ES2208271T3 - Catalizador basado en oxido de vanadio-antimonio promovido por arsenico para la amoxidacion selectiva de parafinas. - Google Patents

Catalizador basado en oxido de vanadio-antimonio promovido por arsenico para la amoxidacion selectiva de parafinas.

Info

Publication number: ES2208271T3
Authority: ES; Spain
Prior art keywords: catalyst; procedure according; arsenic; paraffin; propane
Prior art date: 1999-02-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES00903329T

Other languages

English (en)

Spanish (es)

Inventor

James F. Brazdil, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Standard Oil Co

Original Assignee

Standard Oil Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-02-08

Filing date

2000-01-18

Publication date

2004-06-16

2000-01-18 Application filed by Standard Oil Co filed Critical Standard Oil Co

2004-06-16 Application granted granted Critical

2004-06-16 Publication of ES2208271T3 publication Critical patent/ES2208271T3/es

2020-01-18 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 61
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 title claims description 8
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 34
238000000034 method Methods 0.000 claims abstract description 32
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims abstract description 22
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 20
239000001294 propane Substances 0.000 claims abstract description 17
238000006243 chemical reaction Methods 0.000 claims abstract description 14
229910052785 arsenic Inorganic materials 0.000 claims abstract description 12
239000012188 paraffin wax Substances 0.000 claims abstract description 12
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 11
239000001282 iso-butane Substances 0.000 claims abstract description 11
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims abstract description 10
229910021529 ammonia Inorganic materials 0.000 claims abstract description 10
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 10
230000003647 oxidation Effects 0.000 claims abstract description 9
238000007254 oxidation reaction Methods 0.000 claims abstract description 9
230000003197 catalytic effect Effects 0.000 claims abstract description 8
229910052788 barium Inorganic materials 0.000 claims abstract description 7
229910052796 boron Inorganic materials 0.000 claims abstract description 7
229910052791 calcium Inorganic materials 0.000 claims abstract description 7
150000001768 cations Chemical class 0.000 claims abstract description 7
229910052802 copper Inorganic materials 0.000 claims abstract description 7
229910052733 gallium Inorganic materials 0.000 claims abstract description 7
229910052732 germanium Inorganic materials 0.000 claims abstract description 7
229910052738 indium Inorganic materials 0.000 claims abstract description 7
229910052744 lithium Inorganic materials 0.000 claims abstract description 7
229910052749 magnesium Inorganic materials 0.000 claims abstract description 7
229910052748 manganese Inorganic materials 0.000 claims abstract description 7
239000000203 mixture Substances 0.000 claims abstract description 7
229910052759 nickel Inorganic materials 0.000 claims abstract description 7
229910052758 niobium Inorganic materials 0.000 claims abstract description 7
229910052712 strontium Inorganic materials 0.000 claims abstract description 7
229910052715 tantalum Inorganic materials 0.000 claims abstract description 7
229910052721 tungsten Inorganic materials 0.000 claims abstract description 7
229910052725 zinc Inorganic materials 0.000 claims abstract description 7
229910052726 zirconium Inorganic materials 0.000 claims abstract description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
239000001301 oxygen Substances 0.000 claims abstract description 6
238000004519 manufacturing process Methods 0.000 claims abstract description 5
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 4
229910001882 dioxygen Inorganic materials 0.000 claims abstract description 4
239000000376 reactant Substances 0.000 claims abstract description 4
239000012808 vapor phase Substances 0.000 claims abstract description 4
229910052718 tin Inorganic materials 0.000 claims abstract description 3
229910052719 titanium Inorganic materials 0.000 claims abstract description 3
238000006555 catalytic reaction Methods 0.000 claims abstract 2
238000001354 calcination Methods 0.000 claims description 9
239000011135 tin Substances 0.000 claims description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
239000012530 fluid Substances 0.000 claims description 4
HBNLSMCCHISJHZ-UHFFFAOYSA-N [Sb]=O.[V] Chemical compound [Sb]=O.[V] HBNLSMCCHISJHZ-UHFFFAOYSA-N 0.000 claims description 3
DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 claims description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims description 2
229940000488 arsenic acid Drugs 0.000 claims description 2
239000000463 material Substances 0.000 claims description 2
229910003455 mixed metal oxide Inorganic materials 0.000 claims description 2
239000010936 titanium Substances 0.000 claims description 2
GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims 2
COHDHYZHOPQOFD-UHFFFAOYSA-N arsenic pentoxide Chemical compound O=[As](=O)O[As](=O)=O COHDHYZHOPQOFD-UHFFFAOYSA-N 0.000 claims 2
239000000843 powder Substances 0.000 claims 2
238000001035 drying Methods 0.000 claims 1
238000009736 wetting Methods 0.000 claims 1
229910052742 iron Inorganic materials 0.000 abstract description 2
229910052804 chromium Inorganic materials 0.000 abstract 1
229910052711 selenium Inorganic materials 0.000 abstract 1
229910052714 tellurium Inorganic materials 0.000 abstract 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 5
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
RJAAXVMENUVEAN-UHFFFAOYSA-N antimony vanadium Chemical compound [V].[Sb] RJAAXVMENUVEAN-UHFFFAOYSA-N 0.000 description 4
238000002360 preparation method Methods 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
238000005054 agglomeration Methods 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
239000007789 gas Substances 0.000 description 2
150000005673 monoalkenes Chemical class 0.000 description 2
238000004064 recycling Methods 0.000 description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
230000002650 habitual effect Effects 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
-1 propane or isobutane Chemical class 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

