1059544B1 (es) |
| KR (1) | KR100618479B1 (es) |
| AT (1) | ATE242276T1 (es) |
| DE (1) | DE69908565T2 (es) |
| DK (1) | DK1059544T3 (es) |
| ES (1) | ES2196770T3 (es) |
| TW (2) | TWI222978B (es) |
| WO (1) | WO1999044083A1 (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7039322B1 (en) * | 1998-12-24 | 2006-05-02 | Mitsubishi Rayon Co., Ltd. | Optical communication apparatus |
| WO2001020376A1 (en) * | 1999-09-09 | 2001-03-22 | Mitsubishi Rayon Co., Ltd. | Plastic optical fiber, optical fiber cable and plug-attached optical fiber cable and production methods therefor |
| JP2003098408A (ja) * | 1999-12-24 | 2003-04-03 | Mitsubishi Rayon Co Ltd | 光ファイバケーブル及びプラグ付き光ファイバケーブル |
| US7031582B2 (en) * | 1999-12-24 | 2006-04-18 | Mitsubishi Rayon Co., Ltd. | Optical fiber cable and optical fiber cable with plug |
| JP2003238215A (ja) * | 2002-02-08 | 2003-08-27 | Fujikura Ltd | 光ファイバ被覆用樹脂液 |
| US6927183B1 (en) * | 2002-09-04 | 2005-08-09 | Diversitech Corporation | Reinforced article |
| US20050123451A1 (en) * | 2003-10-31 | 2005-06-09 | Hiroshi Nomura | System and apparatus for body fluid analysis using surface-textured optical materials |
| KR100717925B1 (ko) * | 2005-06-01 | 2007-05-11 | 주식회사 엘지화학 | 점착제용 아크릴계 에스테르 폴리머 시럽의 제조방법 |
| JP4866040B2 (ja) * | 2005-08-26 | 2012-02-01 | 三菱レイヨン株式会社 | プラスチック光ファイバー用コア材の製造方法 |
| EP1844917A3 (de) | 2006-03-24 | 2008-12-03 | Entex Rust & Mitschke GmbH | Verfahren zur Verarbeitung von zu entgasenden Produkten |
| FR2910877B1 (fr) | 2006-12-28 | 2009-09-25 | Eurocopter France | Amelioration aux rotors de giravions equipes d'amortisseurs interpales |
| EP2289687A1 (de) | 2007-05-16 | 2011-03-02 | Entex Rust & Mitschke GmbH | Verfahren zur Verarbeitung von zu entgasenden Produkten |
| FR2941238B1 (fr) * | 2009-01-22 | 2012-06-08 | Arkema France | Utilisation d'une composition transparente pour photobioreacteurs. |
| DE102011112081A1 (de) | 2011-05-11 | 2015-08-20 | Entex Rust & Mitschke Gmbh | Verfahren zur Verarbeitung von Elasten |
| EP2906406B1 (de) | 2012-10-11 | 2019-07-17 | Entex Rust & Mitschke GmbH | Extruder zur verarbeitung von kunststoffen, die zum verkleben neigen |
| WO2014167868A1 (ja) * | 2013-04-12 | 2014-10-16 | 株式会社クラレ | アクリル系樹脂フィルム |
| EP3211463B1 (en) * | 2014-10-20 | 2025-07-16 | Mitsubishi Chemical Corporation | Optical fiber, method for manufacturing optical fiber, optical fiber cable, and sensor |
| DE102015001167A1 (de) | 2015-02-02 | 2016-08-04 | Entex Rust & Mitschke Gmbh | Entgasen bei der Extrusion von Kunststoffen |
| DE102017001093A1 (de) | 2016-04-07 | 2017-10-26 | Entex Rust & Mitschke Gmbh | Entgasen bei der Extrusion von Kunststoffen mit Filterscheiben aus Sintermetall |
| DE102015008406A1 (de) | 2015-07-02 | 2017-04-13 | Entex Rust & Mitschke Gmbh | Verfahren zur Bearbeitung von Produkten im Extruder |
| DE102016002143A1 (de) | 2016-02-25 | 2017-08-31 | Entex Rust & Mitschke Gmbh | Füllteilmodul in Planetwalzenextruderbauweise |
| DE102017006638A1 (de) | 2017-07-13 | 2019-01-17 | Entex Rust & Mitschke Gmbh | Füllteilmodul in Planetwalzenextruderbauweise |
| US11644617B1 (en) * | 2020-09-22 | 2023-05-09 | Apple Inc. | Systems having fibers with antireflection coatings |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3999834A (en) * | 1973-08-14 | 1976-12-28 | Kanebo, Ltd. | Method for producing optical fibers and resulting fibers |
| JPS5217555B2 (es) * | 1973-08-15 | 1977-05-16 | ||
| JPS5217555A (en) | 1975-08-01 | 1977-02-09 | Asahi Glass Co Ltd | Fluorine-containing copolymer compositions containing carbonaceous mat erials |
