ES2199665A1 - Compuestos de polipirrol altamente conductores y procedimiento para su preparacion. - Google Patents
Compuestos de polipirrol altamente conductores y procedimiento para su preparacion.Info
- Publication number
- ES2199665A1 ES2199665A1 ES200200229A ES200200229A ES2199665A1 ES 2199665 A1 ES2199665 A1 ES 2199665A1 ES 200200229 A ES200200229 A ES 200200229A ES 200200229 A ES200200229 A ES 200200229A ES 2199665 A1 ES2199665 A1 ES 2199665A1
- Authority
- ES
- Spain
- Prior art keywords
- pyrrole
- compounds
- highly conductive
- conductivity
- polymerisation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Compuestos altamente conductores del polímero conductor intrínseco polipirrol para fines industriales, preferentemente para realización de baterías eléctricas y procedimiento de preparación de dichos compuestos por polimerización química oxidativa de pirrol en agua caracterizado por el empleo de aditivos promotores de la conductividad y de la estabilidad del material resultante, que comprende la adición, en una o varias veces y bajo agitación fuerte, del pirrol a una disolución acuosa que contiene uno, o más, agentes oxidantes y uno, o más, aditivos promotores de la conductividad y de la estabilidad. Dicho procedimiento permite obtener compuestos de polipirrol de conductividad eléctrica superior a 250 S/cm, con rendimientos de reacción cercanos al 100 % y tiempos de reacción inferiores a 1 h. Así mismo, permite conseguir compuestos de polipirrol que conservan su conductividad eléctrica tras prolongados tiempos a elevadas temperaturas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200200229A ES2199665B1 (es) | 2002-01-31 | 2002-01-31 | Compuestos de polipirrol altamente conductores y procedimiento para su preparacion. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200200229A ES2199665B1 (es) | 2002-01-31 | 2002-01-31 | Compuestos de polipirrol altamente conductores y procedimiento para su preparacion. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2199665A1 true ES2199665A1 (es) | 2004-02-16 |
| ES2199665B1 ES2199665B1 (es) | 2005-03-01 |
Family
ID=31897079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES200200229A Expired - Fee Related ES2199665B1 (es) | 2002-01-31 | 2002-01-31 | Compuestos de polipirrol altamente conductores y procedimiento para su preparacion. |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES2199665B1 (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005037889A1 (es) * | 2003-10-21 | 2005-04-28 | Fundacion Cidetec | Compuestos de polipirrol altamente conductores y procedimiento para su preparación |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5221579A (en) * | 1990-10-03 | 1993-06-22 | Quantum Chemical Corporation | Method of forming and processing conductive polymer composites |
| US5236627A (en) * | 1989-08-14 | 1993-08-17 | Solvay & Cie (Societe Anonyme) | Compositions of electrically conductive polymers derived from substituted or unsubstituted pyrrole and process for obtaining them |
| EP0664308A1 (en) * | 1994-01-19 | 1995-07-26 | Toho Rayon Co., Ltd. | Process for preparation of soluble ion-doped poly(alkyl-substituted pyrrole) |
| EP0727788A2 (en) * | 1995-02-17 | 1996-08-21 | Matsushita Electric Industrial Co., Ltd. | Conductive polymer composition and processes for preparing the same |
-
2002
- 2002-01-31 ES ES200200229A patent/ES2199665B1/es not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5236627A (en) * | 1989-08-14 | 1993-08-17 | Solvay & Cie (Societe Anonyme) | Compositions of electrically conductive polymers derived from substituted or unsubstituted pyrrole and process for obtaining them |
| US5221579A (en) * | 1990-10-03 | 1993-06-22 | Quantum Chemical Corporation | Method of forming and processing conductive polymer composites |
| EP0664308A1 (en) * | 1994-01-19 | 1995-07-26 | Toho Rayon Co., Ltd. | Process for preparation of soluble ion-doped poly(alkyl-substituted pyrrole) |
| EP0727788A2 (en) * | 1995-02-17 | 1996-08-21 | Matsushita Electric Industrial Co., Ltd. | Conductive polymer composition and processes for preparing the same |
Non-Patent Citations (2)
| Title |
|---|
| A. KASSIM et al. "Preparation and Characterization of Polypyrrole Polymer Prepared by Non-electrochemical Method", Ultra Science, 2001, Vol. 13, Nº 3, paginas 306-313. * |
| Y. KUDOH et al. "Properties of Chemically Prepared Polypyrrole with Aqueous Solution Containing Fe2(SO4)3, a Sulfonic Surfactant and a Phenol Derivative", Synthetic Metals, 1998, Vol. 95, paginas 191-196. * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005037889A1 (es) * | 2003-10-21 | 2005-04-28 | Fundacion Cidetec | Compuestos de polipirrol altamente conductores y procedimiento para su preparación |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2199665B1 (es) | 2005-03-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EC2A | Search report published |
Date of ref document: 20040216 Kind code of ref document: A1 |
|
| PC2A | Transfer of patent | ||
| GD2A | Contractual licences |
Effective date: 20050121 |
|
| FG2A | Definitive protection |
Ref document number: 2199665B1 Country of ref document: ES |
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| FD1A | Patent lapsed |
Effective date: 20100312 |