ES00903329T 1999-02-08 2000-01-18 Catalizador basado en oxido de vanadio-antimonio promovido por arsenico para la amoxidacion selectiva de parafinas. Expired - Lifetime ES2208271T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US09/246,266 US6162760A (en)	1999-02-08	1999-02-08	Arsenic promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
US246266		1999-02-08

Publications (1)

Publication Number	Publication Date
ES2208271T3 true ES2208271T3 (es)	2004-06-16

Family

ID=22929961

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES00903329T Expired - Lifetime ES2208271T3 (es)	1999-02-08	2000-01-18	Catalizador basado en oxido de vanadio-antimonio promovido por arsenico para la amoxidacion selectiva de parafinas.

Country Status (14)

Country	Link
US (1)	US6162760A (de)
EP (1)	EP1150945B1 (de)
JP (1)	JP2002536355A (de)
KR (1)	KR20010101956A (de)
CN (1)	CN1337939A (de)
AT (1)	ATE251122T1 (de)
BG (1)	BG105726A (de)
BR (1)	BR0008070A (de)
CA (1)	CA2361688A1 (de)
DE (1)	DE60005644T2 (de)
ES (1)	ES2208271T3 (de)
TR (1)	TR200102284T2 (de)
WO (1)	WO2000046185A1 (de)
ZA (1)	ZA200106072B (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6281378B1 (en) *	1995-06-08	2001-08-28	Nippon Shokubai Co., Ltd.	Vanadium-containing catalysts, process for manufacturing and use of the same
US6710011B2 (en)	2001-12-21	2004-03-23	Saudi Basic Industries Corporatioin	Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same
US7294734B2 (en) *	2003-05-02	2007-11-13	Velocys, Inc.	Process for converting a hydrocarbon to an oxygenate or a nitrile
US20050137422A1 (en) *	2003-12-19	2005-06-23	Saudi Basic Industries Corporation	Process for producing an unsaturated carboxylic acid from an alkane
US8193387B2 (en) *	2003-12-19	2012-06-05	Saudi Basic Industries Corporation	Process for producing an unsaturated carboxylic acid from an alkane
US7449426B2 (en) *	2005-11-29	2008-11-11	Saudi Basic Industries Corporation	Catalyst composition without antimony or molybdenum for ammoxidation of alkanes, a process of making and a process of using thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4746641A (en) *	1984-08-22	1988-05-24	Standard Oil Company	Ammoxidation of paraffins and catalysts therefor
US5008427A (en) *	1988-12-23	1991-04-16	The Standard Oil Company	Ammoxidation of paraffins
KR920021498A (ko) *	1991-05-09	1992-12-18	에또 다께또시	니트릴의 제조 방법
US5693587A (en) *	1995-06-06	1997-12-02	The Standard Oil Company	Method for preparing vanadium antimony oxide based oxidation and ammoxidation catalysts
US5854172A (en) *	1997-01-17	1998-12-29	The Standard Oil Company	Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O

