ES2199666B1 - Procedimiento de produccion de polioleteres. - Google Patents

Procedimiento de produccion de polioleteres.

Info

Publication number
ES2199666B1
ES2199666B1 ES200200455A ES200200455A ES2199666B1 ES 2199666 B1 ES2199666 B1 ES 2199666B1 ES 200200455 A ES200200455 A ES 200200455A ES 200200455 A ES200200455 A ES 200200455A ES 2199666 B1 ES2199666 B1 ES 2199666B1
Authority
ES
Spain
Prior art keywords
polyoleter
sepiolites
polyethers
production procedure
double metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES200200455A
Other languages
English (en)
Other versions
ES2199666A1 (es
Inventor
Mariano Malaga Mellado
M. Dolores Blanco Gonzalez
Beatriz Montalvo Barroso
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Repsol Quimica SA
Original Assignee
Repsol Quimica SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES200200455A priority Critical patent/ES2199666B1/es
Application filed by Repsol Quimica SA filed Critical Repsol Quimica SA
Priority to DE60300201T priority patent/DE60300201T2/de
Priority to EP03380039A priority patent/EP1338618B1/en
Priority to AT03380039T priority patent/ATE284911T1/de
Priority to PT03380039T priority patent/PT1338618E/pt
Priority to KR1020030011430A priority patent/KR100551463B1/ko
Priority to ARP030100609A priority patent/AR038606A1/es
Priority to JP2003047065A priority patent/JP2003342362A/ja
Priority to US10/374,631 priority patent/US6930210B2/en
Publication of ES2199666A1 publication Critical patent/ES2199666A1/es
Application granted granted Critical
Publication of ES2199666B1 publication Critical patent/ES2199666B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedimiento de producción de polioléteres. La invención se refiere a un procedimiento de obtención de polioléteres de alta pureza y bajo olor, con muy bajos niveles de restos catalíticos, mediante reacciones de poliadición de óxidos de alqueno a sustancias que contienen hidrógenos activos, en presencia de cianuros metálicos dobles como catalizadores. El procedimiento se caracteriza por llevar a cabo la reacción de poliadición en presencia de sepiolitas y/o por el tratamiento posterior con sepiolitas de los polioléteres producidos con cianuros metálicos dobles en ausencia de sepiolitas.
ES200200455A 2002-02-25 2002-02-25 Procedimiento de produccion de polioleteres. Expired - Fee Related ES2199666B1 (es)

Priority Applications (9)

Application Number Priority Date Filing Date Title
ES200200455A ES2199666B1 (es) 2002-02-25 2002-02-25 Procedimiento de produccion de polioleteres.
EP03380039A EP1338618B1 (en) 2002-02-25 2003-02-21 Process to produce polyether polyols
AT03380039T ATE284911T1 (de) 2002-02-25 2003-02-21 Verfahren zur herstellung von polyetherpolyolen
PT03380039T PT1338618E (pt) 2002-02-25 2003-02-21 Processo de producao de poliois de polieter
DE60300201T DE60300201T2 (de) 2002-02-25 2003-02-21 Verfahren zur Herstellung von Polyetherpolyolen
KR1020030011430A KR100551463B1 (ko) 2002-02-25 2003-02-24 폴리에테르 폴리올의 제조방법
ARP030100609A AR038606A1 (es) 2002-02-25 2003-02-25 Procedimiento de produccion de polioleteres
JP2003047065A JP2003342362A (ja) 2002-02-25 2003-02-25 ポリエーテルポリオールの製造方法
US10/374,631 US6930210B2 (en) 2002-02-25 2003-02-25 Process to produce polyether polyols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200200455A ES2199666B1 (es) 2002-02-25 2002-02-25 Procedimiento de produccion de polioleteres.

Publications (2)

Publication Number Publication Date
ES2199666A1 ES2199666A1 (es) 2004-02-16
ES2199666B1 true ES2199666B1 (es) 2005-06-01

Family

ID=27635999

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200200455A Expired - Fee Related ES2199666B1 (es) 2002-02-25 2002-02-25 Procedimiento de produccion de polioleteres.