| JPS60151256A (ja) | 1984-01-13 | 1985-08-09 | Nitto Electric Ind Co Ltd | 繊維強化樹脂被覆光フアイバ−の製造方法 |
| JPS6151105A (ja) * | 1984-08-21 | 1986-03-13 | Toray Ind Inc | プラスチツク光フアイバ−の製造方法 |
| DE3769581D1 (de) * | 1986-09-22 | 1991-05-29 | Mitsubishi Rayon Co | Kunststoffmultifilamentfaser als optische faser. |
| JPS6394203A (ja) * | 1986-10-09 | 1988-04-25 | Toray Ind Inc | プラスチツク光フアイバ |
| JPS6395402A (ja) * | 1986-10-13 | 1988-04-26 | Toray Ind Inc | 芯鞘型プラスチツク光フアイバ |
| CA1292461C (en) * | 1987-02-12 | 1991-11-26 | Hiromu Terada | Endoscope |
| US4807964A (en) * | 1987-06-12 | 1989-02-28 | Ppg Industries, Inc. | Plastic optical fiber |
| CA1335022C (en) * | 1987-07-30 | 1995-03-28 | Tsuruyoshi Matsumoto | Cladding material for optical fiber |
| JPH0243506A (ja) * | 1988-08-04 | 1990-02-14 | Mitsubishi Rayon Co Ltd | プラスチツク光フアイバ |
| JPH02158702A (ja) * | 1988-12-13 | 1990-06-19 | Asahi Chem Ind Co Ltd | プラスチック光フアイバ |
| JPH0359501A (ja) * | 1989-07-28 | 1991-03-14 | Mitsubishi Rayon Co Ltd | プラスチック光ファイバの製造方法 |
| US5175786A (en) * | 1989-09-29 | 1992-12-29 | Mitsubishi Rayon Company Ltd. | Distributed refractive index type optical transmission plastic article and method of manufacturing the same |
| JPH03245105A (ja) * | 1990-02-23 | 1991-10-31 | Mitsubishi Rayon Co Ltd | 内視鏡 |
| WO1992015901A1 (fr) * | 1991-03-01 | 1992-09-17 | Mitsubishi Rayon Co., Ltd. | Module d'emission optique compose d'un plastique du type a gradient d'indice et procede de production |
| DE4120312C1 (es) * | 1991-06-20 | 1993-02-18 | Roehm Gmbh, 6100 Darmstadt, De | |
| JPH0532722A (ja) | 1991-07-30 | 1993-02-09 | Hymo Corp | カチオン性水溶性重合体分散液の製造方法 |
| EP0664463A4 (en) * | 1993-06-16 | 1997-08-20 | Sumitomo Electric Industries | BASE MATERIAL FOR PLASTIC OPTICAL FIBER, ITS PRODUCTION, AND METHOD AND APPARATUS FOR ITS PRODUCTION. |
| JPH0777613A (ja) * | 1993-09-08 | 1995-03-20 | Toray Ind Inc | プラスチック光ファイバの製造方法及びそれによるプラスチック光ファイバ |
| US5728793A (en) * | 1993-11-05 | 1998-03-17 | Sumitomo Chemical Company, Limited | Process for production of methacrylate polymers |
| JP3628518B2 (ja) * | 1998-07-14 | 2005-03-16 | 三菱レイヨン株式会社 | メタクリル系重合体およびその製造方法 |
-
1999
- 1999-02-24 DK DK99905290T patent/DK1059544T3/da active
- 1999-02-24 DE DE69908565T patent/DE69908565T2/de not_active Expired - Lifetime
- 1999-02-24 AT AT99905290T patent/ATE242276T1/de active
- 1999-02-24 WO PCT/JP1999/000821 patent/WO1999044083A1/ja not_active Ceased
- 1999-02-24 EP EP99905290A patent/EP1059544B1/en not_active Expired - Lifetime
- 1999-02-24 TW TW088102748A patent/TWI222978B/zh not_active IP Right Cessation
- 1999-02-24 KR KR1020007009293A patent/KR100618479B1/ko not_active Expired - Fee Related
- 1999-02-24 ES ES99905290T patent/ES2196770T3/es not_active Expired - Lifetime
- 1999-02-24 US US09/622,057 patent/US6777083B1/en not_active Expired - Lifetime
- 1999-02-24 TW TW092126818A patent/TWI270554B/zh not_active IP Right Cessation
-
2004
- 2004-04-15 US US10/824,524 patent/US7098281B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010034535A (ko) | 2001-04-25 |
| EP1059544B1 (en) | 2003-06-04 |
| WO1999044083A1 (en) | 1999-09-02 |
| DE69908565T2 (de) | 2004-05-06 |
| US7098281B2 (en) | 2006-08-29 |
| TWI222978B (en) | 2004-11-01 |
| US6777083B1 (en) | 2004-08-17 |
| DK1059544T3 (da) | 2003-09-29 |
| US20040197069A1 (en) | 2004-10-07 |
| TWI270554B (en) | 2007-01-11 |
| EP1059544A1 (en) | 2000-12-13 |
| KR100618479B1 (ko) | 2006-08-31 |
| ATE242276T1 (de) | 2003-06-15 |
| DE69908565D1 (de) | 2003-07-10 |
| TW200403259A (en) | 2004-03-01 |
| EP1059544A4 (en) | 2001-04-25 |
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