1999
- 1999-02-08 US US09/246,266 patent/US6162760A/en not_active Expired - Fee Related
2000
- 2000-01-18 BR BR0008070-5A patent/BR0008070A/pt not_active IP Right Cessation
- 2000-01-18 WO PCT/US2000/001151 patent/WO2000046185A1/en not_active Ceased
- 2000-01-18 DE DE60005644T patent/DE60005644T2/de not_active Expired - Fee Related
- 2000-01-18 JP JP2000597257A patent/JP2002536355A/ja active Pending
- 2000-01-18 KR KR1020017009777A patent/KR20010101956A/ko not_active Withdrawn
- 2000-01-18 EP EP00903329A patent/EP1150945B1/de not_active Expired - Lifetime
- 2000-01-18 ES ES00903329T patent/ES2208271T3/es not_active Expired - Lifetime
- 2000-01-18 TR TR2001/02284T patent/TR200102284T2/xx unknown
- 2000-01-18 AT AT00903329T patent/ATE251122T1/de not_active IP Right Cessation
- 2000-01-18 CA CA002361688A patent/CA2361688A1/en not_active Abandoned
- 2000-01-18 CN CN00803082A patent/CN1337939A/zh active Pending
2001
- 2001-07-23 BG BG105726A patent/BG105726A/bg unknown
- 2001-07-24 ZA ZA200106072A patent/ZA200106072B/en unknown

Also Published As

Publication number	Publication date
DE60005644T2 (de)	2004-08-05
EP1150945A1 (de)	2001-11-07
TR200102284T2 (tr)	2002-01-21
ZA200106072B (en)	2002-10-24
WO2000046185A1 (en)	2000-08-10
CA2361688A1 (en)	2000-08-10
JP2002536355A (ja)	2002-10-29
KR20010101956A (ko)	2001-11-15
BR0008070A (pt)	2002-02-05
BG105726A (bg)	2002-06-28
US6162760A (en)	2000-12-19
EP1150945B1 (de)	2003-10-01
ATE251122T1 (de)	2003-10-15
CN1337939A (zh)	2002-02-27
DE60005644D1 (de)	2003-11-06

Publication	Publication Date	Title
US6156920A (en)	2000-12-05	Molybdenum promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
KR0184871B1 (ko)	1999-04-15	아크릴로니트릴 및 메타크릴로니트릴의 제조방법
US6043185A (en)	2000-03-28	Gallium promoted molybdenum vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
US6458742B1 (en)	2002-10-01	Catalyst for the manufacture of acrylonitrile
CN104936697A (zh)	2015-09-23	用于混合金属氧化物氨氧化催化剂的预煅烧添加剂
EP0288218B1 (de)	1993-06-30	Verfahren zur Ammoxidation und Katalysatorzusammensetzung dafür
US4760159A (en)	1988-07-26	Method for ammoxidation of paraffins and catalyst therefor
US4874738A (en)	1989-10-17	Catalyst for ammoxidation of paraffins
US4837191A (en)	1989-06-06	Catalytic mixture for the ammoxidation of paraffins
ES2208271T3 (es)	2004-06-16	Catalizador basado en oxido de vanadio-antimonio promovido por arsenico para la amoxidacion selectiva de parafinas.
US4883896A (en)	1989-11-28	Method for ammoxidation of paraffins and catalyst system therefor
US4835125A (en)	1989-05-30	Catalyst system for ammoxidation of paraffins
US3895051A (en)	1975-07-15	Catalyst and process for oxidizing or ammoxidizing n-butenes and/or isobutene
US4918214A (en)	1990-04-17	Ammoxidation of paraffins and catalysts therefrom
US4866194A (en)	1989-09-12	Method for ammoxidation of paraffins and catalyst system therefor
US4801727A (en)	1989-01-31	Method for ammoxidation of paraffins and catalyst system therefor
US4866024A (en)	1989-09-12	Catalysts for ammoxidation of paraffins
US4883895A (en)	1989-11-28	Ammoxidation of paraffins and catalysts therefor
US4978764A (en)	1990-12-18	Method for ammoxidation of paraffins
US3978003A (en)	1976-08-31	Process for the oxidation of olefins to unsaturated aldehydes and nitriles and catalysts therefore
US4097518A (en)	1978-06-27	Method for the catalytic production of acrylonitrile
US4897504A (en)	1990-01-30	Method for ammoxidation of paraffins and catalyst system therefor
US5171876A (en)	1992-12-15	Method for ammoxidation of paraffins
JPS6327975B2 (de)	1988-06-06