Country Status (9)

Country Link
US (1) US6930210B2 (es)
EP (1) EP1338618B1 (es)
JP (1) JP2003342362A (es)
KR (1) KR100551463B1 (es)
AR (1) AR038606A1 (es)
AT (1) ATE284911T1 (es)
DE (1) DE60300201T2 (es)
ES (1) ES2199666B1 (es)
PT (1) PT1338618E (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2297110T3 (es) * 2003-06-30 2008-05-01 Repsol Quimica S.A. Procedimiento de purificacion de polioleteres.
EP1756198B2 (en) * 2004-06-09 2011-02-23 Shell Internationale Research Maatschappij B.V. Process of preparing odour-lean polyether polyol
CN1329428C (zh) * 2004-12-07 2007-08-01 上海工程技术大学 一种除去聚醚多元醇中微量c1－c7低碳组分的方法
EP2058352B1 (en) * 2006-08-31 2011-11-09 Asahi Glass Company, Limited Method of purifying polyether compound
SA116370919B1 (ar) 2011-05-17 2017-05-08 ريبسول، اس. ايه. عملية لتحضير مُحفِّز من مُعقَّد سيانيدي مزدوج المعدن
US9527958B2 (en) 2014-05-02 2016-12-27 Covestro Llc Process for purification of polyether carbonate polyols
CN105111428A (zh) * 2015-08-31 2015-12-02 句容宁武新材料发展有限公司 一种低气味聚醚多元醇的制备方法
US20190119444A1 (en) 2017-10-25 2019-04-25 Covestro Llc Process to remove dmc catalysts from polyether carbonate polyols
CN110358070B (zh) * 2019-06-12 2021-11-09 佳化化学科技发展（上海）有限公司 一种低气味聚醚多元醇的生产工艺及系统

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6252039B1 (en) * 1997-04-16 2001-06-26 Basf Aktiengesellschaft Method for decoloring tetrahydrofuran polymers or copolymers

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1063525A (en) * 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3493518A (en) * 1966-04-18 1970-02-03 Exxon Research Engineering Co Method of preparing new crystalline metal aluminosilicate zeolites
US3941849A (en) * 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
JPS5622323A (en) * 1979-08-02 1981-03-02 Takeda Chem Ind Ltd Removal of alkali catalyst from polyether-polyol
CA1155871A (en) * 1980-10-16 1983-10-25 Gencorp Inc. Method for treating polypropylene ether and poly-1,2- butylene ether polyols
EP0283148B1 (en) * 1987-02-26 1997-07-30 ARCO Chemical Technology, L.P. Preparation of filterable double metal cyanide complex catalyst for alkylene oxide polymerisation
US4843054A (en) * 1987-02-26 1989-06-27 Arco Chemical Technology, Inc. Preparation of filterable double metal cyanide complex catalyst for propylene oxide polymerization
US4721818A (en) * 1987-03-20 1988-01-26 Atlantic Richfield Company Purification of polyols prepared using double metal cyanide complex catalysts
US4877906A (en) * 1988-11-25 1989-10-31 Arco Chemical Technology, Inc. Purification of polyols prepared using double metal cyanide complex catalysts
JP2704421B2 (ja) * 1988-12-27 1998-01-26 株式会社豊田中央研究所 鎖状横造粘土鉱物の製造方法
US4987271A (en) * 1989-02-17 1991-01-22 Asahi Glass Company, Ltd. Method for purifying a polyoxyalkylene alcohol
US5010047A (en) 1989-02-27 1991-04-23 Arco Chemical Technology, Inc. Recovery of double metal cyanide complex catalyst from a polymer
US5099075A (en) * 1990-11-02 1992-03-24 Olin Corporation Process for removing double metal cyanide catalyst residues from a polyol
JPH04197407A (ja) * 1990-11-29 1992-07-17 Asahi Glass Co Ltd ポリエーテル類の精製法
US5144093A (en) * 1991-04-29 1992-09-01 Olin Corporation Process for purifying and end-capping polyols made using double metal cyanide catalysts
US5158922A (en) * 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5248833A (en) * 1992-09-22 1993-09-28 Arco Chemical Technology, L.P. Process for purifying polyols made with double metal cyanide catalysts
US5416241A (en) * 1994-01-27 1995-05-16 Arco Chemical Technology, L.P. Method for purifying polyether polyols made with double metal cyanide catalysts
JP3981162B2 (ja) * 1994-07-18 2007-09-26 旭硝子株式会社 ポリエーテルの製造方法
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5627120A (en) 1996-04-19 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5714428A (en) 1996-10-16 1998-02-03 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing functionalized polymers
JPH10263411A (ja) * 1997-03-27 1998-10-06 Mitsubishi Paper Mills Ltd 吸着性光触媒シート
US5844070A (en) 1997-05-16 1998-12-01 Arco Chemical Technology, L.P. Process for rapid activation of double metal cyanide catalysts
ID24172A (id) 1997-10-13 2000-07-13 Bayer Ag Katalis logam ganda yang sangat aktif untuk memproduksi poliol-poliol poliester
IS4687A (is) 1998-03-13 1998-04-06 Shell Internationale Research Maatschappij B.V. Aðferð við framleiðslu á lyktarlitlum pólýeter pólýólum

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6252039B1 (en) * 1997-04-16 2001-06-26 Basf Aktiengesellschaft Method for decoloring tetrahydrofuran polymers or copolymers

Also Published As

Publication number Publication date
US6930210B2 (en) 2005-08-16
ES2199666A1 (es) 2004-02-16
PT1338618E (pt) 2005-04-29
US20030163006A1 (en) 2003-08-28
KR20030070554A (ko) 2003-08-30
EP1338618A1 (en) 2003-08-27
EP1338618B1 (en) 2004-12-15
AR038606A1 (es) 2005-01-19
DE60300201D1 (de) 2005-01-20
JP2003342362A (ja) 2003-12-03
KR100551463B1 (ko) 2006-02-14
ATE284911T1 (de) 2005-01-15
DE60300201T2 (de) 2006-01-12

Similar Documents

Publication Publication Date Title
AR038606A1 (es) Procedimiento de produccion de polioleteres
ATE348075T1 (de) Rückgewinnung des ammoniaksynthesekatalysators
ES2127557T3 (es) Procedimiento para la eliminacion de compuestos clorato y bromato del agua por reduccion catalitica.
DE50007385D1 (de) Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
PT1115490E (pt) Catalisadores a base de cianeto bimetalico para producao de polieter-poliois
TW200611750A (en) Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound
MY136943A (en) Crystalline mww-type titanosilicate catalyst for producing oxidized compound, production process for the catalyst, and process for producing oxidized compound by using the catalyst
DE602005015862D1 (de) Verwendung von k-252a und kinasehemmern zur vorbeugung und behandlung von hmgb1-assoziierten pathologien
PL353722A1 (en) Catalysts of double metal cyanide (dmc) type for use in production of polyether polyols, method of obtaining such catalyst, method of obtaining polyether polyols as well as application of one of or more dmc-type catalysts
AR057787A1 (es) Produccion por auto-oxidacion de peroxido de hidrogeno a traves de hidrogenacion en un microrreactor
PT1100617E (pt) Catalisadores de cianeto bimetalico usados na preparacao de polieterpoliois
ATE525130T1 (de) Aktivierung von hydrierungskatalysatoren mittels kohlenmonoxid und verwendung von katalysatoren zur hydrierung
ATE340642T1 (de) Verfahren in mikrokanalreaktoren mit gebundenem katalysator und einen gebundenen katalysator oder gebundene chirale hilfsmittel enthaltende systeme
BR0001405A (pt) Catalisadores de cianeto de metal duplo para a preparação de poliéter-polióis
PT1633799E (pt) Preparação de poliéter-álcoois mediante a utilização da catálise dmc
SI1438034T1 (sl) Uporaba 1-fenil-3-dimetilaminopropanskih spojin za terapijo urinske inkontinence
AR021305A1 (es) Procedimiento de fabricacion de un oxirano
BR0010302A (pt) Catalisadores de cianeto metálico duplo para a produção de polieterpolióis
ATE265886T1 (de) Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
TW200626179A (en) Dental bleaching material and method for bleaching teeth
BR0212074A (pt) Catalisadores de cianeto de metal duplo para a preparação de poliéter-polióis
ES2076727T3 (es) Procedimiento de amoxidacion de hidrocarburos saturados.
NO20054631D0 (no) Antistoff mot tumorspesifikt antigen som mal
ES2038540A1 (es) Procedimiento para limpiar un sinterizado usado para filtrar una suspension catalizadora metalica.
EP1666443A4 (en) Process for producing cumene and process for propylene oxide production including the production process

Legal Events

Date Code Title Description
EC2A Search report published

Date of ref document: 20040216

Kind code of ref document: A1

FG2A Definitive protection

Ref document number: 2199666B1

Country of ref document: ES

FD2A Announcement of lapse in spain

Effective date: 20211118